序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 Storage-stable liquid brightener formulations US702884 1996-08-26 US5904739A 1999-05-18 Thomas Martini; Petra Rothe
Storage-stable liquid brightener formulations essentially comprise a basic optical brightener, an aprotic polar organic solvent and an acid.
2 Salts of basic dyes, preparation and uses of same US175598 1980-08-05 US4306875A 1981-12-22 Francesco De Feo; Adelio Basilico
This invention relates to novel dye salts of basic dyes or basic optical brighteners and anionic esters of boric acid. The invention also includes the preparation of the aforementioned novel dye salts.
3 Migration-free textile drying US581561 1975-05-28 US3992144A 1976-11-16 Harold L. Jackson
Textile drying process comprising continuously contacting a moving textile web, which is wet with a first fluorocarbon liquid having a textile agent dispersed therein, with the superheated vapors of a second fluorocarbon liquid, the superheated vapors being at a temperature such that no substantial amount of second fluorocarbon liquid condenses on the web, to evaporate substantially all of the first fluorocarbon liquid from the web in no more than seven seconds without causing substantial migration of the textile agent on the web, said first and second fluorocarbon liquids being selected from fluoro and chlorofluoro substituted aliphatic and cycloaliphatic hydrocarbons, ethers and tert.-amines wherein the ratio of hydrogen atoms to halogen atoms is 0 - 0.2, the first fluorocarbon liquid having a boiling point of 20.degree. - 110.degree. C. and the second fluorocarbon liquid having a boiling point of 20.degree. - 220.degree. C.
4 Process for the continuous optical brightening of organic fibre material US3690916D 1970-04-06 US3690916A 1972-09-12 WEGMULLER HANS; KLEEMANN ALOIS; KELLER RUDOLF
A PROCESS FOR THE CONTINUOUS, NON-AQUEOUS OPTICAL BRIGHTENING OF ORGANIC FIBRE MATERIAL, ESPECIALLY FIBRE MATERIAL MADE FROM NATURAL OR SYNTHETIC POLYAMIDE, IS DISCLOSED, WHICH COMPRISES IMPREGNATING SAID FIBRE MATERIAL WITH THE SOLUTION OF AT LEAST ONE OPTICAL BRIGHTENER SALT CONSISTING OF AN ANIONIC RADICAL OF AN ANIONIC OPTICAL BRIGHTENER AND AT LEAST ONE ORGANIC NITROGEN COMPOUND CONTAINING AT LEAST ONE NITROGEN ATOM CAPABLE OF SALT FORMATION, IN A SOLVENT OR SOLVENT MIXTURE, THE SOLVENT OR SOLVENT MIXTURE CONSISTING OF UNSUBSTITUTED OR HALOGENATED HYDROCARBON BOILING BETWEEN 50 AND 150*C., AND, OPTIONALLY LIQUID, WATER-SOLUBLE ORGANIC SOLVENT BOILING BELOW 220*C., REMOVING EXCESS SOLVENT FROM THE MATERIAL AND FINISHING THE BRIGHTENING BY A HEAT TREATMENT OF THE IMPREGNATED FIBRE MATERIAL AT TEMPERATURES BELOW THE SOFTENING POINT OF SAID FIBRE MATEIAL. BY THIS PROCESS, ON THE STATED FIBRE MATERIAL VERY EFFECTIVE AND EVEN OPTICAL BRIGHTENINGS HAVING GOOD FASTNESS PROPERTIES, SUCH AS FASTNESS TO DRY CLEANING AND WASHING, ARE OBTAINED.
5 Benzimidazolylstilbene whitening and brightening agents US50301555 1955-04-21 US2838504A 1958-06-10 CROUNSE NATHAN N
6 Complexes of ultraviolet absorbers and quaternary ammonium compounds which are substantially free from unwanted salts US65618 1998-04-24 US6046330A 2000-04-04 Jessica Ann Qinghong; Edward Zhao Ziaodong
This invention relates to complexes of ultraviolet absorbers with quaternary ammonium compounds which are substantially free from unwanted salts. Such complexes are formed through ionic bonds formed between the two compounds. The inventive complexes are then removed of substantially all excess inorganic salt so as to obtain an UV absorber compound which exhibits improved light- and washfastness properties, which easily coats subject surfaces, which provides excellent non-fogging and non-cracking characteristics, and which also possesses anti-static, anti-microbial, and anti-abrasion properties. This invention also concerns methods of making and utilizing such inventive ultraviolet absorbing complexes.
7 Continuous process for optical brightening US607398 1975-08-25 US4031273A 1977-06-21 Gerhard Reinert; Jack Fallows; Paul Dussy
Process for the continuous optical brightening of synthetic polyamide fibre material from organic solvents, whereinA. the fibre material is dry cleaned,B. at least one ionic optical brightener is applied to the material from a solution, emulsion or dispersion in a non-polar organic solvent,C. the material is intermediately dried,D. the optical brightener is developed in a hot aqueous acid bath, andE. the fibre material is subsequently thermofixed.
8 Viscous water-in-oil type dye or fluorescent brightening agent emulsion and method for the manufacture thereof US463603 1974-04-24 US3951598A 1976-04-20 Masahiro Arashi; Kazuko Iwano; Akira Nakamura
A viscous water-in-oil type emulsion comprising a dye or a fluorescent brightening agent which is sparingly soluble in water and liquid hydrocarbons, water, a liquid hydrocarbon and a nonionic or amphoteric surface active agent. The emulsion is suitable for dyeing or brightening hydrophobic fibers.
