序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
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21 | Water-insoluble benzimidazolone-(5)-sulfonamidophenylene-azo-aryl dyestuffs | US28677072 | 1972-09-06 | US3828019A | 1974-08-06 | JUNKER P; RIBKA J; KUNSTMANN W |
THE PRESENT INVENTION RELATES TO NOVEL WATER-INSOLUBLE MONO- AND DISAZO DYESTUFFS OF THE GENERAL FORMULA
(5-(-NH-CO-CH(-CO-CH3)-N=N-(X1,X2-PHENYLENE)-SO2-NH-),R- BENZIMIDAZOL-2-ONE)N A WHEREIN X1 AND X2 MAY BE IDENTICAL OR DIFFERENT AND REPRESENT A HYDROGEN ATOM, A LOWER ALKYL OR ALKOXY GROUP HAVING PREFERABLY 1 TO 4 CARBON ATOMS, OR A HALOGEN ATOM PERFERABLY A CHLORINE OR BROMINE ATOM, AND R IS A HYDROGEN OR HALOGEN ATOM, METHOXY OR ETHOXY GROUP, N REPATOM, A METHYL, ETHYL, METHOXY OR ETHOXY GROUP, N REPRESENTS THE NUMBERS 1 OR 2 AND A AN OPTIONALLY SUBSTITUTED RADICAL, PREFERABLY OF THE BENZENE, NAPHTHALENE OR BENZIMIDAZOLONE SERIES OF N=1, AND OF THE BENZENE OR DIPHENYL SERIES IF N=2. THESE DYESTUFFS MAY BE USED FOR DYEING OR PRINTING LACQUERS, POLYMERS OR TEXTILE MATERIALS, THEY SHOW A GOOD FASTNESS TO LIGHT, TO WEATHER AND TO MIGRATION. FURTHERMORE, THEY ARE FAST TO HEAT, HAVE A HIGH TINCORIAL STRENGTH TO THE INFLUENCE OF CHEMICAL PRODUCTS, ESPECIALLY SOLVENTS, ACIDS AND ALKALIS. |
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22 | Azobis(2-phenylacrylic acid,3-tropanyl esters) | US3542757D | 1968-01-31 | US3542757A | 1970-11-24 | CALDWELL HENRY C; GROVES WILLIAM G |
23 | Monoazo dyestuffs | US29386663 | 1963-07-09 | US3406165A | 1968-10-15 | WINFRIED KRUCKENBERG |
24 | The dichroic dye composition, polarizing film, the liquid crystal cell, and a display device | JP2009199090 | 2009-08-28 | JP5437744B2 | 2014-03-12 | 亮司 後藤; 伸卓 岩橋 |
25 | Dichroic pigment, liquid crystal composition containing the pigment and liquid crystal element | JP32943395 | 1995-11-27 | JPH09143471A | 1997-06-03 | KANEKO MASAHARU; YONEYAMA TOMIO |
PROBLEM TO BE SOLVED: To obtain a new azo dichroic pigment compound excellent in dichroism, solubility, light resistance and coloring property and useful for a liquid crystal composition for a guest-host-type liquid crystal display element used as a display panel in an automobile, etc. SOLUTION: A compound is represented by formula I [D 1 and D 2 are each a (substituted) phenyl, etc.; W is a (substituted) 4,4'-biphenylene, etc.; X is OCH 2, OOC, etc.; Z 1 to Z 12 are each H, a halogen, methyl, etc., and in each of pairs of Z 2 and Z 3, Z 5 and Z 6, Z 8 and Z 9 and Z 11 and Z 12, they may be mutually linked to each other to form an alicyclic group or a (nitrogen-containing) aromatic ring; (m) and (n) are each 0-2], for example, 4,4'-bis({4-[4-(4-butylphenylazo) naphthalene-1-yl]azo}phenoxymethyl)biphenyl. A compound of formula I is obtained by reacting either or both of a compound of formula II (Y 1 is OH, a carboxyl, etc.) and a compound of formula III (Y 2 is Y 1) with a compound of formula IV [Y 3 is OH, a carboxyl or a group of the formula, CH 2Y 4 (Y 4 is a halogen)]. COPYRIGHT: (C)1997,JPO | ||||||
26 | Mono azo disperse dye | JP12351696 | 1996-05-17 | JPH0925423A | 1997-01-28 | ROBERUTO EGURI; BIITO HENTSUI |
PROBLEM TO BE SOLVED: To obtain a mono azo disperse dye expressed by a specific formula, useful for dyeing a synthetic or semisynthetic fiber, yarn, etc., containing a hydrophobic organic substance, having excellent dyeability and capable of exhibiting excellent heat migration fastness and light fastness after a heat treatment. SOLUTION: This dye is expressed by formula I {R is a (substituted) phenyl or R'O [R' is a 3-4C alkenyl or alkynyl, phenyl or a (substituted) 1-8C alkyl]; R 1 is H or a 1-2C alkyl; R 2 is H or a halogen; R 3 is H or a 1-3C alkyl; R 4 is H, a (substituted) 1-8C alkyl or a (substituted)amino} and having no water soluble group. Further, either of the processes, those are, a diazotized amine of formula II is made to couple with an amine of formula III or a compound of formula IV is made to condense with a compound of formula V, is preferably used for obtaining the dye. COPYRIGHT: (C)1997,JPO | ||||||
