| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 由过氧化钛凝胶去除有机染料和有机污染物 | CN201080033973.5 | 2010-07-30 | CN102481466B | 2014-07-30 | 莫汉·柯巴·东伽尔; 舒巴吉·巴查卓·恩姆巴卡 |
| 本发明揭示了从溶液中去除发色物质/染料/有机污染物的一步式方法，该方法包括不含多聚物的过氧化钛凝胶，也就是具有高Z电势的过氧化钛凝胶。发色物质被去除的浓度高达95-100%。 | ||||||
| 2 | 一种氧化方法 | CN96197605.5 | 1996-10-03 | CN1199350A | 1998-11-18 | D·F·斯特勒 |
| 将电化学再生的RuO4(或Os、Ir、Rh的相应氧化物)用于物质、特别是含有有机物的物质的分解。在处理含有氯的化合物时该方法具有特别的优点。此外,该方法还提供了杂原子N、Cl、P、As、S的去除方法,避免被未氧化的有机物和/或Ru(或Os、Ir、Rh,视情况而定)所污染。 | ||||||
| 3 | 由过氧化钛凝胶去除有机染料和有机污染物 | CN201080033973.5 | 2010-07-30 | CN102481466A | 2012-05-30 | 莫汉·柯巴·东伽尔; 舒巴吉·巴查卓·恩姆巴卡 |
| 本发明揭示了从溶液中去除发色物质/染料/有机污染物的一步式方法，该方法包括不含多聚物的过氧化钛凝胶，也就是具有高Z电势的过氧化钛凝胶。发色物质被去除的浓度高达95-100%。 | ||||||
| 4 | 含卤素、磷、硫和/或金属元素的有机化合物的处理方法 | CN96103916.7 | 1996-03-07 | CN1136971A | 1996-12-04 | E·布泽兹基 |
| 为处理在原子键上除了碳、氢和氧元素外，还包括卤素、磷、硫和/或金属元素的危险或有毒有机化合物，提出了使该有机化合物电离，紧接着进行电渗析的方法，此离子态的最终反应产物可容易操作，并且可毫无问题地进一步使用或以填埋或焚烧方式处理。在电离辐射作用下发生电离。本发明方法特别适合处理含卤素的芳族化合物如各种农药。 | ||||||
| 5 | Removal of organic dyes and organic pollutants by titanium peroxide gel | US13387842 | 2010-07-30 | US09149673B2 | 2015-10-06 | Mohan Kerba Dongare; Shubhangi Bhalchandra Umbarkar |
| The one step process of removal of chromophore/dye/organic pollutant from a solution comprising a polymer free titanium oxide gel i.e. high zeta potential is disclosed. The concentration of the chromophores is removed up to 95-100%. | ||||||
| 6 | Process for the destruction of sulfur and nitrogen mustards, lewisite, and their homologous/analogues in deep eutectic solvents | US12078012 | 2008-03-26 | US08420881B2 | 2013-04-16 | Inas Muen Al Nashef; Saeed M. Al Zahrani |
| The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents. | ||||||
| 7 | Process for the destruction of sulfur and nitrogen mustards and their homologous/analogous at ambient conditions | US12078001 | 2008-03-26 | US20120149963A1 | 2012-06-14 | Inas Muen Al Nashef; Saeed M. Al Zahrani |
| The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in ionic liquids or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in ionic liquids. | ||||||
| 8 | PROCESS AND APPARATUS FOR CHEMICAL CONVERSION | US11841813 | 2007-08-20 | US20080035469A1 | 2008-02-14 | Wayne Conrad; Richard Phillips; Andrew Phillips; Helmut Conrad |
| A process and reactor for chemical conversion is taught. The process allows the selective breaking of chemical bonds in a molecule by use of fast rise alternating current or fast rise pulsed direct current, each fast rise portion being selected to have a suitable voltage and frequency to break a selected chemical bond in a molecule. The reactor for carrying out such a process includes a chamber for containing the molecule and a generator for generating and applying the selected fast rise current. | ||||||
| 9 | Process and apparatus for chemical conversion | US11327308 | 2006-01-09 | US20060118404A1 | 2006-06-08 | Wayne Conrad; Richard Phillips; Andrew Phillips; Helmut Conrad |
| A process and reactor for chemical conversion is taught. The process allows the selective breaking of chemical bonds in a molecule by use of fast rise alternating current or fast rise pulsed direct current, each fast rise portion being selected to have a suitable voltage and frequency to break a selected chemical bond in a molecule. The reactor for carrying out such a process includes a chamber for containing the molecule and a generator for generating and applying the selected fast rise current. | ||||||
| 10 | Mediated electrochemical oxidation of organic waste materials | US10493500 | 2004-08-04 | US20040256247A1 | 2004-12-23 | Roger W. Carson; Bruce W. Bremer |
| A mediated electrochemical oxidation process is used to treat and destroy organic waste materials. The materials are introduced into an apparatus containing an electrolyte having the oxidized form of one or more redox couples. The oxidized couples oxidize the organic waste materials and are converted into their reduced form. The reduced forms are reoxidized by electrochemical anodic oxidation in the anode compartment of an electrochemical cell or reaction with the oxidized form of other redox couples. The redox cycle continues until the desired degree of oxidation is reached. The process takes place at temperatures between ambient and approximately 100null C., to avoid the formation of dioxins or furans. The oxidation process may be enhanced by the addition of reaction enhancements, such as: ultrasonic energy and/or ultraviolet radiation. | ||||||
| 11 | Electrochemical system and method for rendering contaminated electrically conductive material nonhazardous | US09736962 | 2000-12-14 | US06486376B2 | 2002-11-26 | J. Kenneth Wittle; Christy W. Bell |
| An electrokinetic method is disclosed for treating an electrically conductive material including hazardous contaminants, e.g. spent pot liner (SPL), to render such material non-hazardous. | ||||||
| 12 | Process for breaking chemical bonds | US08336242 | 1994-11-07 | US06309514B1 | 2001-10-30 | Wayne Ernest Conrad; Richard Stanley Phillips; Andrew Richard Henry Phillips; Helmut Gerhard Conrad |