9 Process for the continuous optical brightening of acylated cellulose fibre material US3754964D 1971-02-26 US3754964A 1973-08-28 SEURET M; LEUTENEGGER W
A process for the continuous optical brightening of incompletely and completely acylated cellulose fiber material comprising impreganting the material with a solution of at least on optical brightener in a non-aqueous solution of a water-soluble organic solvent which solution also contains at least 80 percent by volume of a water-insoluble organic solvent.
10 Detergent compositions containing carboxy-esters of hydroxybenzimidazolyl-stilbenes US74523658 1958-06-20 US2937997A 1960-05-24 CROUNSE NATHAN N
11 Coumarin derivatives, their preparation and their use as optical brightening agents US540774 1975-01-14 US3994907A 1976-11-30 Annick Marthe Suzanne Simone Domergue
Coumarin of the formula: ##SPC1##In which R.sub.1 represents an alkyl group having 1 to 5 carbon atoms, and either unsubstituted or substituted by a non-ionic and non-chromophoric group, R.sub.2 represents a benzene, styryl or heterocyclic residue such residue being unsubstituted or substituted by one or two non-ionic and non-chromophoric groups; process for the preparation of a coumarin of the above formula which comprises reacting an orthohydroxy-benzaldehyde of formula (II) upon an acid of formula (III) or one of its functional derivatives: ##SPC2##Wherein R.sub.1 and R.sub.2 have the same definitions as in claim 1; process for the fluorescent brightening of fibrous material of synthetic origin which comprises treating the material with a coumarin of the above formula; fluorescent brightening composition containing a coumarin of the above formula and a dispersing agent resulting from the condensation of naphthalene-sulphonic acids with formaldehyde in the presence of or absence of phenol compounds, said dispersing agent comprising 30% to 50% monosulphonated condensates, 30% to 50% disulphonated condensates and 10% to 40% trisulphonated or higher polysulphonated condensates; fibres of synthetic origin treated with a coumarin of the above formula or with a brightening composition as set out above.
12 Colouration process US38657173 1973-08-08 US3929405A 1975-12-30 MORRIS CYRIL; TOPHAM ARTHUR
Process for colouring textile materials which comprises treating the textile material with a stable deflocculated dispersion of a dyestuff in an organic liquid and subsequently removing the organic liquid, the textile material being heated simultaneously with or subsequent to the treatment with the said dispersion.
13 Process for the optical brightening of organic fibre material US17415571 1971-08-23 US3871898A 1975-03-18 REINERT GERHARD; KLEEMANN ALOIS
A process for the non-aqueous optical brightening of organic fibre material, especially fibre material made from cellulose, natural or synthetic polyamide, by the exhaustion method, is disclosed, which comprises treating said fibre material in the solution of at least one optical brightener salt consisting of the anionic radical of an anionic optical brightener and at least one cationic radical of an inorganic or organic base, said organic base being derived from an organic nitrogen compound containing at least one nitrogen atom capable of salt formation, in a solvent mixture consisting of unsubstituted or halogenated hydrocarbon boiling between 50* and 150*C and liquid, water soluble organic solvent boiling below 220*, at a temperature between room temperature and the boiling point of the solvent mixture, optionally under pressure, and finishing the brightened fibre material in the usual manner. By this process, excellent white-effects or brightenings having good fastness properties, such as fastness to dry cleaning and washing, are obtained on said fibre material, without any subsequent heat treatment such as steaming or thermofixing.
14 Process for dyeing polyester textiles US3748091D 1971-04-07 US3748091A 1973-07-24 FAWKES D
PROCESS FOR DYEING OR OPTICALLY BRIGHTENING CELLULOSE TRIACETATE AND AROMATIC POLYESTER TEXTILE MATERIALS WHICH COMPRISES TREATING SAID TEXTILE MATERIALS WITH A DISPERSION OF A DYESTUFF OR OPTICALLY BRIGHTENING AGENT WHICH CONTAINS AT LEAST ONE OPTIONALLY SUBSTITUTED CARBONAMIDO OR SULPHONAMIDO GROUP IN A HALOGENATED HYDROCARBON AND IN THE PRESENCE OF A SMALL AMOUNT OF WATER, THE SAID TREATMENT BEING CARRIED OUT AT A TEMPERATURE ABOVE THE BOILING POINT OF THE AZEOTROPE OF THE HALOGENATED HYDROCARBON AND THE WATER, AND AT A PRESSURE ABOVE ATMOSPHERIC PRESSURE.
15 Dispersions US3728301D 1970-08-13 US3728301A 1973-04-17 SPENCE D; TOPHAM A
A COMPOSITION OF MATTER COMPRISING A DISPERSION OF A SOLID, PREFERABLY A PIGMENT, DYESTUFF OR TEXTILE FINISHING AGENT IN AN ORGANIC SOLVENT AND A POLYUREA ESSENTIALLY FREE FROM BASIC AMINO GROUPS WHICH CONTAINS AT LEAST TWO UREA GROUPS AND AT LEAST TWO ALKYL, ALKENYL OR ALKAPOLYENYL GROUPS CONTAINING AT LEAST EIGHT CARBON ATOMS, SAID POLYUREA BEING SOLUBLE IN THE ORGANIC OLVENT, AND THE USE OF THE SAID COMPOSITIONS OF MATTER.
16 Detergent compositions comprising benzimidazolylstilbene whitening and brightening agents US70372557 1957-12-02 US2937148A 1960-05-17 CROUNSE NATHAN N
17 Carboxy-esters of hydroxybenzimidazolyl-stilbenes US57535356 1956-04-02 US2878248A 1959-03-17 CROUNSE NATHAN N
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