序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 Process for preparing [5-amino-2-(2-hydroxyethylamino)-phenyl](2-hydroxyethyl)sulphone US160698 1993-12-01 US5414131A 1995-05-09 Karl-Josef Herd; Hermann Henk
A process for preparing the sulphone of the formula ##STR1## consists in reductive cleavage of disazo/disazoxy dyestuffs of the formula ##STR2## in which B is a direct bond or a bridging member andv, w, x, y, independently of one another, are 0 or 1,x+y being 0 or 1 and v+w being 0 or 1.
42 Process for the preparation of [5-amino-2-(2-hydroxyethylamino)phenyl](2-hydroxyethyl) sulphone US603097 1990-10-25 US5107025A 1992-04-21 Karl-Josef Herd
A process for the preparation of the sulphone of the formula: ##STR1## consists in reductive cleavage of azo/azoxy dyestuffs of the formula ##STR2##The invention also relates to the azo/azoxy dyestuffs mentioned.
43 Novel photographic products and processes US9120770 1970-11-19 US3826801A 1974-07-30 CIECIUCH R; SIMON M
R-O-CH2-CO-O-(CH2)2-N=N-(CH2)2-O-CO-CH2-O-R

TRANSFER IMAGES IN COLOR ARE FORMED BY EXPOSINGG A PHOTOSENSITIVE ELEMENT CONTANING A SILVER HALIDE EMULSION AND A MONO OR DIAZO DYE WHICH CONTAINS NOT LESS THAN ONE OR MORE THAN TWO GROUPS SELECTED FROM THE GROUP REPRESENTED BY THE FORMULAE -N=N-CH2-CH2-OOC-CH2-O-R WHEREIN R IS A LOWER ALKYL GROUP SAID DYES ALSO CONTAININING NOT LESS THAN ONE OR MORE THAN TWO DIHYDROXYPHENYL SILVER HALIDE DEVELOPING RADICALS, PERMEATING THE PHOTOSENSITIVE ELEMENT WITH AN AQUEOUS ALKALNE PROCESSING COMPOSITION, AND DEACYLATION OF THE -OOC-CH2-O-R

R-O-CH2-COO-CH2-CH2-N=N-CH2-CH2-OOC-CH2-O-R GROUPS BY HYDROLYSIS TO PROVIDE HYDROXYL GROUPS THEREBY PROVIDING A NON-REVESIBLE BATHOCHROMIC SHIFT OF THE SPECIAL ABSORPTION CHARACTERISTICS OF DYE; IMMONILIZING THE DYE AS A RESULT OF THE DEVELOPMENT OF THE EXPOSED AREAS OF THE EMULSION. AND TRANSFERRING BY DIFFUSION, AT LAST A PORTION OF THE IMAGEWISE DISTRIBUTION OF DYES TO A SUPERPOSED IMAGE RECEIVING LAYER TO PROVIDE A POSITIVE DYE IMAGE THEREIN.
44 Insoluble heterocyclic disazo dyes US3691148D 1970-08-07 US3691148A 1972-09-12 PETER RICHARD; ANGLIKER HANS-JOERG
Heterocyclic disazo compounds containing two heterocyclicazoaniline groups of general formula WHERE D is a heterocyclic diazo component such as thiazolyl, benzthiazolyl, benzimidazolyl, etc. C AND D ARE SUCH SUBSTITUENTS AS METHYL, ETHOXY, PHENOXY AND ACYLAMINO R1 can be hydrogen, lower alkyl and lower alkyl substituted by cyano, phenyl, hydroxy, alkoxy, etc. R3 can be alkylene and substituted alkylene, etc. are bridged by a bridging group, Z, which has no dyestuff characteristics, such as -O-R5-O-, -NH-R5-NH- where R5 is aliphatic, cyclo- or araliphatic, aromatic or acyl, WHERE X'' is oxygen, sulfur or -NH and R6 is aliphatic, cycloaliphatic, aromatic or heterocyclic. The compounds are useful in dyeing synthetic fibers, especially polyester and acrylic.
45 Azo dyestuffs derived from stilbene and containing a naphthotriazolo group US3575954D 1968-03-21 US3575954A 1971-04-20 JIROU MARCEL GEORGES; URNE VASILI
AZO DYESTUFFS OF THE FORMULA:

