All-purpose adhesive material and process for its production |
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申请号 | EP00110738.2 | 申请日 | 2000-05-19 | 公开(公告)号 | EP1156092A1 | 公开(公告)日 | 2001-11-21 |
申请人 | Garcia, Fernando H.; Pieroni, Armando; Bartolomei, Carlo Alfredo; | 发明人 | Garcia, Fernando H.; Pieroni, Armando; Bartolomei, Carlo Alfredo; | ||||
摘要 | An all-purpose two-component adhesive material and a process for its production that can be used both for fastening together flexible and porous material, such as for example wood, plastics, fabric, as well as for joining stiff material such as metal, stone. In particular the process can also be carried out using as reagents compounds resulting from processes of neutralization of exhausted sulphuric acid. In large amount adhesive material can be used to make coating material, such as tiles, whereas in different concentration the adhesive material can be used as fire-retardant varnish. The adhesive material is formed by: a first component that is an aqueous solution, having concentration higher than 5% in weight, of a sulphate, chloride, nitrate, acetate of magnesium or zinc; and a second component that is a mixture of magnesium oxide MgO, metal hydroxides, calcium sulphate hemi-hydrated. The magnesium or zinc salt are chosen among MgSO 4 , MgCl 2 ; MgNO 3 ; Mg(CH 3 COO) 2 , ZnSO 4 , ZnCl 2 ; ZnNO 3 ; Zn(CH 3 COO) 2 . In the second component the metal hydroxides are chosen among Mg(OH) 2 ; Al(OH) 3 ; Fe(OH) 3 ; Ti(OH) 4 . | ||||||
权利要求 | |||||||
说明书全文 | The present invention relates to an all-purpose two-component adhesive material that can be used both for fastening together flexible and porous material, such as for example wood, plastics, fabric, as well as for joining stiff material such as metal, stone. Furthermore, the invention relates to a process for its production. In particular, but not exclusively, the process can also be carried out by using compounds resulting from processes of neutralization of sulphuric exhausted acid as reagents. In large amount, the adhesive material can be used to make coating material, such as tiles. In different concentration, the adhesive material can be used as fire-retardant varnish. Two-component cements and adhesives are known that are very strong, which however have the drawback that they are based on noxious organic compounds, that in particular contain noxious volatile solvents. For many applications, instead, the need is felt of having adhesive material the least noxious possible and with very low impact on the environment. Another aspect for cements and other adhesive material is their different efficacy depending on whether they are used for joining either porous surfaces such as wood and rough surfaced stone, or smooth surfaces, such as metal and glossy stone. Normally, an adhesive for smooth material is not suitable for wood and other porous material such as tiles and vice versa. It is also appealing on the market a cheap adhesive material that in large quantities can be used to make coating material such as tiles. It is furthermore felt the problem of disposing of and/or regenerating baths of sulphuric acid used in the industry in known processes, such as for example for the production of titanium dioxide and in many other. In this sense recovery methods are known that are expensive and then not preferable, wherein the exhausted baths are normally delivered to companies that carry out the neutralisation, which is an expensive process and generates not recyclable residues. Neutralisation processes of baths of exhausted sulphuric acid are also known with final production of calcium sulphate. It is an object of the present invention to provide an adhesive material that does not require organic solvents and has high resistance for applications both to porous surfaces and to compact surfaces. It is a particular object of the invention to provide an adhesive material that in large amount is used to provide tiles or similar coating material. It is another particular object of the invention to provide an adhesive material that is used also as fire-retardant varnish. It is a further object of the present invention to provide a process to make such a material that can be made at a very low cost, in particular through exploitation of exhausted sulphuric acid. According to a first aspect of the invention, an adhesive material formed by a first and a second component suitable for being mixed before being applied on surfaces to be joined, wherein:
Preferably, in the first component the magnesium or zinc salt are chosen among:
Advantageously, in the second component the metal hydroxides are chosen among or are a mixture of: Mg(OH)2; Al(OH)3; Fe(OH)3; Ti(OH)4. Preferably, in the second component the following weight proportion can be provided:
In the second component a charge can be added, in a weight proportion from 0,1 to 2,5%, chosen among:
The adhesive material according to the invention operates according to two principles, one of physical nature and the other of physical/chemical nature, according to the material to be joined.
