序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 Cupriferous azo-dyestuffs US39958453 1953-12-21 US2763640A 1956-09-18 HENRI RIAT; PAUL DREYFUSS; FRITZ OESTERLEIN
22 Metallizable monoazo dyestuffs US79116947 1947-12-11 US2551887A 1951-05-08 WERNER KUSTER
23 Azo dyestuffs US32319828 1928-12-01 US1841637A 1932-01-19 HERBERT SAUNDERS KENNETH; MORDECAI MENDOZA
24 Intermediates and dyes therefrom US29349628 1928-07-17 US1841622A 1932-01-19 MORDECAI MENDOZA
25 Mordant azo dyestuffs US13856726 1926-09-29 US1766948A 1930-06-24 MORDECAI MENDOZA; HERBERT SAUNDERS KENNETH
26 Manufacture of new azo dyestuffs US11512226 1926-06-10 US1766947A 1930-06-24 HERBERT SAUNDERS KENNETH
27 Azo dyes. US1914810471 1914-01-05 US1126489A 1915-01-26 KOTHE RICHARD; DRESSEL OSCAR
28 Red azo dye. US1913780459 1913-07-22 US1098388A 1914-06-02 JORDAN HEINRICH; NEELMEIER WILHELM
29 Process of making ortho-oxymonoazo dye. US1910597060 1910-12-13 US987999A 1911-03-28 LASKA AUGUST LEOPOLD
30 Azo triphenylmethane dye. US1910563045 1910-05-24 US980251A 1911-01-03 HAUSDOERFER ARTHUR; HEIDENREICH CARL
31 Fabriken US509623D US509623A 1893-11-28
32 Richard laugh and carl krekeler US502369D US502369A 1893-08-01
33 Richard laucii and carl krekeler US502368D US502368A 1893-08-01
34 Rudolf nietzki US424019D US424019A 1890-03-25
35 Metal complex dyes and preparation thereof US537904 1990-06-12 US5095100A 1992-03-10 Takashi Ono; Tatsuya Yagyu; Katsumi Fukuda; Minako Terasaki
Metal complex dyes comprising a metalizable azo compound represented by one of Formulas [I] through [IV]: ##STR1## In Formulas [I] through [IV], Ps represents a phosphono group in the form of a free acid or a salt; Sf represents a sulfo group in the form of a free acid or a salt; m is 0, 1 or 2. R.sup.1 represents a hydrogen atom or an amino group; X represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2 or a carboxyl group. Y represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2, a carboxyl group or a methyl group; R.sup.2 represents a hydrogen atom or a hydroxyl group; A represents a phenyl group or naphthyl group selected from the group comprising the following 1 through 4: ##STR2## In the above formulas 1 through 4, Sf has the same definition as above; n is 0, 1 or 2. R.sup.3 represents a hydroxyl group or a carboxyl group; R.sup.4 represents a hydroxyl group, a carboxyl group or an amino group; R.sup.5 and R.sup.6 independently represent a hydroxyl group or a carboxyl group; R.sup.7 and R.sup.8 independently represent a hydrogen atom, a hydroxyl group or an amino group. B has the same definition as A above except that R.sup.3 represents a hydroxyl group, a carboxyl group or an amino group. R.sup.9 represents a hydrogen atom, a methyl group, an alkoxy group having a carbon number of 1 or 2 or a sulfo group in the form of a free acid or a salt; D represents a coupling component residue having a metalizable hydroxyl group at the position adjoining to the azo group.Use of these metal complex dyes makes it possible to dye metal-tanned leather with good permeability and excellent color fastness to rubbing and color fastness to light.
36 Salicyl phenyl naphthyl trisazo di and trisulfonic developed direct black dyes US52622 1979-06-27 US4279814A 1981-07-21 Howard L. Smith
New trisazo compounds that are useful as developed direct black dyes for cellulosic textiles and as self-shade dyes for paper and leather having the structure: ##STR1## wherein R' is at least one of the following groups: ##STR2## and M is H, Na, K, Li, N(R).sub.3 H where R is H, lower alkyl or lower hydroxyalkyl and each of the R groups can be the same or different.
37 Azo dyestuffs US668034 1976-03-18 US4091021A 1978-05-23 Herbert Francis Andrew; David William Crichton Ramsay; Cecil Vivian Stead
Azo dyestuffs, which in the acid form, are represented by the formula:A -- N .dbd. N -- M -- N .dbd. N -- E (1)whereinA is an aromatic radical,M is a 1,4-benzene radical which may be substituted,E is the residue of a coupling component which is free from azo groups,At least one of A and M containing a phosphonic acid group, and the metal complexes of those having a metallisable group are reactive dyes suitable for use in the process of German OLS No. 2324809.
38 Nent azo dye with a bis-(2-hydroxy-3-carboxyphenyl) methane coupling compo US3759892D 1970-02-12 US3759892A 1973-09-18 WICKI H
AZO DYES AND THEIR METAL COMPLEX COMPOUNDS ARE FORMED BY COUPLING 1 OR 2 MOLES OF A DIAZO COMPONENT WITH A BIS-1-(2-HYDROXY-3-CARBOXYPHENYL METHANE. THEY ARE HIGHLY SUITABLE FOR DYEING LEATHER, FOR WHICH THEY HAVE VERY GOOD PENETRATIVE PROPERTIES AND YIELD LIGHT-FAST DYEINGS.
39 Trifluoromethyl-benzeneazosalicylic acid dyestuffs US20030462 1962-06-06 US3238189A 1966-03-01 MAY ERNEST M; ANDREW FONO
40 Tetrakisazo dyestuffs US41041054 1954-02-15 US2797214A 1957-06-25 WERNER BOSSARD
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