| A process and reactor for chemical conversion is taught. The process allows the selective breaking of chemical bonds in a molecule by use of fast rise alternating current or fast rise pulsed direct current, each fast rise portion being selected to have a suitable voltage and frequency to break a selected chemical bond in a molecule. The reactor for carrying out such a process includes a chamber for containing the molecule and a generator for generating and applying the selected fast rise current. | ||||||
| 13 | Munitions treatment by acid digestion | US879539 | 1997-06-20 | US6011193A | 2000-01-04 | Craig A. Myler; Martin E. Toomajian; Monte R. Elmore; Evan O. Jones; Alan H. Zacher |
| A treatment method for containers of hazardous materials, including chemical and conventional weapons, is described. The method is applicable to munitions containing explosives and chemical warfare agents, and to training or test rounds. The containers are subjected to a highly corrosive fluid which dissolves all or part of the container and renders the containers useless as munitions. The highly corrosive fluid may render the hazardous material non-hazardous. The result of the treatment is a liquor which can undergo further treatment for recovery or disposal. | ||||||
| 14 | Method of oxidation | US29086 | 1998-02-19 | US5952542A | 1999-09-14 | David Frame Steele |
| Electrochemically regenerated RuO.sub.4 (or corresponding oxides of Os, Ir, Rh) is used in the decomposition of matter, especially matter containing organic material. The method has particular advantage in dealing with compounds containing chlorine and, in a development, provides for the removal of heteroatoms N, Cl P, As, S, avoiding contamination with unoxidised organics and/or Ru (or Os, Ir, Rh as the case may be). | ||||||
| 15 | Mediated electrochemical oxidation of organic wastes using a Co (III) mediator in a nitric acid based system | US986476 | 1997-12-08 | US5911868A | 1999-06-15 | G. Bryan Balazs; Zoher Chiba; Patricia R. Lewis; Norvell Nelson; G. Anthony Steward |
| An electrochemical cell with a Co(III) mediator and nitric acid electrolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the mediator oxidizes the organics and insoluble transuranic compounds and is regenerated at the anode until the organics are converted to CO.sub.2. The nitric acid is an excellent oxidant that facilitates the destruction of the organic components. The anode is not readily attacked by the nitric acid solution, thus the cell can be used for extended continual operation without electrode replacement. | ||||||
| 16 | Method and device for treating an aqueous solution | US768475 | 1996-12-18 | US5766447A | 1998-06-16 | Yves L. M. Creijghton |
| The invention relates to a method and a device for treating an aqueous solution, in which a pulsed electric field is generated in the aqueous solution between two electrodes. In accordance with the invention, at least one of the electrodes is covered with a layer of a dielectric material which, during operation of the device, completely separates this (these) electrode(s) from the aqueous solution. This measure in accordance with the invention enables field strengths to be used which are much higher than those permissible in the known devices. The use of an oxygen-containing gas and a bipolarly pulsed electric field leads to a further improvement of the method in accordance with the invention. | ||||||
| 17 | Degradation of halogenated carbon compounds | US221077 | 1980-12-29 | US4410402A | 1983-10-18 | Donald T. Sawyer; Julian L. Roberts, Jr. |
| Halogenated carbon compounds containing at least three halogen atoms and capable of undergoing bimolecular nucleophilic substitution are degraded by reaction in an aprotic solvent with a strong nucleophile selected from superoxide ion and hydroxide ion. The process is particularly applicable to compounds in which at least three halogen atoms are covalently joined to a tetrahedral carbon atom. In a specific embodiment, superoxide ion is electrolytically generated in an aprotic solvent containing a soluble organic electrolyte. In a further embodiment, the aprotic solvent is dimethyl sulfoxide, which, when converting carbon tetrahalide, forms dimethylsulfone and carbonate. | ||||||
| 18 | フッ素系有機化合物の分解方法、及びフッ素系有機化合物の分解装置 | JP2014083193 | 2014-04-14 | JP6284188B2 | 2018-02-28 | 堀 久男; 加藤 昌明 |
| 19 | Apparatus and method for oxidizing organic materials | JP53743397 | 1997-04-18 | JP2000512538A | 2000-09-26 | ゲッティング，ジョン・ジー・エイチ; スーマ，ジェフリー・イー; バットナー，アール・スコット; ブライアン，ゲイリー・エイチ |
| (57)【要約】 本発明は、電気化学セルのアノード液の中に高いセリウム濃度を用いることにより有機物質を酸化させる方法及び装置である。 本方法及び装置は、更に、超音波ミキサを用いて、電気化学セルの中の有機物質の酸化速度を高める。 | ||||||
| 20 | The method for decomposing a Cmpo | JP6432597 | 1997-03-18 | JP3080596B2 | 2000-08-28 | 正基 小沢; 剛陸 岸; 知佐子 川上; 吉廣 星野; 康正 田中; 宏之 田沼 |
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