Coating composition |
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| 申请号 | EP91301695.2 | 申请日 | 1991-03-01 | 公开(公告)号 | EP0501055B1 | 公开(公告)日 | 1994-09-07 |
| 申请人 | Armstrong World Industries, Inc.; | 发明人 | Glotfelter, Craig Allen; Ryan, Robert Parke; | ||||
| 摘要 | |||||||
| 权利要求 | |||||||
| 说明书全文 | This invention relates to coating compositions and to surface covering layers comprising or derived from them. More particularly, the invention relates to an epoxy/glass coating composition which provides stain and gloss protection when applied, for example, over a clear protective layer. Since the mid-1940's it has been known that metal alkoxides could be hydrolysed and condensed to form glasses. Subsequently, from about the mid-1970's it has been known that silica could be produced in situ as a chemical product of compounds such as tetraethylorthosilicate (TEOS). It has previously been proposed in U.S. Patent No. 3,811,918 partially to acid hydrolyse silicon alkoxide and add metal oxide to prepare a glass precursor which could be fired to a glass composition at a temperature above 1000°C. Further, U.S. Patent No. 4,346,131 describes the preparation of a clear alcohol solution of acid hydrolysed metal alkoxide which may be coated on a substrate and dried to produce an optical coating. Silane coupling agents as disclosed in U.S. Patent No. 4,480,072 provided a useful means to crosslink organic and inorganic surfaces and particles. An article on SOL-GEL DERIVED DIP COATINGS by Helmut Dislich of Schott Glaswerke, Hattenbergstr. 10, 6500 Mainz, Germany, discloses how mixtures of metal alkoxides may be used to condense mixed metal on a glass surface such, for example, as silicon-titanium, aluminium-magnesium, cadmium-tin and indium-tin. An article on ORGANICALLY MODIFIED SILICATES AS INORGANIC-ORGANIC POLYMERS by H. K. Schmidt of Fraunhofer-Institut fur Silicatforschung, Wurzburg, Germany, describes combinations of linear organic polymer networks with three dimensional tetrahedron silicon networks using the sol-gel process, e.g., where combined polymerization of methacrylate and condensation of Ti(OR)₄/Si(OR)₄/epoxy-Si(OR)₃ produce a reinforced system with increased tensile strength and scratch resistance. U.S Patent No. 4746366 and EP-A-373451 describe the manufacture of scratch-resistant lacquer by condensation of a hydrolysable titanium or zirconium compound, an organofunctional silane and optionally an inorganic oxide, by initially mixing the starting materials under acidic conditions in the presence of a smaller quantity of water than required for hydrolysis of all the hydrolysable groups. In Polymer Bulletin, 24, 173, the preparation of ultramicro organophilic silica particles, by base-catalysed co-hydrolysis of and co-condensation between tetraethoxysilane and a trialkoxy-organosilane, is described. Japanese Application No. 86/25,739 discloses antifogging tile coatings where silica is bonded to polyvinyl alcohol using hydrolysed [3-(glycidyloxy)propyl] trimethoxysilane. European Patent Application No. 222,582 discloses an ultraviolet curable composition with good adhesion to glass comprising epoxy resin, poly-organosiloxane, aromatic onium salt and acrylate resin. British Patent Application No. 2,177,093 describes an ultraviolet curable coating composition comprising a multifunctional glycidyl or cycloaliphatic epoxy oligomer, hydrolysed silane coupling agent treated inorganic filler and photoinitiator for reaction of epoxy groups. There still remains, however, a need to provide protective wear surfaces which may be conveniently produced without adverse environmental effects. The present invention provides a composition comprising an acid-catalysed hydrolysis product of an inorganic metal alkoxide and an acid-catalysed hydrolysis product of a coupling agent having an inorganic metal alkoxide functionality and an organic functionality; provided that (a) the composition comprises an acid-catalysed hydrolysis product of an inorganic metal alkoxide, an acid-catalysed hydrolysis product of a coupling agent having an inorganic metal alkoxide functionality and an organic functionality, and a multifunctional organic monomer, the organic functionality of the multifunctional monomer and the organic functionality of the coupling agent being reactively compatible; or (b) the composition consists essentially of an acid-catalysed hydrolysis product of an inorganic metal alkoxide selected from the group consisting of tetramethylorthosilicate, tetraethylorthosilicate and tetrapropylorthosilicate, the hydrolysis of the alkoxide having taken place in the presence of a stoichiometric quantity of water, and an acid-catalysed hydrolysis product of a coupling agent having an inorganic metal alkoxide functionality and an organic functionality selected from the group consisting of acrylates, methacrylates, epoxides and amino-functionalities, the