序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 磷酸盐化合物组合物及其作为肥料的用途 CN201180005363.9 2011-01-04 CN102712549B 2016-03-30 哈维尔·埃罗; 罗伯托·拜戈里; 何塞·加西亚·米纳; 让-克洛德·伊温
发明涉及由一种方法获得的磷酸盐化合物,所述方法包括任选地在无机酸有机酸的存在下使不溶性磷酸盐源与主要为植物来源的有机源反应,所述有机源具有至少10%的络合官能团。本发明的化合物可用于制备肥料
2 一种利用和处理硫酸白生产中废酸、废渣的方法 CN93118849.0 1993-10-09 CN1064032C 2001-04-04 宁甲保
硫酸法生产白的生产过程中,会产生大量废稀酸和废渣,本发明通过提高废稀酸的浓度,通过加入催化剂而大大加快了生成肥料的速度,提高化肥的质量,通过加入残渣达到了处理残渣、改善肥料的综合性能之目的。该法制做的肥料,成本低,含磷高,且含利于作物吸收的有益元素,颗粒细而膨松,具有方法简单,成本低廉,肥效高等特点。
3 一种生产氮磷复合肥的方法 CN97120282.6 1997-11-12 CN1184094A 1998-06-10 武善东; 武征
发明公开了一种生产氮磷复合肥的新方法。以磷矿粉酸解后的固液两部分产物为原料与挥发进行反应。本发明使磷铵工艺所弃固体废渣得以充分利用,并将挥发氨转化成固定铵,同时省去了磷铵工艺中的氨化炉。该方法简单易行,生产成本低,生产规模大,为小氮肥改造提供了新的途径。
4 磷酸盐化合物及其作为肥料的用途 CN201180005363.9 2011-01-04 CN102712549A 2012-10-03 哈维尔·埃罗; 罗伯托·拜戈里; 何塞·加西亚·米纳; 让-克洛德·伊温
发明涉及由一种方法获得的磷酸盐化合物,所述方法包括任选地在无机酸有机酸的存在下使不溶性磷酸盐源与主要为植物来源的有机源反应,所述有机源具有至少10%的络合官能团。本发明的化合物可用于制备肥料
5 除去硫酸白生产中废酸、废渣的方法 CN93118849.0 1993-10-09 CN1101637A 1995-04-19 宁甲保
硫酸法生产白的生产过程中,会产生大量废稀酸和废渣,本发明通过提高废稀酸的浓度,通过加入催化剂而大大加快了生成肥料的速度,提高化肥的质量,通过加入残渣达到了处理残渣、改善肥料的综合性能之目的。该法制做的肥料,成本低,含磷高,且含利于作物吸收的有益元素,颗粒细而膨松,具有方法简单,成本低廉,肥效高等特点。
6 Process for the removal of heavy metals from acid, phosphate-containing aqueous media EP87201356.0 1987-07-14 EP0253454B1 1990-11-14 Weterings, Cornelis Antonius Maria,; Janssen, Johannes Anna,
7 Potash compound fertilizer JP2005123767 2005-04-21 JP4548835B2 2010-09-22 祐也 佐藤; 輝男 浦野
8 New potassium phosphate compound fertilizer JP2005123767 2005-04-21 JP2006298706A 2006-11-02 URANO TERUO; SATO YUYA
<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a new potassium phosphate compound fertilizer capable of validating a phosphoric acid component contained in incinerated ashes of poultry dung by improving its solubility and at the same time having a powdery form with good handling that is obtained by neutralizing an alkali derived from a lime component, and a new potassium phosphate compound fertilizer. <P>SOLUTION: The problem can be solved by adding an alkaline earth metal compound to incinerated ash powder of poultry dung, adding a mineral acid to this so as to cause a neutralization reaction between the added alkaline earth metal compound powder and the added mineral acid, raising the temperature of the reaction system by utilizing the heat build-up at the neutralization reaction, accelerating a reaction between the mineral acid and a lime component or the like contained in the incinerated ash of poultry dung, converting a phosphoric acid component to a citric acid-soluble phosphate, and at the same time keeping the product in a neutral or weakly acidic range. <P>COPYRIGHT: (C)2007,JPO&INPIT
9 METHOD FOR PRODUCING GRANULAR FERTILISERS EP03739499.6 2003-02-18 EP1480926A2 2004-12-01 MINAEV, Vladimir Vasillievich
In particular to improve the physico-mechanical properties of granular fertilisers and in order to increase the efficiency of the application of alkaline, alkaline earth-elements and group IV elements, the invention provides a method for producing granular fertilisers comprising at least one structural compound based on at least one salt with the steps of disposing of at least one salt comprising nitrogen, humidifying the at least one salt, mixing the at least one humidified salt with at least one substance comprising at least one alkaline and/or alkaline-earth element and/or at least one element of the forth period of group IV, producing a granular fertiliser by granulation of the mixture, and cooling the granular fertiliser. The invention further provides a granular fertiliser comprising nitrogen and having a ph in the range of 3 = pH = 7. The granular fertiliser shows a strength σ of σ = 3 Mpa and an entire amount csc of at least one structural compound with csc = 50 wt. -%.
