序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
121 LAYERED SHEETS AND PROCESSES FOR PRODUCING THE SAME US11995311 2006-07-07 US20090148687A1 2009-06-11 Junji Hirose; Takeshi Fukuda
Provided herein is a process for producing a layered sheet. The process involves preparing a cell dispersed urethane composition by a mechanical foaming method. The cell dispersed urethane composition is applied to a base material sheet and cured to produce a polyurethane foam layer of uniform thickness. A releasing sheet may be utilized to make the thickness of the polyurethane foamed layer uniform. Also, provided herein is a layered sheet produced by the above process. The polyurethane foamed layer may have spherical fine cells having an average cell diameter of 20 to 300 μm. The polyurethane foamed layer may have a specific gravity of 0.2 to 0.5. The polyurethane foamed layer may also have a Asker C hardness of 10 to 50 degrees.
122 MODIFIED COPOLYESTERS AND IMPROVED MULTILAYER REFLECTIVE FILMS US12267947 2008-11-10 US20090062504A1 2009-03-05 Timothy J. Hebrink; William W. Merrill; Carl A. Stover
A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
123 High-durability photocatalyst film and structure having photocatalytic functions on surface US10522915 2003-07-30 US07488524B2 2009-02-10 Ryouzo Nishikawa; Naoki Tanaka; Norihiro Nakayama
A high-durability photocatalyst film that is a laminated film comprising a substrate film and a photocatalytically active material layer formed thereon via a protective layer, wherein the substrate film is a film having specific performances in a weather resistance test with a sunshine weatherometer, the protective layer is an organic-inorganic composite graded film and the above laminated film exhibits specific performances in an accelerated weather resistance test with a sunshine weatherometer, and a structure having photocatalytic functions on a surface formed of the above photocatalyst film.
124 MODIFIED COPOLYESTERS AND IMPROVED MULTILAYER REFLECTIVE FILMS US11611462 2006-12-15 US20070098970A1 2007-05-03 TIMOTHY HEBRINK; William Merrill; Carl Stover
A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
125 OPTICAL FILM US11461406 2006-07-31 US20060286396A1 2006-12-21 James Jonza
Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth can be achieved.
126 Micro-coextruded film modified with piezoelectric layers US11412451 2006-04-27 US20060267459A1 2006-11-30 Marcus Shelby
Disclosed are layered films having a combination of piezoelectric layers that change dimension with applied voltage and non-piezoelectric layers. The layered structures can form a wide range of electrically switchable optical films. These films have applications in displays, polarizers, optical compensators, aesthetic films, and “hot” and “cold” mirrors that selectively reflect only certain wavelengths. Also disclosed are monochromatic and multicolor displays using these films.
127 Laminated sheet for forming article US10565940 2004-07-27 US20060240246A1 2006-10-26 Masanobu Fukuda; Kouji Shiota; Tatsuya Kouyama; Kenkichi Yano
A laminated sheet for molding comprising: a film layer which comprises thermoplastic acrylic resin, wherein the film layer is one of transparent or translucent; an intermediate layer which comprises a curable resin including a polyisocyanate compound and an acrylic resin having hydroxyl groups, wherein the a curable resin is a cured material in a semi-cured state; and a decorative layer having a mirror-like metallic luster, which comprises a binder resin and fine metal grains obtained from a thin metal film; wherein the layers are laminated in the order stated.
128 Composite sheet with mirror finish US11234055 2005-09-23 US20060070699A1 2006-04-06 Darrell Sparks; Grant LaFontaine
A method for producing a polymer mirror by continuously manufacturing a polymeric substrate, applying a reflective layer or layers which may be a polymer whose surface has been metalized so as to make it reflective or a multi-layer film wherein the combined refractive indices of the layers give the quality of a mirror surface. An optional coating may be applied to a surface of the reflective layer to promote adhesion to the underlying substrate. A composite is formed by heat lamination using a calendar roll assembly to fuse the layers into a rigid final article having a reflective surface having the character of a silver mirror, a highly reflective mirror, or a colored mirror.
