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Direct oxidative conversion of sodium sulfide to sodium sulfite by absorbing the heat of reaction in a fluidized bed system using adiabatic cooling

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专利汇可以提供Direct oxidative conversion of sodium sulfide to sodium sulfite by absorbing the heat of reaction in a fluidized bed system using adiabatic cooling专利检索,专利查询,专利分析的服务。并且Process for simultaneously producing sulfite pulping chemical from a spent pulping medium by the exothermic oxidative conversion of sodium sulfide to sodium sulfite and for the control of the temperature in exothermic reaction and also for employing the exothermic reaction heat to make steam to be mixed with air for use in said oxidation process. Ground particles of a spent pulping smelt are treated in a fluidized bed reactor in intimate contact with moving air enriched with steam for about 10 seconds to 2 hours, wherein the weight ratio of steam to air ranges from about 0.2 to 1 to 1.2 to 1. The temperature in the reactor is adiabatically controlled and the heat of reaction generated in the reactor is absorbed by adiabatic cooling to form the steam used in the reactor.,下面是Direct oxidative conversion of sodium sulfide to sodium sulfite by absorbing the heat of reaction in a fluidized bed system using adiabatic cooling专利的具体信息内容。

  • 2. A process for controlling the temperature of the exothermic reaction employed for the direct oxidation conversion of sodium sulfide contained in a pulping smelt to sodium sulfite in a fluidized bed reactor system and forming the necessary steam for moderation of the reaction, the process comprising the steps of:
  • 2. absorbing the heat of reaction by adiabatic cooling to form the steam for the reaction in the reactor system at a temperature of about 212* F. to about 1,200* F. to thereby produce the temperature controlled oxidation reaction and sodium sulfite, the process further characterized by a balance between the steam required for moderation of the reaction and that formed by the adiabatic cooling of the reactor.
  • 3. A process as defined in claim 2 in which the temperature of step (2) is about 350* to 1,100* F.
  • 4. A process as defined in claim 2 in which the steps (1) and (2) are repeated step-wise at least once, and the water is introduced into a fluid reactor of the reactor system.
  • 5. A process as defined in claim 2 in which the steps (1) and (2) are repeated step-wise at least once, and water is introduced into a transport-type reactor of the reactor system.
  • 6. A process as defined in claim 2 in which the steps (1) and (2) are repeated step-wise at least once, and water is introduced into a multistage spouted bed reactor of the reactor system.
  • 7. A process as defined in claim 2 in which the temperature of the water in step (1) is about 50* to 212* F.
  • 8. A process as defined in claim 2 in which 0.2 to 1.2 pounds of water of step (1) is employed for each pound of the gas containing oxygen in the gas stream.
  • 9. A process as defined in claim 2 in which in step (1) 0.5 to 2.0 pounds of water is used for each pound of smelt particles.
  • 10. A process as defined in claim 1 in which the generated steam is conveyed to the outside of the fluidized reactor and mixed with air to produce a gaseous air stream mixture before the mixture enters the fluidized bed direct oxidation reaction for the conversion of sodium sulfide to sodium sulfite.
  • 11. A process as defined in claim 1 in which generated steam is introduced into the fluidized reactor.
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