序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
121 Temporary support film for transferring white pigment layer US850115 1997-05-01 US5800962A 1998-09-01 Martin Benzing; Dieter Mohr; Juergen Mertes; Peter Blum
A process for the production of a color image is described, in which a photosensitive material that has a temporary support film, a colored photosensitive layer and an adhesion-promoting layer that can be activated by heat is laminated at high temperature and under pressure with an image-receiving material which carries, on a support, a pigment layer containing a white pigment. The photosensitive layer is exposed imagewise and developed to produce an image, the temporary support film is peeled off from the image-receiving material before or after exposure to light and, if required, these steps are repeated with at least one further photosensitive material whose colored layer has another color to produce a multi-colored image. The process gives color images having a smaller dot enlargement compared with a halftone original and is particularly suitable for the color testing of copy for multicolor printing.
122 Laminable proofing elements US594162 1996-01-31 US5776651A 1998-07-07 Ying-Yuh Lu; Bruce W. Weeks; Paul J. Wang
This application discloses a core/shell latex thermal adhesive comprising a thermally softenable polymeric shell having a Tg of greater than 20.degree.C., and a thermally softenable, crosslinked polymeric core having a Tg of less than 20.degree. C., the difference between the Tg of the core and the shell being at least 10.degree.C. This application also discloses a thermally activated adhesive composition comprising: a) from about 50 to 100 parts of a transparent film-forming core/shell latex polymer, wherein the ratio of core to shell of said core/shell latex polymer ranges from about 20/80 to about 80/20,the shell having a Tg above 20.degree. C. and the core having a Tg below 20.degree. C. with the core having a Tg lower than the Tg of the shell by at least 10.degree. C.; b) from about 0 to about 15 parts inorganic, wax or polymeric particles; c) from zero to about fifteen percent of optical brightening agents; d) from zero to fifteen percent ultraviolet radiation absorbers; e) and from 0 to 40% by weight non-core-shell polymeric latex, the total of b), c), d), and e) being less than fifty percent.
123 Color proofing article incorporating novel antihalation dye US601625 1996-02-14 US5756257A 1998-05-26 Kevin D. Landgrebe; Alice S. Mendelsohn
The present invention provides a photosensitive color proofing article incorporating an antihalation effective amount of one or more antihalation dyes of the general formula (I) shown below: ##STR1## wherein: Z is an oxygen atom, NH, or NR; R is an alkyl group of 1 to 12 carbon atoms or a hydrogen atom; R.sup.1 represents a perfluoroalkylsulfonyl group of 1 to 12 carbon atoms or an arylsulfonyl group; and R.sup.2 represents a perfluoroalkylsulfonyl group of from 1 to 12 carbon atoms; an arylsulfonyl group; or a cyano group. The antihalation dyes of formula (I) absorb radiation within the wavelength range of from about 325 to 700 nm and preferably, from about 325 to 450 nm.
124 Solid transfer negative- or positive-working color proofing element US163214 1993-12-07 US5725988A 1998-03-10 Stephan J. W. Platzer
This invention provides an improved negative-working or positive-working, single sheet color proofing method which can accurately reproduce images by using colored, photosensitive layers on substrates which are then overcoated with partially developable adhesive layers. The final construction is useful in predicting the image quality from a lithographic printing process. The partial removal of the adhesive layers cleans out any background stain which may remain from the incomplete removal of the photosensitive layer.
125 Color image forming process through transfer of image portion to receiving material, via cushion layer US665005 1996-05-15 US5723256A 1998-03-03 Tetsuya Taniguchi; Kiyoshi Goto; Takeo Akiyama; Miyuki Hosoi; Tetsuya Masuda; Hideaki Mochizuki
Disclosed is a color image-formable material for forming and transferring a color image. The color image-formable material has a support, a cushion layer provided on the support and color light-sensitive layer containing a light-sensitive composition and a coloring agent provided on the cushion layer. It gives a transferred image by forming a color image portion by imagewise exposure and developing treatment and then transferring the color image portion alone to an image-receiving material. The cushion layer has a hardness of 40 to 85 and a thickness of 15 .mu.m to 100 .mu.m. A process for preparation of the color image-formable material is also disclosed.
