序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 分散剂粘度改进剂 CN201080039796.1 2010-07-06 CN102482608A 2012-05-30 D·普赖斯; W·R·S·巴顿; M·R·萨顿; M·C·戴维斯
本公开的发明涉及包含接枝聚合物的组合物。所述聚合物包含具有至少一个烯嵌段和至少一个乙烯基芳族嵌段的主链。所述聚合物接枝有含羰基的侧基,所述接枝是如下进行的:将所述乙烯基芳族嵌段的乙烯基芳族卤化,然后在活化剂存在下将羧酸或其衍生物接枝在所述卤化的乙烯基芳族碳上。所述含羰基的基团任选被取代以提供酯、酰亚胺和/或酰胺官能团。所述接枝聚合物可用作润滑组合物例如发动机油中的分散剂粘度改进剂。
2 用于传动系统应用的包含酯化共聚物和低分散剂含量的润滑组合物 CN201380019671.6 2013-02-14 CN104220570A 2014-12-17 M·R·贝克; M·鲍姆; L·希克曼; D·C·维斯格; W·R·S·巴顿
公开了润滑组合物,制备方法和使用方法。润滑剂包含酯化共聚物,所述酯化共聚物包含含有衍生自乙烯基脂族单体的单元和衍生自羧酸单体的单元的骨架,羧酸单体包含α,β-烯属不饱和二羧酸或其衍生物。该润滑组合物还包含具有润滑粘度的油。润滑组合物包含不多于2.5重量%的不同于所述酯化共聚物的分散剂用于分散化产物。
3 接枝共聚物、其制造方法和含有该共聚物的组合物 CN200510003626.9 2005-01-07 CN1322018C 2007-06-20 M·K·米斯拉; S·斯里尼瓦桑
接枝共聚物,尤其可用来作为润滑油组合物中分散剂粘度指数改进剂者,有选自烯聚合物、双烯聚合物、乙烯基聚合物和偏亚乙烯基聚合物组成的一组的聚合物主链,是用选自下列的胺接枝的:N-对二苯胺-1,2,3,6-四氢邻苯二甲酰亚胺、4-苯胺基苯基甲基丙烯酰胺、4-苯胺基苯基来酰亚胺、4-苯胺基苯基衣康酰胺、4-羟基二苯胺的丙烯酸酯和甲基丙烯酸酯、对基二苯胺或对烷胺基二苯胺与甲基丙烯酸环丙酯的反应产物、对氨基二苯胺与异丁的反应产物、对羟基二苯胺的衍生物、吩噻嗪的衍生物、二苯胺的插烯衍生物、及其混合物;而且可以用一种使用溶液或本体接枝条件的单一步骤工艺制备。
4 接枝共聚物、其制造方法和含有该共聚物的组合物 CN200510003626.9 2005-01-07 CN1673245A 2005-09-28 M·K·米斯拉; S·斯里尼瓦桑
接枝共聚物,尤其可用来作为润滑油组合物中分散剂粘度指数改进剂者,有选自烯聚合物、双烯聚合物、乙烯基聚合物和偏亚乙烯基聚合物组成的一组的聚合物主链,是用选自下列的胺接枝的:N-对二苯胺-1,2,3,6-四氢邻苯二甲酰亚胺、4-苯胺基苯基甲基丙烯酰胺、4-苯胺基苯基来酰亚胺、4-苯胺基苯基衣康酰胺、4-羟基二苯胺的丙烯酸酯和甲基丙烯酸酯、对基二苯胺或对烷胺基二苯胺与甲基丙烯酸环丙酯的反应产物、对氨基二苯胺与异丁的反应产物、对羟基二苯胺的衍生物、吩噻嗪的衍生物、二苯胺的插烯衍生物、及其混合物;而且可以用一种使用溶液或本体接枝条件的单一步骤工艺制备。
5 一种具有极性两端的螺旋高分子摩擦改进剂 CN201310389325.9 2013-08-30 CN104419499A 2015-03-18 李韶辉; 汤正林; 黄东升; 崔海涛; 赵治宇; 官婷婷; 狄泽超
发明涉及一种具有极性两端的螺旋高分子摩擦改进剂;摩擦改进剂分子为螺旋高分子,如下式结构;其螺旋高分子表示DNA、RNA、聚肽、蛋白质或多糖的天然大分子及它们的衍生物,或者是聚烯、聚烷、聚异氰酸酯、聚乙炔、聚甲基丙烯酸酯、聚甲基丙烯酰胺、聚、聚苯撑、聚亚芳香基苯炔或聚异氰化物的合成螺旋高分子及它们的衍生物,P1和P2是独立存在的含有氮、、硫、磷、氟、或氯杂原子的极性基团;制备的具有极性两端的螺旋高分子摩擦改进剂,其长链的功能化极性两端分别与摩擦副表面的金属配位,同时长链使摩擦副的两个金属表面完全隔开,防止两摩擦表面的直接接触,实现无磨损摩擦,可为润滑油提供极佳的抗磨损性能。。
6 添加剂组合物及其制备方法 CN200980151754.4 2009-12-15 CN102264782B 2014-09-03 J·J·哈里森; M·侯赛尼
一种通过包括如下步骤的方法制备的油溶性润滑油添加剂组合物:(A)将(i)不饱和酸性试剂和(ii)单烯的共聚物与至少一种交联烃基二伯胺进行反应,由此制造具有约10%~约90%未反应的酸酐基团的混杂琥珀酸酐共聚物;并随后(B)将所述混杂琥珀酸酐共聚物与第二胺化合物反应,由此制造所述琥珀酰亚胺。
7 分散剂粘度改进剂 CN201080039799.5 2010-07-06 CN102482607A 2012-05-30 M·R·萨顿; W·R·S·巴顿; D·普赖斯; M·C·戴维斯