hydrolysis of the coupling agent having taken place in the presence of a stoichiometric quantity of water. The present invention also provides a composition comprising the reaction product of the hydrolysis products and, if present, the organic monomer, and a surface covering product comprising the reaction product in the form of a layer providing stain resistance and gloss retention. The surface covering product is advantageously a flooring material. The metal, both in the alkoxide and the coupling agent, may be, for example, aluminium, zirconium, titanium or, advantageously, silicon. Preferred hydrolysis products of metal alkoxides are the products of hydrolysis of tetramethylorthosilicate (TMOS), tetraethylorthosilicate (TEOS) and tetrapropylorthosilicate (TPOS). Preferred coupling agents are acid-hydrolysed epoxy/silanes. Preferred monomers are difunctional. Epoxy monomers are also preferred; difunctional epoxy monomers are much preferred. Monomers are advantageously present in the composition even when the coupling agent does have a preferred organic functionality. The composition may contain a photoinitiator if it is to be curable by ultraviolet radiation. A preferred composition comprises
A preferred method for preparing a protective coating comprises
The coating may be cured by any suitable means including heat or ultraviolet light irradiation. The hardness and durability of ceramics have long made them a desirable surface for, for example, wall and floor applications. The best ceramics have Mohs hardness ratings of 8 and above. Unfortunately, all traditional ceramics with high Mohs hardnesses require, as part of their processing, a firing step during which temperatures of 800°C and above are the norm. To create a ceramic surface on a typical floor substrate such as vinyl tile, then, would seem to be highly improbable. Yet in spite of the difficulty perceived, the present invention provides a polymer/glass hybrid coating based on sol-gel technology that has outstanding physical properties, for example, on vinyl-based flooring substrates. The sol-gel process embodies the phase transformation of a colloidal dispersion (or sol) of a metal oxide to a gel. The metal oxide gel may then be dried to form the corresponding glass as indicated by Equation (1). where X = Si, Ti, Al... Methods of accomplishing the sol-gel transformation include dispersion of a fine particulate metal oxide (e.g. silica) in an aqueous acidic solution, neutralization of an acidic metal salt solution (e.g. indium nitrate in nitric acid), neutralization of an alkali metal silicate with acid (e.g. sodium silicate), and the hydrolysis/condensation reaction of a metal alkoxide or halide (e.g. tetraethylorthosilicate or tetrachlorosilane). Sol-gel processing of metal alkoxides is of particular importance because with varying reaction conditions the control of particle size in gels is possible (optical clarity), the composition of the final glass may be easily varied (toughened glasses, e.g., borosilicate, zirconia/silica), and polymer species may be introduced in solution to achieve hybrid inorganic/organic materials. Generally, any of the metal alkoxides based upon Al, Zr, Si or Ti will readily form oxides after hydrolysis and removal of solvent as indicated by Equation (2) where X = Si, Ti, Zr, Al... Typically, the hydrolysis/condensation reactions of metal alkoxides are run using a stoichiometric amount of water and at a pH of about 2. This procedure works well for the silicon and aluminium alkoxides but other alkoxides such as zirconium and titanium require a very low pH or slow hydrolysis reactions to maintain a reasonable stability. Those alkoxides forming stable gels at low pH are otherwise unsuitable for inorganic/organic hybrid systems because of the reactivity of the monomer/polymer portion of the system. Many alkoxides, when hydrolysed, immediately condense to form macroscopic metal oxide particles. Zirconium and titanium alkoxides exhibit this behaviour if the pH of the system is not sufficiently low. Silicon and aluminium alkoxides, however, are able to be hydrolysed at pH's of 2 to 5 and remain stable for relatively long periods of time. The term polymerization is often used in sol-gel processing to describe the transformation of the sol phase to the gel/glass phase since glass is a polymer. However, it is probably more correct to think of the gel-to-glass conversion as an aggregation step during which discrete oxide particles of small size (in the range of 4 nm for acid catalysed silicon alkoxides) form and are chemically bonded to one another. This contrasts with the molecular polymerization concept where each functional group reacts to form either a linear or three dimensional network. Glasses prepared from acid-catalysed sol-gel processes form clear, hard films because of the extremely small sizes of the aggregated oxide particles and, in thin films (150 nm), sol-gel derived glasses rival the performance of traditional glasses. Silicon alkoxides are by far the easiest alkoxides from which such glasses may be formed. Using metal halides has the disadvantage of acid generation during the hydrolysis step. TEOS and TMOS are readily hydrolysed at pH 2 and condense upon evaporation of solvent to give approximately 90 % yield pure silica as determined by IR (powder dried 2 hrs. @ 150°C). If the hydrolysis product is left in solution and the solution sufficiently concentrated, a gel will form in 24 - 72 hours. The present invention provides a hybrid coating preferably based on a cycloaliphatic epoxy and a silicon alkoxide. Typically, the coatings have a Mohs hardness rating of 1.5 - 4. While falling short of the Mohs hardness of ceramic surfaces, the hybrid coating represents an increase in hardness compared to normal "hard" polymers (e.g. PMMA has a Mohs hardness of 1.50). In fact, it has been surprisingly found that 0.5 to 8 µm coatings of the present invention have stain resistance and wear retention rivaling ceramic tile. Thus, when applied to a flooring structure consisting of either a tile or resilient base and an intermediate layer of a U.V. curable clear, transparent layer, a 1-2 µm coating of the invention greatly enhances the wear properties of currently available flooring wear surfaces when applied, via a spray or dip process for example. The general scheme for producing a polymer/glass hybrid is: (1) preparation of a hydrolysed metal alkoxide in solution (acid catalysed), (2) preparation of a hydrolysed coupling agent (e.g., bifunctional having one trialkoxysilane functionality and one organic functionality) in solution (acid catalysed), and after mixing the above, (3) inclusion of photopolymerizable monomer (either free-radical or cationically initiated), (4) inclusion of an appropriate photoinitiator, (5) inclusion of a surfactant, (6) coating on a clear, protective layer (7) drying, and (8) ultraviolet exposure. If curing is by means other than ultraviolet, the photoinitiator may be omitted. TMOS, TEOS and TPOS are the preferred silicates for acid hydrolysis at a pH of 4 or below. Triethylborate (TEB) or boric acid may be substituted for the TMOS, TEOS or TPOS in amounts from 0.25 to 1.5 % by weight of TMOS, TEOS or TPOS in order to increase the useful lifetime of the coating solution. While other metal alkoxides might not be as convenient to use, they nevertheless may be employed to vary the properties of the wear surface protective coating within the practice of the present invention as long as they are compatible with the sol-gel process. There are a number of commercially available silane coupling agents with polymerizable functional groups. Acrylates, methacrylates and epoxides are available as well as amino-functional silanes capable of polymerizing epoxide resins. Epoxy functional coupling agents perform best when they incorporate a trifunctional alkoxysilane. While it is not critical if the epoxy silane is either a glycidyl ether or cycloaliphatic oxide type, a preferred coupling agent is 3-glycidoxypropyltrimethoxy silane. Epoxy monomers which were found to be useful within the present invention include: On the other hand, epoxy monomers which were found to be unsuitable in the present invention include: While it is not known with any degree of certainty, it is believed that cycloaliphatic oxide functionality must predominate over glycidyl ether functionality in order for the epoxy monomer to produce the hybrid system of the present invention. A particularly useful epoxide is ERL-4221 with the structural formula: Vinyl monomers, for example triethylene glycol divinyl ether, also provide excellent glass protection and stain resistance equivalent to the preferred epoxy monomers. Acrylate or vinyl monomers such as described in U.S. Patent Nos. 2,760,683; 2,791,504; 2,927,022; 3,261,686; or 3,380,831 may be employed solely or in combination with epoxy monomers depending on the degree of hardness desired for the protective coating. Mixtures of monomers may necessitate having mixtures of photoinitiators for both types of polymerization. For epoxy polymerization there are commercially available photoinitiators which produce an acid catalyst capable of initiating epoxy polymerization based on aryliodonium, arylsulfonium or aryldiazonium compounds. These include diphenyliodonium hexafluorophosphate and bis[4-(diphenylsulphonio)-phenyl]-bis-hexafluorophosphate. A surfactant may be conveniently employed in the coating composition. Suitable surfactants include: Triton X-100 from Rohm and Haas, Surfynol 104-E from Air Products, Aerosol OT from American Cyanamid, FC-120 from 3M, and Tergitol NP-27 from Union Carbide. (Triton, Surfynol, Aerosol OT, and Tergitol are trade marks). It is preferred to use a silicone oil surfactant such as poly(dimethylsiloxane) to obtain superior