Process for recovering cesium from cesium alum

申请号 EP84107903 申请日 1984-07-06 公开(公告)号 EP0132656A3 公开(公告)日 1985-04-17
申请人 CARUS CORPORATION; 发明人 Mein, Peter Guenter;
摘要 @ Cesium is recovered from cesium alum, CsAl(SO 4 ) 2 , by a two-reaction sequence in which the cesium alum is first dissolved in an aqueous hydroxide solution to form cesium alum hydroxide, CsAl (OH) 3 , and potassium sulfate, K 2 SO 4 . part of the K 2 SO 4 precipitates and is separated from the supernatant solution. In the second reaction, a water-soluble permanganate, such as potassium permanganate, KMnO., is added to the supernatant. This reaction forms a precipitate of cesium permanganate, CsMnO.. This precipitate may be separated from the residual solution to obtain cesium permanganate of high purity, which can be sold as a product or converted into other cesium compounds.
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