序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 单丝增强的中空纤维膜和制备该膜的方法 CN201280020347.1 2012-04-25 CN103501882B 2016-08-31 徐彰敏; 李景模
为了解决现有技术中出现的由具有复丝的中空纤维膜中须毛或细毛造成的损坏问题,本发明提供了进一步改善的中空纤维膜,其中螺旋制备了使用单丝的稀松型管状编织物且所得编织物埋置在聚合物树脂中。该稀松型管状编织物的特征在于,该编织物由各个单丝以固定度编织,以便形成菱形或方形。该单丝在增塑的线缆上编织以形成上述编织物,用于上述中空纤维膜的聚合物涂料被涂布在该编织物上使得编织物埋置在聚合物中,然后涂料凝固。这里,增塑的线缆决定了中空纤维膜的内径。如上所述,其中埋置稀松型编织物的中空纤维膜在纵向可扩展(可扩张),在径向也可扩展,从而实现双轴扩展。也就是,上述中空纤维膜在径向以及纵向都是柔性的。由于径向的柔性,中空纤维膜可在较高的压反冲洗,而使用复丝制成的膜不行,使用复丝制成的膜在径向几乎不可扩展。因此,本发明的生产效率提高了。
2 单丝增强的中空纤维膜和制备该膜的方法 CN201280020347.1 2012-04-25 CN103501882A 2014-01-08 徐彰敏; 李景模
为了解决现有技术中出现的由具有复丝的中空纤维膜中须毛或细毛造成的损坏问题,本发明提供了进一步改善的中空纤维膜,其中螺旋制备了使用单丝的稀松型管状编织物且所得编织物埋置在聚合物树脂中。该稀松型管状编织物的特征在于,该编织物由各个单丝以固定度编织,以便形成菱形或方形。该单丝在增塑的线缆上编织以形成上述编织物,用于上述中空纤维膜的聚合物涂料被涂布在该编织物上使得编织物埋置在聚合物中,然后涂料凝固。这里,增塑的线缆决定了中空纤维膜的内径。如上所述,其中埋置稀松型编织物的中空纤维膜在纵向可扩展(可扩张),在径向也可扩展,从而实现双轴扩展。也就是,上述中空纤维膜在径向以及纵向都是柔性的。由于径向的柔性,中空纤维膜可在较高的压反冲洗,而使用复丝制成的膜不行,使用复丝制成的膜在径向几乎不可扩展。因此,本发明的生产效率提高了。
3 单丝增强的中空纤维 CN201180070173.5 2011-12-22 CN103501881B 2016-10-12 徐彰敏; 李景模
通过埋置仅具有单丝的螺旋稀松编织的编织物形成中空纤维膜,以避免在现有技术复丝编织物支撑的管状膜中常见的“须状物”问题。所述稀松编织的特征为被单丝分开的聚合物膜的连续的、圆周的、菱形的区域。当在增塑的PVA线缆上支撑所述编织物时,可用膜聚合物渗透,当凝固物埋置在编织物内时,将其放置于内腔的周围。当埋置在膜内时,不含任何圆周收缩的单丝的螺旋的编织物允许膜双轴地扩张。换句话说,膜不仅在轴向或纵向而且在径向具有“弹性”。在径向的“弹性”允许在比不是径向扩张的可比较的编织物的更高的压反冲洗污染的膜。
4 单丝增强的中空纤维 CN201180070173.5 2011-12-22 CN103501881A 2014-01-08 徐彰敏; 李景模
通过埋置仅具有单丝的螺旋稀松编织的编织物形成中空纤维膜,以避免在现有技术复丝编织物支撑的管状膜中常见的“须状物”问题。所述稀松编织的特征为被单丝分开的聚合物膜的连续的、圆周的、菱形的区域。当在增塑的PVA线缆上支撑所述编织物时,可用膜聚合物渗透,当凝固物埋置在编织物内时,将其放置于内腔的周围。当埋置在膜内时,不含任何圆周收缩的单丝的螺旋的编织物允许膜双轴地扩张。换句话说,膜不仅在轴向或纵向而且在径向具有“弹性”。在径向的“弹性”允许在比不是径向扩张的可比较的编织物的更高的压反冲洗污染的膜。
5 Monofilament-reinforced hollow fiber membrane US14331100 2014-07-14 US09561475B2 2017-02-07 Chang Min Seo; Gyeong Mo Lee
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
6 Monofilament-reinforced hollow fiber membrane with scalloped lumen US13659648 2012-10-24 US10046281B2 2018-08-14 Chang Min Seo; Gyeong Mo Lee
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilament. When the braid is supported on a plasticized PVA cable having a scalloped periphery, the braid can be infiltrated with membrane polymer which, when coagulated, embeds the braid positioning it around the lumen. The embedded spiral weave, free of any circumferentially constricting monofilament, allows the membrane to be biaxially distensible. The membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
7 MONOFILAMENT-REINFORCED HOLLOW FIBER MEMBRANE US14331100 2014-07-14 US20140339153A1 2014-11-20 Chang Min Seo; Gyeong Mo Lee
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
8 Monofilament-reinforced hollow fiber membrane US13338557 2011-12-28 US08827085B2 2014-09-09 Chang Min Seo; Gyeong Mo Lee
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
9 Monofilament-Reinforced Hollow Fiber Membrane with Scalloped Lumen US13659648 2012-10-24 US20130112614A1 2013-05-09 CHANG MIN SEO; GYEONG MO LEE
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable having a scalloped periphery, the braid can be infiltrated with membrane polymer which, when coagulated, embeds the braid positioning it around the lumen.The embedded spiral weave, free of any circumferentially constricting monofilament, allows the membrane to be biaxially distensible. The membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
10 MONOFILAMENT-REINFORCED HOLLOW FIBER MEMBRANE US13338557 2011-12-28 US20120273409A1 2012-11-01 Chang Min SEO; Gyeong Mo LEE; Kwon Il KIM
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a “whiskering” problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has “give” not only in the axial or longitudinal direction but also in the radial direction. “Give” in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
11 HOLLOW FIBER MEMBRANE HAVING A REINFORCED MONOFILAMENT EP11864288 2011-12-22 EP2703067A4 2015-03-25 SEO CHANG-MIN; LEE GYEONG-MO
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a "whiskering" problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by mono filaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has "give" not only in the axial or longitudinal direction but also in the radial direction. "Give" in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
12 HOLLOW FIBER MEMBRANE HAVING A REINFORCED MONOFILAMENT EP11864288.3 2011-12-22 EP2703067A1 2014-03-05 SEO, Chang-Min; LEE, Gyeong-Mo

A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a "whiskering" problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by monofilaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has "give" not only in the axial or longitudinal direction but also in the radial direction. "Give" in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.