126 Image-receiving material for production of a color image utilizing a transferred white pigment layer US641263 1996-04-30 US5705315A 1998-01-06 Martin Benzing; Dieter Mohr; Juergen Mertes; Peter Blum
A process for the production of a color image is described, in which a photosensitive material that has a temporary support film, a colored photosensitive layer and an adhesion-promoting layer that can be activated by heat is laminated at high temperature and under pressure with an image-receiving material which carries, on a support, a pigment layer containing a white pigment. The photosensitive layer is exposed imagewise and developed to produce an image, the temporary support film is peeled off from the image-receiving material before or after exposure to light and, if required, these steps are repeated with at least one further photosensitive material whose colored layer has another color to produce a multi-colored image. The process gives color images having a smaller dot enlargement compared with a halftone original and is particularly suitable for the color testing of copy for multicolor printing.
127 Photosensitive material and production of metal-colored images utilizing pearl luster pigment US344427 1994-11-23 US5637438A 1997-06-10 Karin Maerz; Silvia Neumann; Dieter Mohr
Described is a photosensitive material for producing metal-colored images, comprisingA) a flexible transparent plastic support film,B) a photosensitive layer comprising a polymeric binder, a photosensitive substance and a pearl luster pigment, and optionallyC) a thermoplastic adhesion-promoting layer.The material of the invention makes it possible to produce color-proofing images for metal-colored multicolor prints by combining metal-colored single-color images with single-color images in the usual primary colors as desired.
128 Providing imagewise variation in glossiness to a receptor US429928 1995-04-27 US5633117A 1997-05-27 Hamid Barjesteh; Michael B. Heller
This invention is a surface modifying element comprising a photosensitive layer on one side of a carrier substrate. The photosensitive layer comprises a photosensitive binder material and particulates. The invention is also a method of using the surface modifying element to create a receiver having imagewise variation in glossiness.
129 Imaged element utilizing a transfer process and a non-photosensitive/photosensitive combination for forming the colored image US443501 1995-05-18 US5616439A 1997-04-01 Gregory A. Bodager; Phillip L. Beighle
The invention relates to an imaged element comprising(1) a carrier element having a release surface wherein the carrier element is resistant to aqueous development; (2) a first adhesive layer; (3) a first colored pattern, resulting from the imagewise exposure and washout development of a first unpigmented, photosensitive layer comprising an aqueous liquid developable photosensitive composition and at least one overlying acqueous permeable colorant-containing composition; (4) and a transfer element having a release surface. There is an adhesion force F1, F2 and F3 between the various layers wherein each of F2 and F3 is greater than F1 and F2 is greater than F3.
130 Process for forming a colored image US100222 1993-08-02 US5565301A 1996-10-15 Gregory A. Bodager
A process for forming a colored image comprising, in order:(A) imagewise exposing to actinic radiation a photosensitive element comprising a carrier support, a carrier surface, a first adhesive layer and a first photosensitive layer,(B) developing the exposed first photosensitive layer,(C) laminating to the element a transfer element comprising a transfer support, and a transfer surface layer which is adjacent to a colored pattern in the element of step (A) with the proviso that the transfer element does not have an adhesive layer which transfers to the colored pattern,(D) removing said carrier support and said carrier surface, revealing said first adhesive layer,(E) laminating the element the element from step (D) to a permanent support wherein the first adhesive layer is adjacent to the permanent support; and(F) removing said transfer support and said transfer surface layer.
131 Peel-apart process for the production of a colored image and imaged product produced through the process US424800 1995-04-19 US5534373A 1996-07-09 Stephan J. W. Platzer; Andrea Buchmann; Gerhard Buhr
A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.1 ') of the exposed photosensitive layer (B) to the adhesion-promoting layer (C) and than the cohesions of the adhesion-promoting layer (C) and of the exposed photosensitive layer (B) is useful for the production of a colored image, in particular, is useful in a color proofing method for multicolor printing, which process gives images having high resolution.