本公开的发明涉及包含接枝聚合物的组合物。所述聚合物主链包含烯嵌段和乙烯基芳族嵌段。所述聚合物主链接枝有含羰基的侧基,所述接枝是在油中在引发剂存在下进行的。所述含羰基的基团任选被取代以提供酯、酰亚胺和/或酰胺官能团。所述接枝聚合物可用作润滑组合物例如发动机油中的分散剂粘度改进剂。
8 添加剂组合物及其制备方法 CN200980151754.4 2009-12-15 CN102264782A 2011-11-30 J·J·哈里森; M·侯赛尼
一种通过包括如下步骤的方法制备的油溶性润滑油添加剂组合物:(A)将(i)不饱和酸性试剂和(ii)单烯的共聚物与至少一种交联烃基二伯胺进行反应,由此制造具有约10%~约90%未反应的酸酐基团的混杂琥珀酸酐共聚物;并随后(B)将所述混杂琥珀酸酐共聚物与第二胺化合物反应,由此制造所述琥珀酰亚胺。
9 基于来酸酐-苯乙烯共聚物的分散剂粘度改性剂 CN200580020125.X 2005-04-18 CN100560611C 2009-11-18 D·瓦尔戈; D·维斯格尔; B·朔贝尔; S·帕特尔森; P·莫热; C·弗兰德; J·普德尔斯基; M·J·科维特克; C·A·詹姆斯; D·普赖斯; L·奥尔泽克
一种互聚物组合物,其包含以下物质的单体衍生的单元:(i)至少一种含有2-30个原子的脂族烯和乙烯基芳族单体,和(ii)至少一种α,β-不饱和酰化剂;其中部分所述酰化剂单体被酯化,并且其中部分所述酰化剂单体与至少一种芳族胺缩合,该组合物提供了好的粘度改性和分散性能。
10 基于来酸酐-苯乙烯共聚物的分散剂粘度改性剂 CN200580020125.X 2005-04-18 CN1968976A 2007-05-23 D·瓦尔戈; D·维斯格尔; B·朔贝尔; S·帕特尔森; P·莫热; C·弗兰德; J·普德尔斯基; M·J·科维特克; C·A·詹姆斯; D·普赖斯; L·奥尔泽克
一种互聚物组合物,其包含以下物质的单体衍生的单元:(i)至少一种含有2-30个原子的脂族烯和乙烯基芳族单体,和(ii)至少一种α,β-不饱和酰化剂;其中部分所述酰化剂单体被酯化,并且其中部分所述酰化剂单体与至少一种芳族胺缩合,该组合物提供了好的粘度改性和分散性能。
11 板材和型材轧机润滑剂系统 CN87102555 1987-04-01 CN87102555A 1987-10-14 雅克韦斯·佩里亚德; 汉斯·鲁道夫·施陶普; 马尔科·拉尼尼
发明所述的用于板材和型材轧机润滑剂系统含有一种固体润滑剂,一种胶粘组分和/或一种增稠剂,以及作为载体介质的。这种润滑剂系统作为悬浮液喷射到轧机机座中的工作辊上,这时水至少部分汽化,并在工作辊上形成一层粘牢的、防水的、润滑和分离的薄层。
12 Lubricating Composition Including Esterified Copolymer And Low Dispersant Levels Suitable For Driveline Applications US14378373 2013-08-22 US20160040089A1 2016-02-11 Mark R. Baker; Marina Baum; Lynsey Hickman; Daniel C. Visger; William R.S. Barton
A lubricating composition, method of making, and method of use are disclosed. The lubricant includes an esterified copolymer including a backbone that includes units derived from a vinyl aliphatic monomer and units derived from a carboxylic acid monomer, the carboxylic acid monomer comprising an α,β-ethylenically unsaturated dicarboxylic acid or derivative thereof. The lubricating composition also includes an oil of lubricating viscosity. The lubricating composition includes no more than 2.5 wt. % of dispersant for dispersing oxidation products, other than the esterified copolymer.