129 High durabel photocatalyst film and structure having surface exhibiting photocatalytic function US10522915 2003-07-30 US20050249943A1 2005-11-10 Ryouzo Nishikawa; Naoki Tanaka; Norihiro Nakayama
A high-durability photocatalyst film that is a laminated film comprising a substrate film and a photocatalytically active material layer formed thereon via a protective layer, wherein the substrate film is a film having specific performances in a weather resistance test with a sunshine weatherometer, the protective layer is an organic-inorganic composite graded film and the above laminated film exhibits specific performances in an accelerated weather resistance test with a sunshine weatherometer, and a structure having photocatalytic functions on a surface formed of the above photocatalyst film.
130 Thermally controlled solar reflector facet with heat recovery US10755969 2004-01-12 US20040139960A1 2004-07-22 James B. Blackmon JR.; Nelson Edwin Jones; Robert E. Drubka
A high concentration central receiver system and method provides improved reflectors and a unique heat removal system. The central receiver has a plurality of interconnected reflectors coupled to a tower structure at a predetermined height above ground for reflecting solar radiation. A plurality of concentrators are disposed between the reflectors and the ground such that the concentrators receive reflective solar radiation from the reflectors. The central receiver system further includes a heat removal system for removing heat from the reflectors and an area immediately adjacent the concentrators. Each reflector includes a mirror, a facet, and an adhesive compound. The adhesive compound is disposed between the mirror and the facet such that the mirror is fixed to the facet under a compressive stress.
131 Multilayer optical bodies US10215791 2002-08-09 US06744561B2 2004-06-01 Peter D. Condo; Timothy J. Hebrink; John A. Wheatley; Andrew J. Ouderkirk; Andrew T. Ruff; Yaoqi J. Liu; Milton H. Andrus, Jr.
Optical bodies, comprising: a plurality of first optical layers comprising a first polymer composition that comprises (i) a polyester portion having terephthalate comonomer units and ethylene glycol comonomer units, and (ii) a second portion corresponding to a polymer having a glass transition temperature of at least about 130° C.; and a plurality of second optical layers disposed in a repeating sequence with the plurality of first optical layers. Also disclosed are optical bodies comprising: (a) a plurality of first optical layers, each first optical layer being oriented; and (b) a plurality of second optical layers, disposed in a repeating sequence with the plurality of first optical layers, comprising a blend of polymethylmethacrylate and polyvinylidene fluoride. Methods of making the above-described optical bodies, and articles employing such optical bodies are also provided.
132 Optical film US10654348 2003-09-02 US20040043205A1 2004-03-04 James M. Jonza; Michael F. Weber; Andrew J. Ouderkirk; Carl A. Stover
Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth, can be achieved.
133 Modified copolyesters and improved multilayer reflective films US09996655 2001-11-28 US06641900B2 2003-11-04 Timothy J. Hebrink; William W. Merrill; Carl A. Stover
A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
134 Optical film US09962748 2001-09-25 US06613421B2 2003-09-02 James M. Jonza; Michael F. Weber; Andrew J. Ouderkirk; Carl A. Stover
Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, mirror films with high reflectivity in two different planes of polarization for any incident direction over a wide bandwidth can be achieved.
135 Multilayer optical bodies US10215791 2002-08-09 US20030053215A1 2003-03-20 Peter D. Condo; Timothy J. Hebrink; John A. Wheatley; Andrew J. Ouderkirk; Andrew T. Ruff; Yaoqi J. Liu; Milton H. Andrus JR.
Optical bodies, comprising: a plurality of first optical layers comprising a first polymer composition that comprises (i) a polyester portion having terephthalate comonomer units and ethylene glycol comonomer units, and (ii) a second portion corresponding to a polymer having a glass transition temperature of at least about 130null C.; and a plurality of second optical layers disposed in a repeating sequence with the plurality of first optical layers. Also disclosed are optical bodies comprising: (a) a plurality of first optical layers, each first optical layer being oriented; and (b) a plurality of second optical layers, disposed in a repeating sequence with the plurality of first optical layers, comprising a blend of polymethylmethacrylate and polyvinylidene fluoride. Methods of making the above-described optical bodies, and articles employing such optical bodies are also provided.
136 Modified copolyesters and improved multilayer reflective films US09996655 2001-11-28 US20020064671A1 2002-05-30 Timothy J. Hebrink; William W. Merrill; Carl A. Stover
A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
137 Optical film US09927982 2001-08-10 US20020061393A1 2002-05-23 James M. Jonza; Michael F. Weber; Andrew J. Ouderkirk; Carl A. Stover
Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth, can be achieved.