132 Aqueous alkaline developing solution US201693 1994-02-25 US5532116A 1996-07-02 Tamotsu Suzuki; Mikio Totsuka; Chiyomi Niitsu; Fumiaki Shinozaki
An aqueous alkaline developing solution comprises an alkali compound, water and an alkylnaphthalene sulfonate having the following formula: ##STR1## in which R represents an alkyl group of 3 to 5 carbon atoms and q is 0 or an integer of 1 to 3, in the amount of 1 to 20 weight %. The aqueous alkaline developing solution further contains an anionic surface active agent of the specific sulfonate compound having a naphthalene ring and a polypolyoxyethylene moiety, in the amount of 0.1 to 10 weight % and an nonionic surface active agent having a polyoxyethylene moiety and an aromatic ring in its structure in the amount of 0.03 to 3 weight %, or contains an anionic surface active agent of the specific sulfonate compound having the specific aralkyl-substituted benzene ring and a polypolyoxyethylene moiety.
133 Process for forming a colored image utilizing a non-photosensitive/photosensitive combination US315738 1994-09-30 US5532115A 1996-07-02 Gregory A. Bodager; Phillip L. Beighle
A process for forming a colored image comprising, in order: (a) applying at least one aqueous permeable colorant-containing composition to a photosensitive element comprising a permanent carrier element having a carrier surface, and an unpigmented, first photosensitive layer consisting essentially of an aqueous liquid developable photosensitive composition, wherein the aqueous permeable colorant-containing composition is applied to the unpigmented, first photosensitive layer; (b) imagewise exposing to actinic radiation the photosensitive element having applied thereon the permeable colorant-containing composition to form imagewise exposed and unexposed regions in the unpigmented, first photosensitive layer and the overlying permeable colorant-containing composition; and (c) developing the exposed element by washing with an aqueous liquid, thereby removing either the imagewise exposed or imagewise unexposed regions, to produce a first colored pattern is described.
134 Reactive polymeric dyes US334202 1994-11-04 US5532111A 1996-07-02 Gary L. Holmes; Terrance P. Smith; Mahfuza B. Ali; David W. Macomber
Reactive polymeric dyes are provided comprising a chromophoric moiety derived from at least one free radically polymerizable dye and an azlactone moiety derived from 2-alkenylazlactone such that the free radically polymerizable dye is incorporated into the backbone of the polymer. Alternatively, 2-alkenylazlactone is polymerized and then derivatized with a nucleophilic dye or dyes, such that the chromophoric portion of the dye is pendent to the polymer backbone. Both types of reactive polymeric dyes may also contain additional polymerized monomeric units. The reactive polymeric dyes of the present invention can be used in a photoresist system and in particular in a color proofing construction.
135 Image forming process US268777 1994-06-30 US5468594A 1995-11-21 Tamotsu Suzuki; Mikio Totsuka; Chiyomi Niitsu; Fumiaki Shinozaki
Disclosed is an image forming process employing a light-sensitive image forming material and a developing solution. The image forming material comprises a support and either a light-sensitive resin layer containing a pigment or a colorant layer containing a pigment and a light-sensitive resin layer, superposed in order. The process comprises the steps of imagewise exposing the image forming material to light and developing the material by the use of an alkaline developing solution containing at least one of compounds having the following formula (1): ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents hydrogen, an alkyl group having 1 to 5 carbon atoms which may be substituted or an aryl group which may be substituted, M.sup.1 represents hydrogen, potassium or an ammonium group, Y represents hydrogen or --SO.sub.3 M.sub.2 (in which M.sup.2 represents sodium, potassium or an ammonium group and M.sup.2 may be the same as or different from M.sup.1) and n represents a number in the range of 1 to 1000; to form an image on the support.
