21 |
Cupriferous azo-dyestuffs |
US39958453 |
1953-12-21 |
US2763640A |
1956-09-18 |
HENRI RIAT; PAUL DREYFUSS; FRITZ OESTERLEIN |
|
22 |
Metallizable monoazo dyestuffs |
US79116947 |
1947-12-11 |
US2551887A |
1951-05-08 |
WERNER KUSTER |
|
23 |
Azo dyestuffs |
US32319828 |
1928-12-01 |
US1841637A |
1932-01-19 |
HERBERT SAUNDERS KENNETH; MORDECAI MENDOZA |
|
24 |
Intermediates and dyes therefrom |
US29349628 |
1928-07-17 |
US1841622A |
1932-01-19 |
MORDECAI MENDOZA |
|
25 |
Mordant azo dyestuffs |
US13856726 |
1926-09-29 |
US1766948A |
1930-06-24 |
MORDECAI MENDOZA; HERBERT SAUNDERS KENNETH |
|
26 |
Manufacture of new azo dyestuffs |
US11512226 |
1926-06-10 |
US1766947A |
1930-06-24 |
HERBERT SAUNDERS KENNETH |
|
27 |
Azo dyes. |
US1914810471 |
1914-01-05 |
US1126489A |
1915-01-26 |
KOTHE RICHARD; DRESSEL OSCAR |
|
28 |
Red azo dye. |
US1913780459 |
1913-07-22 |
US1098388A |
1914-06-02 |
JORDAN HEINRICH; NEELMEIER WILHELM |
|
29 |
Process of making ortho-oxymonoazo dye. |
US1910597060 |
1910-12-13 |
US987999A |
1911-03-28 |
LASKA AUGUST LEOPOLD |
|
30 |
Azo triphenylmethane dye. |
US1910563045 |
1910-05-24 |
US980251A |
1911-01-03 |
HAUSDOERFER ARTHUR; HEIDENREICH CARL |
|
31 |
Fabriken |
US509623D |
|
US509623A |
1893-11-28 |
|
|
32 |
Richard laugh and carl krekeler |
US502369D |
|
US502369A |
1893-08-01 |
|
|
33 |
Richard laucii and carl krekeler |
US502368D |
|
US502368A |
1893-08-01 |
|
|
34 |
Rudolf nietzki |
US424019D |
|
US424019A |
1890-03-25 |
|
|
35 |
Metal complex dyes and preparation thereof |
US537904 |
1990-06-12 |
US5095100A |
1992-03-10 |
Takashi Ono; Tatsuya Yagyu; Katsumi Fukuda; Minako Terasaki |
Metal complex dyes comprising a metalizable azo compound represented by one of Formulas [I] through [IV]: ##STR1## In Formulas [I] through [IV], Ps represents a phosphono group in the form of a free acid or a salt; Sf represents a sulfo group in the form of a free acid or a salt; m is 0, 1 or 2. R.sup.1 represents a hydrogen atom or an amino group; X represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2 or a carboxyl group. Y represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2, a carboxyl group or a methyl group; R.sup.2 represents a hydrogen atom or a hydroxyl group; A represents a phenyl group or naphthyl group selected from the group comprising the following 1 through 4: ##STR2## In the above formulas 1 through 4, Sf has the same definition as above; n is 0, 1 or 2. R.sup.3 represents a hydroxyl group or a carboxyl group; R.sup.4 represents a hydroxyl group, a carboxyl group or an amino group; R.sup.5 and R.sup.6 independently represent a hydroxyl group or a carboxyl group; R.sup.7 and R.sup.8 independently represent a hydrogen atom, a hydroxyl group or an amino group. B has the same definition as A above except that R.sup.3 represents a hydroxyl group, a carboxyl group or an amino group. R.sup.9 represents a hydrogen atom, a methyl group, an alkoxy group having a carbon number of 1 or 2 or a sulfo group in the form of a free acid or a salt; D represents a coupling component residue having a metalizable hydroxyl group at the position adjoining to the azo group.Use of these metal complex dyes makes it possible to dye metal-tanned leather with good permeability and excellent color fastness to rubbing and color fastness to light. |
36 |
Salicyl phenyl naphthyl trisazo di and trisulfonic developed direct
black dyes |
US52622 |
1979-06-27 |
US4279814A |
1981-07-21 |
Howard L. Smith |
New trisazo compounds that are useful as developed direct black dyes for cellulosic textiles and as self-shade dyes for paper and leather having the structure: ##STR1## wherein R' is at least one of the following groups: ##STR2## and M is H, Na, K, Li, N(R).sub.3 H where R is H, lower alkyl or lower hydroxyalkyl and each of the R groups can be the same or different. |
37 |
Azo dyestuffs |
US668034 |
1976-03-18 |
US4091021A |
1978-05-23 |
Herbert Francis Andrew; David William Crichton Ramsay; Cecil Vivian Stead |
Azo dyestuffs, which in the acid form, are represented by the formula:A -- N .dbd. N -- M -- N .dbd. N -- E (1)whereinA is an aromatic radical,M is a 1,4-benzene radical which may be substituted,E is the residue of a coupling component which is free from azo groups,At least one of A and M containing a phosphonic acid group, and the metal complexes of those having a metallisable group are reactive dyes suitable for use in the process of German OLS No. 2324809. |
38 |
Nent azo dye with a bis-(2-hydroxy-3-carboxyphenyl) methane coupling compo |
US3759892D |
1970-02-12 |
US3759892A |
1973-09-18 |
WICKI H |
AZO DYES AND THEIR METAL COMPLEX COMPOUNDS ARE FORMED BY COUPLING 1 OR 2 MOLES OF A DIAZO COMPONENT WITH A BIS-1-(2-HYDROXY-3-CARBOXYPHENYL METHANE. THEY ARE HIGHLY SUITABLE FOR DYEING LEATHER, FOR WHICH THEY HAVE VERY GOOD PENETRATIVE PROPERTIES AND YIELD LIGHT-FAST DYEINGS.
|
39 |
Trifluoromethyl-benzeneazosalicylic acid dyestuffs |
US20030462 |
1962-06-06 |
US3238189A |
1966-03-01 |
MAY ERNEST M; ANDREW FONO |
|
40 |
Tetrakisazo dyestuffs |
US41041054 |
1954-02-15 |
US2797214A |
1957-06-25 |
WERNER BOSSARD |
|