27 | Water insoluble monoazo dye | JP14294378 | 1978-11-21 | JPS5480330A | 1979-06-27 | JIOATSUKIINO BOFUA; FURABIO BIRURAANI; ROMAANO JIANOORA |
28 | Dye-ascorbic acid derivatives | US13812869 | 2011-08-05 | US08709104B2 | 2014-04-29 | Thomas Rudolph; Philipp Buehle |
The invention relates to specific dye-ascorbic acid derivatives and the use thereof as dyes for the coloring of matrices, such as, for example, skin, hair, nails or textiles, and a process for the preparation thereof, a process for the coloring of matrices, and a composition comprising these dye-ascorbic acid derivatives, and a process for the preparation of these compositions. On use of the specific dye-ascorbic acid derivatives according to the invention, a positive effect on the moisture content of the matrices arises. | ||||||
29 | DYE-ASCORBIC ACID DERIVATIVES | US13812869 | 2011-08-05 | US20130125317A1 | 2013-05-23 | Thomas Rudolph; Philipp Buehle |
The invention relates to specific dye-ascorbic acid derivatives and the use thereof as dyes for the colouring of matrices, such as, for example, skin, hair, nails or textiles, and a process for the preparation thereof, a process for the colouring of matrices, and a composition comprising these dye-ascorbic acid derivatives, and a process for the preparation of these compositions. On use of the specific dye-ascorbic acid derivatives according to the invention, a positive effect on the moisture content of the matrices arises. | ||||||
30 | DYES WITH CHANGEABLE SOLUBILITIES, AND METHODS FOR THEIR USE | US13546333 | 2012-07-11 | US20120272461A1 | 2012-11-01 | Seth Adrian MILLER |
Solubility changeable dye compositions include a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic. A method of dying a substrate with such dye compositions includes contacting the dye with the substrate. | ||||||
31 | Dyes with changeable solubilities, and methods for their use | US13546333 | 2012-07-11 | US08298298B1 | 2012-10-30 | Seth Adrian Miller |
Solubility changeable dye compositions include a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic. A method of dying a substrate with such dye compositions includes contacting the dye with the substrate. | ||||||
32 | Dyestuffs and resin compositions | US1921 | 1997-12-31 | US6051360A | 2000-04-18 | Akio Karasawa; Hisato Itoh |
Dyestuffs represented by the below-described formula (1), that is, dyestuffs formed of a chromophoric nucleus and a bisphenol introduced therein have excellent solubility in solvents and binder resins, and can provide color filters having excellent transmittance characteristics and durability. ##STR1## wherein Dye represents a chromophoric nucleus, X represents a direct bond or a divalent connecting group, R.sup.1 to R.sup.10 and n are defined with the provision that one of R.sup.9 and R.sup.10 has 3 or more carbon atoms. | ||||||
33 | Color filter having novel dyestuff | US659616 | 1996-06-06 | US5773172A | 1998-06-30 | Akio Karasawa; Hisato Itoh |
Dyestuffs represented by the below-described formula (1), that is, dyestuffs formed of a chromophoric nucleus and a bisphenol introduced therein have excellent solubility in solvents and binder resins, and can provide color filters having excellent transmittance characteristics and durability. ##STR1## wherein Dye represents a chromophoric nucleus, X represents a direct bond or a divalent connecting group, R.sup.1 to R.sup.10 and n are defined with the provision that one of R.sup.9 and R.sup.10 has 3 or more carbon atoms. | ||||||