stain and gloss protection. The hard, epoxy/glass (inorganic/organic) coating composition is conveniently prepared by combining the acid-catalysed hydrolysis product of either TMOS, TEOS or TPOS with the acid-catalysed hydrolysis product of an epoxy/silane coupling agent such, for example, as 3-glycidoxypropyltrimethoxysilane or 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane. The hydrolysis of the alkoxide and the coupling agent is carried out, for example, with stoichiometric amounts of 0.1 % aqueous HCl solution. The liquor from the hydrolysis reaction is combined with, for example, a difunctional epoxy monomer having at least one cycloaliphatic epoxide functionality, e.g., 4-vinyl cyclohexenedioxide or 3,4-epoxycyclohexylmethyl-3,4-epoxy cyclohexane carboxylate. An amount of arylonium salt capable of initiating the ring-opening, cationic photopolymerization of the epoxy monomer is used, as well as 0.25 weight per cent of a surfactant based on poly(dimethylsiloxane). The combined ingredients are coated via a blade applicator, spray, or floor coating onto a substrate and dried to a slight tack state, U.V. cured using a dosage of typically 1.0 - 3.0 joules/cm², and in an optional step heat cured at 250°F (121°C). Generally, the more basic the hydrolysis reaction, the larger the particle size in the aggregated gel that forms. When the particles reach sufficient size, they interfere with visible light and form opaque gels. If the pH of the reaction mixture is >7 the most likely result is a precipitated silica product. The gels are of high clarity and have the physical characteristic of behaving as though in a highly compressed, totally elastic state much like a "superball". The gel continues to densify with the evaporation of solvent until eventually reaching a glass state. Sol-gel processing of metal alkoxides is highly sensitive to stoichiometric factors during hydrolysis as well as the pH of the medium in which the hydrolysis condensation reaction is carried out. Although the sol-gel process provides a route for the low-temperature conversion of metal alkoxides to glasses, the problems encountered during the drying stage after gel formation are formidable (volume changes of 8 : 1 are common). And although the sol-gel process is touted as a low-temperature route to glass formation, the temperatures involved in transforming gels to glasses are almost always much higher than practical for a wear surface production process. Polymer/glass hybrids, however, can be designed to obtain their ultimate properties at suitable temperatures. It has been discovered that silica/epoxy hybrids can be processed at temperatures ranging from 125° to 400°F (about 50° to about 200°C). Generally, the higher the processing temperature, the harder the final wear surface obtained. Formulations particularly preferred for the present invention contain four elements: (1) acid hydrolysed silicon alkoxide, (2) acid hydrolysed silicon alkoxide coupling agent, (3) difunctional, cycloaliphatic epoxy monomer, and (4) silicone surfactant. Total water content for the coating formulation is typically about 20 % by weight. A coating is prepared from the formulation by any thin film application method, dried and exposed to U.V. or electron beam radiation (in which case the photoinitiator is not required). The resulting hybrid film consists of a chemically bonded glass phase and polymer phase as typified by the following Equation (3) where R = epoxy, acrylate.... and a = multifunctional polymerizable monomer (epoxy, acrylate...) Polymer/glass hybrids have advantages over all glass systems in that they can be applied as relatively thick coatings (76-127 µm), require modest cure energy, and exhibit outstanding performance as wear surfaces in flooring applications. Coating thicknesses of 1-2 µm have proven to be especially outstanding in physical property tests when applied over flooring substrates. The present invention advances building and flooring materials art by providing a hard wear surface with excellent stain and gloss protection which can be bonded over a relatively soft surface. Since these transparent polymer/glass (organic/inorganic) compositions can be applied over clear, protective layers, there can be a wide range of applications for a wear surface which will not detract from the appearance of the support or surface being protected. The following examples illustrate the invention. For safety all preparatory work should be done in a hood. The tetraethylorthosilicate (TEOS) hydrolysis is carried out using a stoichiometric amount of water and is catalysed by keeping the pH of the reaction mixture at about 2 (normally 1 or 2 drops conc. HCl in a batch size using 100 ml. TEOS). The coupling agent hydrolysis is carried out separately and also uses a stoichiometric amount of water (one drop conc. HCl catalyst per 50 ml. batch size). There is an exotherm observed