138 Modified copolyesters and improved multilayer reflective films US09232332 1999-01-15 US06352761B1 2002-03-05 Timothy J. Hebrink; William W. Merrill; Carl A. Stover
A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The second set of optical layers comprise copolyesters wherein 0.01 to 2.5 mol % of the combined carboxylate and glycol subunits are carboxylate subunits derived from compounds having three or more carboxylate or ester functionalities, glycol subunits derived from compounds having three or more hydroxyl functionalities, or combinations thereof. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
139 Optical film US09527452 2000-03-17 US06296927B1 2001-10-02 James M. Jonza; Michael F. Weber; Andrew J. Ouderkirk; Carl A. Stover
Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth, can be achieved.
140 重合性化合物を含む重合性組成物、フィルム、投映像表示用ハーフミラー、および重合性化合物 JP2016070209 2016-07-08 JPWO2017007007A1 2018-06-21 加藤 峻也; 中沢 佑起; 吉川 将
本発明は、
式(I):

式中、Aはフェニレン基またはトランス−1,4−シクロヘキシレン基を示し、Lは−OC(=O)−、−OC(=O)O−等を示し、mは3〜12を示し、Sp1、Sp2は連結基等を示し、Q1およびQ2は重合性基等を示す;で表される重合性化合物を少なくとも2種含み、トランス−1,4−シクロヘキシレン基の数をmで割った数をmcとしたとき、上記2種の重合性化合物のmcは互いに異なり、上記2種の重合性化合物の少なくとも1種が0.5 20161027 A16333 全文 3 式(I): 式中、 Aは、置換基を有していてもよいフェニレン基または置換基を有していてもよいトランス−1,4−シクロヘキシレン基を示し、 Lは単結合、−CH 2O−、−OCH 2−、−(CH 2) 2OC(=O)−、−C(=O)O(CH 2) 2−、−C(=O)O−、−OC(=O)−、−OC(=O)O−、−CH=CH−C(=O)O−、および−OC(=O)−CH=CH−からなる群から選択される連結基を示し、 mは3〜12の整数を示し、 Sp 1およびSp 2はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、および炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、 Q 1およびQ 2はそれぞれ独立に、原子または以下の式Q−1〜式Q−5で表される基からなる群から選択される重合性基を示し、ただしQ 1およびQ 2のいずれか一方は重合性基を示す; で表される重合性化合物を少なくとも2種含み、 Aで表される置換基を有していてもよいトランス−1,4−シクロヘキシレン基の数をmで割った数をmcとしたとき、前記2種の重合性化合物のmcは互いに異なり、前記2種の重合性化合物の少なくとも1種が0.5 (削除) 式(I)において、フェニレン基およびトランス−1,4−シクロヘキシレン基が有していてもよい前記置換基が、アルキル基、アルコキシ基、および−C(=O)−X 3−Sp 3−Q 3で表される基からなる群から選択され、ここで、X 3が単結合、−O−、−S−、もしくは−N(Sp 4−Q 4)−を示すか、または、Q 3およびSp 3と共に環構造を形成している窒素原子を示し、Sp 3およびSp 4はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、および炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、Q 3およびQ 4はそれぞれ独立に、水素原子、シクロアルキル基、シクロアルキル基において1つもしくは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、もしくは−C(=O)O−で置換された基、または式Q−1〜式Q−5で表される基からなる群から選択されるいずれかの重合性基を示す請求項1に記載の重合性組成物。 