13 HOLLOW FIBER MEMBRANE REINFORCED WITH MONOFILAMENTS, AND METHOD FOR MANUFACTURING SAME EP12777115 2012-04-25 EP2703069A4 2015-03-25 SEO CHANG MIN; LEE GYEONG MO
A hollow fiber membrane is formed by embedding a braid having a spiral open weave of monofilaments only, to avoid a "whiskering" problem common in prior art multifilament braid-supported tubular membranes. The open weave is characterized by contiguous, circumferential, rhomboid-shaped areas of polymer film separated by mono filaments. When the braid is supported on a plasticized PVA cable it can be infiltrated with membrane polymer which, when coagulated embeds the braid positioning it around the lumen. The spiral weave, free of any circumferentially constricting monofilament, when embedded in film, allows the membrane to be biaxially distensible. In other words, the membrane has "give" not only in the axial or longitudinal direction but also in the radial direction. "Give" in the radial direction permits soiled membranes to be backwashed under higher pressure than in a comparable braid which is not radially distensible.
14 모노필라멘트가 보강된 중공사 멤브레인 및 그 제조방법 KR1020110134597 2011-12-14 KR101185424B1 2012-10-08 서창민; 이경모
PURPOSE: A monofilament-reinforced hollow fiber membrane and a manufacturing method of the same are provided to prevent a tubular-shaped knitted product from being contaminated with permeated contaminants. CONSTITUTION: A hollow fiber membrane is a reinforced hollow fiber membrane. The inner diameter of the hollow fiber membrane is formed by embedding knitted shaped mono-filaments(12) into a tubular polymer film. A knitted product(10) is obtained. 6-24 mono-filaments of 25-250 deniers are spirally braided in the knitted product to ensure a rhomboid or diamond shaped-open region. The braided angle of the knitted product is maintained in a range between 20 and 60 degrees to the longitudinal direction. The thickness of the polymer film is in a range between 0.2 and 0.6mm.
15 모노필라멘트가 보강된 중공사 멤브레인 및 그 제조방법 KR1020120043047 2012-04-25 KR101179687B1 2012-09-04 서창민; 이경모
PURPOSE: A hollow fiber membrane based on enhanced mono-filaments and a method for manufacturing the same are provided to improve the adhesive and the durability of a hollow fiber membrane and to overcome leakage failure. CONSTITUTION: A hollow fiber membrane includes a tubular polymer film and mono-filaments(12) which are inserted into the tubular polymer film. The mono-filaments are in the form of knitted products. The mono-filaments of 25-250 deniers are braided to secure a long radial shaped region or a diamond shaped region. 6-24 mono-filaments are spirally braided, and the braided angles of the mono-filaments to the longitudinal direction are in a range between 20 and 60 degrees.
16 HOLLOW FIBER MEMBRANE REINFORCED WITH MONOFILAMENTS, AND METHOD FOR MANUFACTURING SAME PCT/KR2012003189 2012-04-25 WO2012148168A3 2013-03-28 SEO CHANG MIN; LEE GYEONG MO
In order to solve problems of damage due to fibrils or lint in a hollow fiber membrane having multifilaments that arise in the prior art, the present invention provides a further improved hollow fiber membrane in which an open-type tubular knitwork using monofilaments is spirally manufactured and the resultant knitwork is embedded into a polymer resin. The open-type tubular knitwork is characterized in that it is weaved at a fixed angle by each monofilament so as to form either a rhomboid or a diamond shape. The monofilaments are weaved onto a plasticized cable to form the knitwork, and a polymer dope for the hollow fiber membrane is coated on the knitwork, such that the knitwork is embedded into the polymer, and then the dope is coagulated. Here, the plasticized cable determines the inner diameter of the hollow fiber membrane. The hollow fiber membrane, in which the open-type knitwork is embedded as described above, is expandable (extendable) in a longitudinal direction and is expandable in a radial direction, thereby enabling biaxial expansion. That is, the hollow fiber membrane is flexible in the radial direction as well as in the longitudinal direction. Due to the flexibility in the radial direction, the hollow fiber membrane can be backwashed at a higher pressure than can a hollow fiber membrane made using multifilaments, which is hardly expandable in the radial direction. Thus, manufacturing efficiency is improved.
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