Preparing poly(arylene ketones)

申请号 EP85302192 申请日 1985-03-28 公开(公告)号 EP0173408A3 公开(公告)日 1987-09-30
申请人 RAYCHEM CORPORATION (a California corporation); 发明人 Reamey, Robert Howard;
摘要 The preparation of poly(arylene ketones) and in particular all para-linked poly(arylene ether ketones) by Friedel-Crafts polymerization in the presence of a Lewis acid generally results in an intractible reaction product difficult to remove from the reaction vessel and difficult to purify. The addition of a liquefaction agent, such as a hydrogen halide and in particular hydrogen chloride, to the reaction mixture, results in a tractible gel or a liquid which can be readily handled. The hydrogen halide is preferably under pressure and a diluent may also be added along with the hydrogen halide.
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