式(II)で表される部分構造を有する式(I)で表される化合物を少なくとも一種含む請求項1または3のいずれか一項に記載の重合性組成物; 式中、R 1、R 2はそれぞれ独立に、水素原子、アルキル基、アルコキシ基、および−C(=O)−X 3−Sp 3−Q 3で表される基からなる群から選択され、ここで、X 3が単結合、−O−、−S−、もしくは−N(Sp 4−Q 4)−を示すか、または、Q 3およびSp 3と共に環構造を形成している窒素原子を示し、Sp 3およびSp 4はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、Q 3およびQ 4はそれぞれ独立に、水素原子、シクロアルキル基、シクロアルキル基において1つもしくは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、もしくは−C(=O)O−で置換された基、または式Q−1〜式Q−5で表される基からなる群から選択されるいずれかの重合性基を示す。 R 1およびR 2がそれぞれ独立に、−C(=O)−X 3−Sp 3−Q 3であり、X 3が−O−である請求項4に記載の重合性組成物。 R 1およびR 2が同一である請求項4または5に記載の重合性組成物。 前記重合性化合物が、いずれも0.5 式(I)で表される化合物が式(V)で表される化合物であり; 式中、nn1およびnn2はそれぞれ独立に1または2の整数を示し、 前記2種の重合性化合物は互いにnn1+nn2で表される値が異なる請求項1、3〜7のいずれか一項に記載の重合性組成物。 架橋剤を含有する請求項1、3〜8のいずれか一項に記載の重合性組成物。 重合開始剤を含有する請求項1、3〜9のいずれか一項に記載の重合性組成物。 キラル化合物を含有する請求項1、3〜10のいずれか一項に記載の重合性組成物。 請求項1、3〜11のいずれか1項に記載の重合性組成物を硬化した層を含むフィルム。 請求項1、3〜11のいずれか1項に記載の重合性組成物を硬化した層を2層以上含むフィルム。 選択反射を示し、 前記選択反射の波長域の半値幅Δλと前記選択反射の中心波長λとの比であるΔλ/λが0.09以下である請求項12または13に記載のフィルム。 可視光を反射する請求項12〜14のいずれか一項に記載のフィルム。 請求項1、3〜11のいずれか一項に記載の重合性組成物を硬化した層を少なくとも3層含むフィルムであって、 前記3層が、赤色光波長域に選択反射の中心波長を有するコレステリック液晶相を固定した層、緑色光波長域に選択反射の中心波長を有するコレステリック液晶相を固定した層、および青色光波長域に選択反射の中心波長を有するコレステリック液晶相を固定した層であるフィルム。 請求項16に記載のフィルムを含む投映像表示用ハーフミラー。 無機ガラスまたはアクリル樹脂である基材を含む請求項17に記載の投映像表示用ハーフミラー。 最表面に反射防止層を含む請求項17または18に記載の投映像表示用ハーフミラー。 式(I): 式中、 Aは、置換基を有していてもよいフェニレン基または置換基を有していてもよいトランス−1,4−シクロヘキシレン基を示し、 Lは単結合、−CH 2O−、−OCH 2−、−(CH 2) 2OC(=O)−、−C(=O)O(CH 2) 2−、−C(=O)O−、−OC(=O)−、−OC(=O)O−、−CH=CH−C(=O)O−、および−OC(=O)−CH=CH−からなる群から選択される連結基を示し、 mは6〜12の整数を示し、 Aで表される置換基を有していてもよいトランス−1,4−シクロヘキシレン基の数をmで割った数をmcとしたとき、0.5 Sp 1およびSp 2はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、および炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、 Q 1およびQ 2はそれぞれ独立に、水素原子または以下の式Q−1〜式Q−5で表される基からなる群から選択される重合性基を示し、ただしQ 1およびQ 2のいずれか一方は重合性基を示す; で表される重合性化合物。 mが7または9である請求項20に記載の重合性化合物。 式(V)で表される請求項21に記載の重合性化合物; 式中、 Sp 1およびSp 2はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、および炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、 Q 1およびQ 2はそれぞれ独立に、水素原子または以下の式Q−1〜式Q−5で表される基からなる群から選択される重合性基を示し、ただしQ 1およびQ 2のいずれか一方は重合性基を示し; X 3は単結合、−O−、−S−、もしくは−N(Sp 4−Q 4)−を示すか、または、Q 3およびSp 3と共に環構造を形成している窒素原子を示し、Sp 3およびSp 