10 Process for the removal of heavy metals from acid, phosphate-containing aqueous media EP87201356.0 1987-07-14 EP0253454A1 1988-01-20 Weterings, Cornelis Antonius Maria,; Janssen, Johannes Anna,

A process for the removal of heavy metals from an acid phosphate containing, liquid medium in which process a precipitate containing heavy metals is formed and is subsequently separated and wherein at least one of the two additives a) sulphate ions and b) calcium ions is added to the phosphate-containing, liquid medium under such conditions that a calcium sulphate anhydride-containing precipi­tate is formed.

11 PHOSPHATE COMPOUNDS AND USE THEREOF AS FERTILIZER US13519663 2011-01-04 US20130104612A1 2013-05-02 Javier Erro; Roberto Baigorri; Jose Garcia-Mina; Jean-Claude Yvin
The invention relates to phosphate compounds obtained according to a method comprising reaction of a source of insoluble phosphate with an organic source, principally of vegetable origin, optionally in the presence of a mineral acid or an organic acid, said organic source having at least 10% of complexing functional groups.The compounds of the invention are useful for preparing fertilizer.
12 Treatment of phosphate rock with acids US3671189D 1966-06-16 US3671189A 1972-06-20 BETTS ANSON G
PHOSPHATE ROCK IS DECOMPOSED BY TREATMENT WITH SOLUTION OF ACID SELECTED FROM THE GROUP OF ACIDS NAMED IN THE SPECIFICATION, USING A PROPORTION OF ACID SUFFICIENT TO SUBSTANTIALLY COMPLETE THE DECOMPOSITION OF THE CALCIUM FLUOPHOSPHATE OF THE USED PORTION OF THE PHOSPHATE ROCK. THERE IS PROVIDED AND USED IN THE ACID TREATMENT OF THE PHOSPHATE ROCK A REACTING COMPOUND OF ALUMINUM USED IN THE PROPORTION STATED IN THE SPECIFICATION, WITH THE RESULT THAT THE FLUORINE OF THE TREATED PHOSPHATE ROCK CHEMICALLY REACTS AND COMBINES WITH ALUMINUM OF THE USED COMPOUND OF ALUMINUM TO FORM A COMPOUND OF ALUMINUM AND FLUORINE. SEPARATE COMPOUNDS OF (1) SUBSTANTIALLY FLUORINE-FREE ARTIFICIAL PHOSPHATE AND (2) OF ALUMINUM-FLUORINE COMPOUND OF RESULT, WHICH MAY BE RECOVERED SEPARATELY IN AN ARIFICIAL PHOSPHATE PRODUCT AND A SOLID FLUOALUMINATE PRODUCT. SULPHUROUS ACID FORMED WHEN A STREAM OF GAS FROM COMBUSTION OF A SULPHUR-CONTAINING SUBSTANCE IS BROUGHT INTO AN AQUEOUS SOLUTION, MAY BE USED AS THE ACID OF TREATMENT OF PHOSPHATE ROCK, MYSELF HAVING DISCOVERED THAT WHILE PHOSPHATE ROCK IS REFRACTORY TOWARD SO-OBTAINED SULPHUROUS ACID, PHOSPHATE ROCK IS CHEMICALLY DECOMPOSABLE BY SUCH SOLUTION OF SULPHUROUS ACID CONTAINING A REACTABLE ALUMINUM COMPOUND. AS A RESULT OF MY DISCOVERY THE RECOVERY AND UTILIZATION OF SULPHUR DIOXIDE FROM GAS STREAMS RESULTING FROM THE BURNING OF SULPHUR-CONTAINING SUBSTANCES IS MADE PRACTICAL AND USEFUL. NEW AND USEFUL PHOSPHATE PRODUCTS RESULT FROM THE USE OF MY SAID DISCOVERY.
13 Continuous method of producing ammonium phosphate fertilizer US60592966 1966-12-29 US3396004A 1968-08-06 LEGAL JR CASIMER C; ALVIN RICHMOND
14 Treatment of phosphate rock US11545061 1961-06-07 US3150957A 1964-09-29 SEYMOUR JAMES E; ROBERT WHITE
15 Production of water-soluble phosphate compounds US54826831 1931-07-01 US1945914A 1934-02-06 EMIL REUBKE
16 Method of treating phosphate rock US19045D USRE19045E 1934-01-16
17 Method of leaching raw phosphate US36607829 1929-05-25 US1902648A 1933-03-21 MARKUS LARSSON
18 Method of leaching phosphate rock US50883031 1931-01-15 US1836672A 1931-12-15 MARKUS LARSSON
19 Process for the manufacture of phosphate manures US43711821 1921-01-13 US1445167A 1923-02-13 HERMANN PLAUSON
20 Method for preparing phosphate compounds US13519663 2011-01-04 US09079804B2 2015-07-14 Javier Erro; Roberto Baigorri; Jose Garcia-Mina; Jean-Claude Yvin
The invention relates to phosphate compounds obtained according to a method comprising reaction of a source of insoluble phosphate with an organic source, principally of vegetable origin, optionally in the presence of a mineral acid or an organic acid, said organic source having at least 10% of complexing functional groups.The compounds of the invention are useful for preparing fertilizer.
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