34 | Water-insoluble nitrophenylazophenyl compounds containing a terminal --N--(C.sub.2).sub.n --O--CO-- or --CO--O--CH.sub.2 --CH.sub.2 --C.sub.3 F.sub.5 group | US457681 | 1974-04-03 | US4085099A | 1978-04-18 | Jean Marie Louis Leroy; Jacques Pierre Edmond Pechmeze |
Dyestuffs falling within the formula: ##STR1## in which A represents the residue of a diazotizable amine free from substituents giving rise to an acid dissociation, m is 0 or 1, the benzene nucleus B may be substituted by methyl or methoxy groups, X represents a hydrogen atom or a methyl, methoxy or ethoxy group, Y represents a hydrogen or chlorine atom or a methyl, methoxy or acylamino group, n is 1, 2 or 3, Z represents --O--CO--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5 or --CO--O--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5 or, provided that Y is --NHCO--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5, a hydrogen atom or a hydroxy, cyano, alkoxycarbonyl or acyloxy group, and R represents a substituted or unsubstituted alkyl group of low molecular weight or --(CH.sub.2).sub.n --Z wherein n and Z have the meanings given above; mixture of such dyestuffs; processes for their preparation; process for the coloration of hydrophobic fibres in which the coloring agent is a dyestuff of the formula given above or a mixture thereof; textile materials dyed or printed with a dyestuff of the formula given above or with a mixture thereof and intermediate products of the formula: ##STR2## | ||||||
35 | Fluorinated esters with a pesticide action | US3689522D | 1968-11-15 | US3689522A | 1972-09-05 | ROSSI GIORGIO; MICHIELI GIANNANTONIO; PAOLUCCI PARIDE |
Described are fluorinated aromatic compounds of the formula: WHEREIN N 0 OR > OR = 1 AND M 0, 1 OR 2; WHEN N 0, M 0 OR 1; WHEN N 1, M 0, 1 OR 2; WHEN N > 1, m 0; and A. WHEN N 0, M 0, X may be alkyl with a linear or branched chain, alkoxyl, hydroxyl, phenyl optionally substituted, nitro, halo, carboxy-2-fluoro-ethyl and acyl; B. WHEN N 0, M 1, X and Y equal or different from each other, may be alkyl with a linear or branched chain, alkoxyl, hydroxyl, phenyl optionally substituted, nitro, halo, acyl; C. WHEN N 1, M 0, X may be cyclohexyl, phenyl, optionally substituted, benzyl, benzoyl, azophenyl; D. WHEN N 1, M 1 OR 2, X and Y, the same or different from each other, may be nitro or halo; E. WHEN N > 1; M 0, X may be halo, alkoxyl, phenyl optionally substituted.
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36 | Reactive mono- and disazo dyestuffs suitable for dyeing modified polypropylene | US3502646D | 1966-07-29 | US3502646A | 1970-03-24 | CANONICA LUIGI; CROTTI ARGENTO; PIERI GIAMPIERO |
37 | Fat-soluble azo-dyestuffs | US52282455 | 1955-07-18 | US2888452A | 1959-05-26 | MAX SCHMID; WILLY MUELLER |
38 | Cellulose acetate dyed with monoazo dyes | US46632542 | 1942-11-20 | US2412312A | 1946-12-10 | STANLEY ARGYLE CHRISTOPHER |
39 | Yellow azo dyestuffs | US36018040 | 1940-10-07 | US2283326A | 1942-05-19 | FRIEDRICH FELIX; WILLY MULLER |
40 | 화합물 및 이색성 색소, 및 편광막 | KR1020130019201 | 2013-02-22 | KR1020130098915A | 2013-09-05 | 오카와하루키; 하타나카노부유키 |
PURPOSE: A compound has the absorption peak in 400-520 nm and can form a polarizing film with a high dichroic ratio. CONSTITUTION: A compound is represented by chemical formula 1. A dichroic dye includes the compound as an active ingredient. The composition includes the compound and a polymerizable liquid crystal compound. The polymerizable liquid crystal compound is a smetic liquid crystal compound. A manufacturing method of a polarizer includes a step of preparing a laminate where an alignment layer is laminated on a transport substrate; a step of forming a coating film by spreading the composition on the alignment layer of the laminate; and a step of polymerizing the polymerizable liquid crystal compound being included in the coating film. |