=(N-(3-(H-O3S-)-1,4-PHENYLENE)-CH=CH-(2-(H-O3S-)-

1,4-PHENYLENE)-N=N-(1,4-PHENYLENE)-

(2H-NAPTHO(1,2-D)TRIAZOLYLENE)-SO3-H)2

WHEREIN THE BENZENE NUCLEUS A IS UNSUBSTITUTED OR SUBSTITUTED BY ONE OR MORE ALKYL AND/OR ALKOXY GROUPS, AND PROCESS FOR THEIR PREPARTION. THESE DYESTUFFS ARE PARTICULARLY WELL SUITED FOR DYEING OF CELLULOSIC FIBRES AND THE SHADES OBTAINED ARE DISTINGUISHED BY THEIR GOOD GENERAL FASTNESS ESPECIALLY TO WATER AND WASHING.
46 Azo dyestuffs containing a triazole group US3501454D 1966-08-08 US3501454A 1970-03-17 NICKEL HORST; SUCKFULL FRITZ
47 Azo dyestuffs US188160 1960-01-12 US3135732A 1964-06-02 KARL-HEINZ SCHUNDEBUTTE; HERST NICKEL; KARL-HEINZ SCHMIDT; FRITZ SUCKFULL
48 Triazole azo dyestuffs US74274558 1958-06-18 US2932636A 1960-04-12 FRITZ SUCKFULL; HORST NICKEL
49 Anthraquinone-azoic pigments US64033057 1957-02-15 US2900380A 1959-08-18 BERGSTROM HERMAN A
50 Cupriferous azo-dyestuffs US49274455 1955-03-07 US2837507A 1958-06-03 HENRI RIAT
51 Production of dyeing conversion products of azo-dyestuffs US59284332 1932-02-13 US1907192A 1933-05-02 ERICH WANNER
52 Azo compound, aqueous dye solution using the same, ink and use thereof JP2011126963 2011-06-07 JP2011225887A 2011-11-10 KITAYAMA HIROKAZU; SHIRASAKI YASUO; MATSUI TAKAHIKO; ONO HIROAKI
PROBLEM TO BE SOLVED: To provide an azo compound which is reduced in the copper ion content and exhibits hue and clarity suitable for inkjet recording and which can give records having excellent light fastness, water resistance, and moisture resistance, and such ozone resistance as to control the fading and the discoloration, and to provide a water-based yellow ink using the same.SOLUTION: There are provided the azo compound represented by formula (12) having a content of impurity copper ions of 100 ppm or below or a salt thereof, and an ink containing the same.
53 Preparation of (5-amino-2-(2-hydroxy-ethylamino)-phenyl)(2-hydroxyethyl)sulphone JP33923793 1993-12-06 JPH06199772A 1994-07-19 KAARUUYOZEFU HERUTO; HERUMAN HENKU
PURPOSE: To prepare the subject compd. useful as an intermediate for dyestuff synthesis of reactive dyestuffs by cleaving reductively a specified disazo/disazoxy dyestuff and separating the compd. as a slightly water-soluble complex betaine. CONSTITUTION: Disazo/disazoxy dyestuff of formula I [B is a direct bond or a crosslinking member; (v), (w), v+w, (x), (y) and x+y are each 0 or 1] is cleaved reductively under pressured hydrogen to produce a compd. of formula II. The compd. of formula II is oxidized and precipitated, then separated as a slightly water-soluble complex betaine to obtain a compd. of formula III. It is preferable that the compd. of formula II is tetra-azotized and coupled with 2-(2-hydroxyethyl)mercapto-N-(2-hydroxyethyl)-aniline to obtain a compd. of formula IV, then the obtained compd.) of formula IV is oxidized to obtain a compound of formula I. COPYRIGHT: (C)1994,JPO
54 Azo dye and process for the preparation of (5-amino-2-(2-hydroxyethylamino)phenyl)(2-hydroxyethyl) sulfone JP32138590 1990-11-27 JPH03181454A 1991-08-07 KARURUUYOZEFU HERUTO
PURPOSE: To obtain easily the subject compound as a feedstock for azo dyestuffs, etc., by using benzothiazole and ethylene oxide as feedstocks, hydrolyzing the product, diazotizing the product, coupling the product, oxidizing the product, and subjecting the product to reductive cleavage. CONSTITUTION: A benzothiazole of formula I (E is H or CH 3) is reacted with ethylene oxide in an aqueous medium to give an N-formuly- or N-acethyl-N-(2- hydroxyethyl)aniline derivative of formula II. The product is hydrolyzed to give an aniline derivative of formula III. The product is coupled with a diazotized amine D-NH 2 to give a mono azo dye of formula IV. The product is oxidized to give an azo/azoxy dye of formula V. The product is subjected to reductive cleavage by conventional manner to give D-NH 2 (D is a diazo component) and a compound of formula VI. COPYRIGHT: (C)1991,JPO
55 JPS5549195B1 - JP7757671 1971-10-05 JPS5549195B1 1980-12-10
56 JPS5137838B1 - JP12684872 1972-12-19 JPS5137838B1 1976-10-18
57 JPS5136257B1 - JP9694870 1970-11-05 JPS5136257B1 1976-10-07
58 Managing computer network resources US10186526 2002-06-28 US07747730B1 2010-06-29 James D. Harlow
Software agents are assigned goals in accordance with network policies that define a desired operational characteristic of a computer network. A software agent achieves its assigned goal by executing a predefined task. An assigned goal may be dynamically modified as necessary based on the actual operational characteristics of the network. The software agent may request further policy if it cannot achieve its assigned goal by performing the predefined task.
59 Azo compound, aqueous dye solutions containing the same, inks and use thereof US10572334 2004-09-29 US20070119341A1 2007-05-31 Hirokazu Kitayama; Yasuo Shirasaki; Takahiko Matsui; Hiroaki Ohno
An azo compound which is reduced in the copper ion content and exhibits hue and clarity suitable for ink-jet recording and which can give records having excellent light fastness, water resistance, and moisture proofness, and such ozone resistance as to control the fading and the discoloration; and water-base yellow inks containing the same. In particular, the azo compound represented by the formula (12) having a content of impurity copper ions of 100 ppm or below or salts thereof; and inks containing the same.
60 Polyazo compounds containing 2,4,2{40 ,4{40 -tetrahydroxy-dibenzylamine as coupling component US22037972 1972-01-24 US3915952A 1975-10-28 SAILER ANDRE LOUIS; FRANK PIERRE
Azo dyes of the formula:

WHEREIN X represents the bivalent grouping -CH2-NH-CH2-, m represents an integer of 2 to 4, and Y represents a radical of the benzene, naphthalene, heterocyclic or azo series, at least one of which is substituted by at least one sulphonic or carboxylic acid group, and salts thereof with an amine or ammonium compound, and nitrosated, oxidised and metalliferous derivatives thereof; the dyes, derivatives and salts are useful for the color-finishing of leathers, for example for the aniline finishing of skins, whether or not previously dyed, and for the finishing of leathers with a buffed or artificial hair side, as well as for the spray-gun dyeing of full-grain leathers on which they give very vivid transparent shades which are very fast, especially to light and wet rubbing.
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