136 Photosensitive polyfunctional aromatic diazo compounds useful in photosensitive compositions US95743 1993-07-21 US5430130A 1995-07-04 Hirotada Iida; Noriaki Tochizawa; Yasuo Kuniyoshi; Masaharu Watanabe; Katsuyo Tokuda; Ichiro Hozumi
An photosensitive polyfunctional aromatic diazo compound having at least two groups of Formula (uD) in the molecule, and a photosensitive composition using the same. The diazo compound can be handled under visible light free from ultraviolet, is highly photosensitive, has good shelf life, and is adequate as a photosensitive agent for lithographic printing plates and screen printing plates: ##STR1## wherein G.sup.1 is a substituent derived from alcoholic hydroxyl group; R.sup.1 and R.sup.2 are hydrogen, or alkyl or alkyloxy of 1 to 8 carbon atoms;R.sup.3 is alkyl or substituted alkyl of 1 to 8 carbon atoms, aralkyl or substituted aralkyl of 7 to 14 carbon atoms, or --CH.sub.2 CHG.sup.2 --CH.sub.2 --;X.sup.- is an anion based on protonic acid from which a proton is removed.
137 Image forming process US916969 1992-07-20 US5368982A 1994-11-29 Tamotsu Suzuki; Tomohisa Tago; Fumiaki Shinozaki
Disclosed is an image forming process employing a light-sensitive image forming material and a developing solution. The image forming material comprises a support, a peel layer and a light-sensitive resin layer containing a pigment having an anionic group, superposed in order. The process comprises the steps of imagewise exposing the image forming material to light and developing the material by the use of a developing solution having a polymer having the following recurring unit (A): ##STR1## such as poly(N-vinylpyrrolidone) to form an image on the peel layer.
138 Method of forming multi-color image US795552 1991-11-21 US5273855A 1993-12-28 Hisahiro Omote; Masahiro Yoshikawa; Masahide Takano
(Objective) In a color-proof material performed by forming multi-color image on an arbitrary material (ultimate image-receiving material) such as paper using a photosensitive transfer sheet and an intermediate image-receiving sheet, the objective is to bring the quality close to the printed quality formed with inks alone.(Constitution) For the photosensitive sheet, the colored photosensitive layer is formed with a material comprising a synthetic resin emulsion with Tg=-20.degree. to 40.degree. C. such as acrylic ester or ethylene-vinyl acetate copolymer so that the image layer itself has heat-adhesivity. Moreover, the image-receiving layer of the intermediate image-receiving sheet is formed with a material containing a resin cross-linked copolymer of olefin and .alpha., .beta.-unsaturated carboxylic acid with metallic ions and a resin comprising a copolymer of ethylene and vinyl acetate in a proportion by weight of 100/0 to 10/90.(Effect) It becomes possible to transfer the image layer alone onto the ultimate image-receiving material, thus a color-proof close to the print formed with inks alone can be produced.
139 Hard copy imaging system US746544 1991-08-19 US5252425A 1993-10-12 Pranab Bagchi
This invention relates to a full-color hard copy imaging system and a process, where a multiply photosensitive donor sheet, comprising clear polymeric or an opaque paper base, coated sequentially with a first layer of patches of a cyan, a magenta, and a yellow dye, that are thermally diffusible, with a second layer also coated sequentially with patches of a red light sensitive, a green light sensitive or a blue light sensitive, negative or a positive working photoresist layer, in such a manner that each of the colored dye patches are in registry with their complementary color sensitive photoresist patches, is exposed with white light sequentially, three times in registry on the three primary light sensitive patches, through a multicolor image (a positive transparency or a photographic negative), to produce crosslinks, image wise, in the exposed areas in the case of the negative resist system, or to uncrosslink the resist structure image wise in the exposed areas for a positive working resist system. In the second step, the first color patch is laminated on to a receiver sheet that is composed of a clear plastic layer in which the chromogenic dyes are soluble, with or without a white reflective backing and the first color image is transferred to the receiver sheet by thermal evaporation. The image is formed due to the hindrance of diffusion of dye in the crosslinked regions of the resist layer in the donor sheet. In subsequent consecutive steps the two remaining color images are transferred, by similar thermal process in registry on to the receiver sheet, thereby forming a full-color image of the original image.
140 Pre-press proofing method US728311 1991-07-08 US5240810A 1993-08-31 Hamid Barjesteh
Most prepress color proofing systems require the use of special receptor sheets. The differences between the special sheets and the final print sheet can affect the desired color balance. The use of a proof image on a temporary transfer sheet, with an adhesive layer between the image and a final receptor layer, enables the use of essentially any printing stock or printing surface as the final proofing image substrate.
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