13 Dispersant viscosity modifiers US13382555 2010-07-06 US08778854B2 2014-07-15 David Price; William R. S. Barton; Michael R. Sutton; Mark C. Davies
The disclosed invention relates to a composition comprising a grafted polymer. The polymer comprises a backbone with at least one olefin block and at least one vinyl aromatic block. The polymer is grafted with a pendant carbonyl containing group, the grafting being conducted by halogenating the vinyl aromatic carbon of the vinyl aromatic block and then grafting a carboxylic acid or derivative thereof on the halogenated vinyl aromatic carbon in the presence of an activating agent. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.
14 Lubricant and Functional Fluid Compositions Containing Viscosity Index Improver US13978604 2012-01-09 US20140031269A1 2014-01-30 David Price; William R.S. Barton
The disclosed invention relates to lubricant or functional fluid compositions containing viscosity index improvers in the form of self-healing polymers. The polymers may comprise one or more cleavable linkages, such as one or more disulfide bonds and/or one or more diene/dienophile linkages, to permit the polymer to reform if cleaved during use.
15 Dispersant viscosity modifiers based on maleic anhydride-styrene copolymers US11568051 2005-04-18 US08168574B2 2012-05-01 Daniel Visger; Daniel Vargo; Barton Schober; Suzanne Patterson; Patrick E Mosier; Christopher Friend; John Pudelski; Michael J Covitch; Calvin James; David Price; Leonard E Orzech
An interpolymer composition comprising monomer-derived units of (i) at least one of an aliphatic olefin containing from 2 to 30 carbon atoms and a vinyl aromatic monomer, and (ii) at least one alpha, beta-unsaturated acylating agent; wherein a portion of said acylating agent monomers is esterified and wherein a portion of said acylating agent monomers is condensed with at least one aromatic amine, provides good viscosity modification and dispersancy performance.
16 Lubricant composition, speed reduction gear using the same, and electric power steering apparatus using the same US11081876 2005-03-17 US07709427B2 2010-05-04 Kouji Kitahata; Naoki Uchida; Mitsuo Yoneda; Masahiro Hayashi
Disclosed are a lubricant composition to which is added as buffer particles to a lubricant polyurethane resin particles obtained by reacting and synthesizing long-chain polyol having a number-average molecular weight of not less than 500, a crosslinking agent having three or more active hydrogen groups in one molecule, and polyisocyanate as buffer particles, a speed reduction gear filled with the lubricant composition, and an electric power steering apparatus having the speed reduction gear incorporated therein, wherein noise produced by the speed reduction gear can be made lower than ever before irrespective of the magnitude of backlash in a case where a worm and a worm wheel are combined with each other and without complicating the configuration of the speed reduction gear by the buffer action of the buffer particles added to the lubricant composition, thereby making it possible to reduce noise produced in an automobile due to the electric power steering apparatus at low cost.
17 Dispersant Viscosity Modifiers Based on Maleic Anhydride-Styrene Copolymers US11568051 2005-04-18 US20090305923A1 2009-12-10 Daniel C. Visger; David Price; Leonard E. Orzech; Patrick E. Mosier; Suzanne M. Patterson; Calvin A. James; Barton J. Schober; Christopher Friend; Michael J. Covitch; John K. Pudelski; Renee A. Eveland; Matthew D. Gieselman
An interpolymer composition comprising monomer-derived units of (i) at least one of an aliphatic olefin containing from 2 to 30 carbon atoms and a vinyl aromatic monomer, and (ii) at least one alpha, beta-unsaturated acylating agent; wherein a portion of said acylating agent monomers is esterified and wherein a portion of said acylating agent monomers is condensed with at least one aromatic amine, provides good viscosity modification and dispersancy performance.
18 Polyolefin-substituted amines grafted with poly(aromatic-n-monomers) for olegaginous compositions US9615 1998-01-20 US5871554A 1999-02-16 Abhimanyu Onkar Patil; Robert Dean Lundberg; Antonio Gutierrez
Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.
19 Amino-substituted polymers containing graft polymer segments derived from aromatic nitrogen-containing monomers US559760 1990-07-30 US5278241A 1994-01-11 Abhimanyu O. Patil; Sudhin Datta; Robert D. Lundberg
The novel polymers of the present invention are prepared by graft polymerization of at least one aromatic nitrogen-containing monomer onto a low T.sub.g amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups). Preferred aromatic nitrogen-containing moieties are illustrated by aniline, and preferred low T.sub.g amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene elastomeric terpolymers. The polymers of this invention are useful in electrical, textile and other applications.
20 Lubricant compositions containing a viscosity index improver having dispersant properties US157348 1988-02-17 USH826H 1990-10-02 Carl L. Willis; Andy M. Arismendi, Jr.
The present invention relates to a lubricant composition containing a minor amount of a thermally stable moldified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein an amide functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
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