4はそれぞれ独立に、単結合、炭素数1から20の直鎖もしくは分岐のアルキレン基、および炭素数1から20の直鎖もしくは分岐のアルキレン基において1つまたは2つ以上の−CH 2−が−O−、−S−、−NH−、−N(CH 3)−、−C(=O)−、−OC(=O)−、または−C(=O)O−で置換された基からなる群から選択される連結基を示し、Q 3およびQ 4はそれぞれ独立に、水素原子、シクロアルキル基、シクロアルキル基において1つもしくは2つ以上の−CH 2−が−O−、−S−、−NH、−N(CH 3)−、−C(=O)−、−OC(=O)−、もしくは−C(=O)O−で置換された基、または式Q−1〜式Q−5で表される基からなる群から選択されるいずれかの重合性基を示し、 nn1およびnn2はそれぞれ独立に1または2の整数を示し、nn1+nn2は3または4である。 A16330 0060 3 【0060】
を用いて測定した膜厚(d)は1.52mであり、位相差(Re)と膜厚(d)の比から算出した波長550nmにおけるΔn(Re/d)は0.043であった。
[0162]
上記重合性組成物塗布液(1)の重合性化合物(化合物1−3および化合物1−20)につき、下記表に示すように変更した以外は実施例1と同様にして、実施例2、5〜6、参考例および比較例1の位相差膜を作製した。また、上記液晶性組成物塗布液(1)の代わりに上記の組成の液晶性組成物塗布液(3)および液晶性組成物塗布液(4)を用いた以外は実施例1と同様にして、実施例3および4の位相差膜をそれぞれ作製した。作製した実施例2〜6、参考例および比較例1の位相差膜それぞれについて、実施例1と同様に、位相差と膜厚を測定し、さらにΔnを算出した。結果を表2に示す。なお、比較例1は塗布後に重合するまでの間に、結晶の析出が見られた。
[0163]
[表2]
[0164]
<選択反射フィルム(101)の形成>
上記で合成した例示化合物を用いて、下記の組成の液晶性組成物塗布液(101)を調製した。
塗布液(101)
液晶組成物(Ml−1) 100質量部
キラル剤 LC−756(BASF社製) 5.5質量部
空気界面配向剤(A) 0.02質量部 (51)Int.Cl. FI テーマコード(参考)
C07C 69/86 (2006.01) C07C 69/86
B32B 7/02 (2006.01) B32B 7/02 103

(81)指定国 AP(BW,GH,GM,KE,LR,LS,MW,MZ,NA,RW,SD,SL,ST,SZ,TZ,UG,ZM,ZW),EA(AM,AZ,BY,KG,KZ,RU,T
J,TM),EP(AL,AT,BE,BG,CH,CY,CZ,DE,DK,EE,ES,FI,FR,GB,GR,HR,HU,IE,IS,IT,LT,LU,LV,MC,MK,MT,NL,NO,PL,PT,R
O,RS,SE,SI,SK,SM,TR),OA(BF,BJ,CF,CG,CI,CM,GA,GN,GQ,GW,KM,ML,MR,NE,SN,TD,TG),AE,AG,AL,AM,AO,AT,AU,AZ,
BA,BB,BG,BH,BN,BR,BW,BY,BZ,CA,CH,CL,CN,CO,CR,CU,CZ,DE,DK,DM,DO,DZ,EC,EE,EG,ES,FI,GB,GD,GE,GH,GM,GT,H
N,HR,HU,ID,IL,IN,IR,IS,JP,KE,KG,KN,KP,KR,KZ,LA,LC,LK,LR,LS,LU,LY,MA,MD,ME,MG,MK,MN,MW,MX,MY,MZ,NA,NG
,NI,NO,NZ,OM,PA,PE,PG,PH,PL,PT,QA,RO,RS,RU,RW,SA,SC,SD,SE,SG,SK,SL,SM,ST,SV,SY,TH,TJ,TM,TN,TR,TT,TZ,
UA,UG,US

Fターム(参考) 4F100 AG00A AK25A AL05B AL05C AL05D AS00B AS00C AS00D AT00A BA02
BA03 BA04 BA05 BA07 GB41 GB90 JB12B JB12C JB12D JN06
JN06B JN06C JN06D JN06E JN30
4H006 AA01 AB46 BJ20 BJ50 BP10 KC14 KC20 KC30 KE10
4J005 AA07
4J036 AA01 AA05 AD11 AD12 JA15
4J100 AL08P AL66Q AL66R BA04Q BA04R BA15P BA15Q BA15R BC04P BC04Q
BC04R BC43P BC43Q BC43R CA04 CA05 DA62 DA63 FA03 FA19
JA39

(注)この公表は、国際事務局(WIPO)により国際公開された公報を基に作成したものである。なおこの公表に
係る日本語特許出願(日本語実用新案登録出願)の国際公開の効果は、特許法第184条の10第1項(実用新案法
第48条の13第2項)により生ずるものであり、本掲載とは関係ありません。
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