in both hydrolysis reactions. After the hydrolysis reactions are completed, the coupling agent and TEOS solutions are stirred for at least 30 minutes. After this time, the two solutions are combined in a two to one weight ratio of TEOS solution to coupling agent solution. The epoxy and epoxy photoinitiator if required are added. The solution is mixed well for 15 minutes and is then ready for coating after addition of the silicone oil surfactant. If dilutions are to be made, they are done at this point with an 80/20 volume per cent mixture of ethanol and water. For test purposes, a tile or resilient substrate having a typical filled or unfilled PVC plastisol composition was prepared by applying a U.V. curable, clear, protective coating, usually via a curtain-coater, at a thickness of 2-4 mils (51-102 µm) and cured via a dosage of 3 joules/cm² U.V. The coated flooring structure was then given a spray or dip application of the invention sufficient to give a 1-2 µm dry thickness of the invention and subsequently exposed to U.V. radiation. Stain protection was determined by comparing discoloration of control and invention test samples which were covered with various stain compositions and then wiped clean. Trafficked samples were abraded with dirt for 30, 60 and 90 minutes and comparative gloss measurements were taken to determine the effectiveness of the protective surface. The % reduction from the initial gloss reading can be taken as an indication of surface wear. The ingredients designated ERL-4221 and FX-512 are trade names for the difunctional, cycloaliphatic epoxy monomer and arylonium salt and are marketed by Union Carbide and 3M Company, respectively. The TEOS and 32.5 g water were combined in a beaker and let stir for 45 minutes. During this time, the GPTMOS was combined with 13.5 g water and stirred. After 45 minutes (or when the TEOS solution was clear), the TEOS and GPTMOS solutions were mixed and the remaining components were added as described above. A coating of 1-2 µm final thickness was obtained by a 4 : 1 dilution with an 80/20 volume per cent mixture of ethyl alcohol (abs.) and water followed by the spray application of approximately 1 mil (25.4 µm) wet of the diluted form of Example 1. After 5 minutes at 150°F (66°C) drying time, the coating was U.V. cured with a dose of 3 joules/cm². Table 1 and Table 2 contain comparative results for stain and gloss protection for the invention versus uncoated control tile. A formulation was prepared as in Example 1 except that 4-vinyl cyclohexene dioxide was used as the epoxy monomer and diphenyliodonium hexafluorophosphate was used as the photoinitiator. After U.V. exposure and heat curing at 250°F (121°C) for 30 minutes, a clear, hard, abrasive-resistant coating was produced which had excellent resistance to household stains similar to Table 2. Coatings were prepared as in Example 1 except that TMOS or TPOS was used to replace TEOS as the acid hydrolysed silicate. After U.V. curing, the samples were heat cured at 250°F (121°C) for 30 minutes. These samples gave moderate stain versus severe stain for the control. Coatings were prepared as in Example 1 except that a cycloaliphatic epoxy/silane coupling agent was used. The coupling agent, 2-(3,4-epoxycyclohexyl)ethyl-trimethoxysilane, gave satisfactory coating compositions and was U.V. cured to produce satisfactory wear surfaces with properties similar to Tables 1 and 2 above. A composition containing acrylate monomer was prepared as follows: As in Example 1, the TEOS and silane coupling agent were separately acid hydrolysed before combination and addition of acrylate monomer, benzophenone photoinitiator and surfactant. When coated and tested in comparison with the composition of Example 1, the acrylate composition gave stain and gloss protection better than a control, but not as good as an epoxy formulation. Results are shown in Table 3. Coating compositions were prepared and tested as in Example 1 except using a surfactant selected from: Triton X-100, Surfynol 104-E, Aerosol OT, FC-120, Tergitol NP-27. While a satisfactory wear surface was produced, these tests did not produce the superior stain and gloss protection of Examples 1 to 5 wherein a silicone surfactant was incorporated in the composition. A coating composition was prepared and tested as in Example 1 except that a vinyl monomer, i.e., triethylene glycol divinyl ether, was substituted for the epoxy monomer. Fully equivalent wear and stain were obtained as illustrated in Tables 1 and 2. Coating compositions were prepared and tested as in Example 1 except that portions of TEOS were replaced with triethylborate (TEB). Test samples were cured at 3 joules/cm² U.V. exposure. The coating compositions were examined at intervals to determine shelf life. Table 4 contains comparative results for stain and gloss retention. |
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