According to another aspect of the invention, a material that can be used in the building industry comprises a first and a second component suitable for being mixed and cast into moulds and has the characteristic that:
The filling charge can be chosen among or is a mixture of one of the following substances:
The material thus obtained has a high resistance to wear and to shocks and can be used for production of many types of floors, in particular tile floors. According to a further aspect of the invention, a process for the production of a material for the building industry such as an adhesive material or a material suitable for being cast into moulds for the production of tiles and the like, starting from a bath of sulphuric exhausted acid in presence of metal ions in solution, comprises the steps of:
The reaction H2SO4 is the sulphuric exhausted acid and the reagent MgO is present in a mixture of metal oxides obtained by calcination of the metal hydroxides Mg(OH)2; Al(OH)3; Fe(OH)3; Ti(OH)4. Per better disclosing the invention, the following examples, not limitative, are given. A composition used as adhesive material having the following weight proportion:
A composition used as material for the building industry having the following weight proportion:
A product with high resistance to wear and to shocks red coloured that can be used for making floors is obtained. In a possible exemplifying application of the process, the sulphuric exhausted acid and the soluble calcium salt, for example CaCl2, are mixed in a precipitator, with the consequent precipitation of calcium sulphate bi-hydrated, which is filtered in a decantation apparatus and washed: In the precipitator hydrochloric acid and metal salts in solution remain in liquid phase, as resulting from the reaction of ion exchange respectively between the ions H+ and other metal cations of the bath of sulphuric acid with the anions of the calcium chloride. The starting calcium chloride can be obtained by a reaction of ion exchange between added calcium carbonate and the hydrochloric acid as coming out from the precipitator, wherein the calcium sulphate is already precipitated, as liquid part split from the calcium sulphate: In particular the metal chlorides MClx in solution are MgCl2 + AlCl3+ FeCl3 + TiCl4 + H2O. Carbon dioxide is formed also that is stored apart. To separate the calcium chloride lime is added, whereby by adjusting the pH metal hydroxides precipitate that are decanted apart, according to the reaction: The calcium chloride in solution is then used again for reaction with other exhausted acid. The metal hydroxides precipitated and filtered Mg(OH)2 + Al(OH)3+ Fe(OH)3 + Ti(OH)4 are then used in the mixture for making adhesive material or for making material for the building industry as above described. Part of the metal hydroxides, further to reaction of calcination form metal oxides according to the reaction: These metal oxides may be TiO2, Al2O3, MgO. In particular MgO is used as component of the mixture according to the present invention above described, whereas Fe2O3 can be used as dye for applications like example 2, Sulphuric acid is provided by a chemical plant at a concentration of 98 g/l and temperature 50°C. In a reactor for precipitation the acid is mixed with a solution of CaCl2 at 10% p/v and kept at a temperature of 50°. Starting from a flow rate of 2,4 t/h of sulphuric acid and 2,7 t/h of calcium chloride 4,2 t/h of calcium sulphate are stoichiometrically obtained. Since an is necessary excess of 15% of calcium chloride, its flow rate must be of 2,7*1,15= 3,15 t/h. For recovering metal oxides from the reaction Once separated the calcium sulphate, calcium carbonate is added for the preparation of calcium chloride. Then the metal chlorides precipitate after the addition of calcium hydroxide. Bringing the pH to 5.6 precipitates at first Fe(OH)3 + Ti(OH)4. Then, bringing the pH to 11,5 Mg(OH)2 + Al(OH)3 precipitate. The metal hydroxides precipitated are calcined at 1000°C obtaining a solid mixture (A) containing both ferric oxide at high resistance to wear and corundum artificial of high hardness and resistance. With 25000 l/h of effluent containing sulphuric exhausted acid 1.3 t/h of solid mixture (A) of metal oxides are obtained. Parallel, red calcium sulphate bi-hydrated is calcined at 1000° C to obtain calcium sulphate hemi-hydrated (B) (plaster of Paris). Part of the solid mixture (A) reacts with the sulphuric exhausted acid up to neutralization so that the magnesium oxide MgO forms magnesium oxy-sulphate MgSO4 in solution (C). The other metal oxy-sulphates are used as charge. By making a solid mixture (A) + (B) with 75% of (A) and 25% of (B) and by adding the liquid (C) further diluted in water at 12%, a mixture is obtained that is warmed up to 75° and then cast into tiles that are baked in oven, obtaining "baked red Tuscan tiles". With reference to example 4, at first Fe(OH)3 + Ti(OH)4 + Al(OH)3 can be precipitated with pH less than 11, then Mg(OH)2 can be obtained bringing the pH to 11.5. Then, after calcination MgO is obtained. Then, building material can be made from the mixture That is warmed up to 75° and then moulded into tiles that are baked in oven. A composition according to example 5 used as fire-retardant varnish, with dilution by addition of water to obtain a consistency suitable for application onto wood or plastics surfaces for insulating them from fire. The foregoing description of a specific embodiment will so fully reveal the invention according to the conceptual point of view, so that others, by applying current knowledge, will be able to modify and/or adapt for various applications such an embodiment without further research and without parting from the invention, and it is therefore to be understood that such adaptations and modifications will have to be considered as equivalent to the specific embodiment. The means and the materials to realise the different functions described herein could have a different nature without, for this reason, departing from the field of the invention. It is to be understood that the phraseology or terminology employed herein is for the purpose of description and not of limitation. |