| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 二硫化物染料 | CN201280027370.3 | 2012-05-02 | CN103582680A | 2014-02-12 | S·马夸伊斯-比奈瓦尔德; C·克雷梅尔; B·弗洛林 |
| 本发明公开了式(1)或式(2)的化合物。这些化合物用于染色有机材料，例如角质纤维、羊毛、皮革、丝绸、纤维素或聚酰胺，尤其是含有角质的纤维，棉或尼龙，优选毛发，更优选人毛发。(1)(2)。(1)A-(X1)p-(Csat)r-S-S-(Csat)q-(X2)p-D | ||||||
| 2 | 有机材料染色用的黄色阳离子染料 | CN03802236.2 | 2003-01-07 | CN1615343A | 2005-05-11 | V·P·埃柳; B·弗勒林; J·豪泽 |
| 本发明涉及一种通式(I)的新型黄色阳离子染料，其中R1和R2彼此独立地是C1～C8烷基基团或未取代或取代的苄基基团，条件是，取代基R1和R2至少之一是未取代或取代的苄基基团R3是氢、C1～C8烷基、C1～C8烷氧基、氰基或卤原子，优选氢，以及X－是阴离子，条件是，当R1是苄基基团且R2是甲基基团时，R3不是氢，还涉及其组合物，尤其是含有其他染料的，涉及其制备方法及其在染有机材料，例如，角蛋白、毛、丝、纤维素或聚酰胺，尤其是含角蛋白纤维、棉或尼龙，优选人发上的应用。 | ||||||
| 3 | 着色组合物、着色固化膜及显示元件 | CN201480030683.3 | 2014-05-26 | CN105246978B | 2017-09-26 | 米田英司; 江幡敏; 仓怜史; 成濑秀则 |
| 本发明提供一种适合于形成能兼顾耐热性与耐溶剂性的着色固化膜的着色组合物。一种着色组合物，是包含(A)着色剂和(B)聚合性化合物的着色组合物，所述着色剂含有具有下述式(1)所示的结构单元的化合物，[式(1)中，R1表示氢原子、甲基或三氟甲基；R2和R3相互独立地表示氢原子、卤素基或者取代或未取代的烃基，其中R2和R3中至少一个为卤素基或卤素取代的烃基；A表示2价基团；G表示2价烃基或单键，其中2价烃基在C‑C键间也可具有选自‑O‑基、‑S‑基、‑CO‑基、‑NR7‑基中的连结基团，R7表示氢原子或者取代或未取代的烃基；Zm+表示阳离子性发色团；m表示1～3的自然数；p表示1～8的自然数]。 | ||||||
| 4 | 含有腙结构部分的有机染料及其在染料敏化太阳能电池中的用途 | CN201380034934.0 | 2013-06-26 | CN104411775A | 2015-03-11 | I·布鲁德; R·森德; S·乌尔尼凯特; T·马利瑙斯卡斯; M·达斯凯维奇内; V·格陶蒂斯 |
| 本发明涉及通式(I)化合物，其中R100和R200各自独立为氢，C1-C10烷基，在C2烷基的情况下，其可间隔有一个氧原子，在C3-C10烷基的情况下，其可间隔有一个或两个不相邻的氧原子，C5-C7环烷基，芳基，芳基-C1-C10烷基或芳氧基-C1-C10烷基，D为含有至少一个碳-碳或碳-杂原子双键和/或至少一个未稠合或稠合碳-或杂环的m价(m＝1、2或3)给体结构部分，A为含有至少一个碳-碳或碳-杂原子双键和/或至少一个未稠合或稠合碳-或杂环的受体结构部分，给体结构部分D和受体结构部分A彼此π-共轭。此外，本发明涉及式(I)化合物在制备染料敏化太阳能电池中的用途以及包含式(I)化合物的染料敏化太阳能电池。 | ||||||
| 5 | 双阳离子二腙化合物、包含至少一种该化合物的染料组合物、其实施方法及其应用 | CN200510113510.0 | 2005-10-14 | CN1796371A | 2006-07-05 | H·达维德; A·格里夫斯; L·埃尔库埃; A·拉格朗日 |
| 本发明涉及一类可用作直接染料的新型双阳离子二腙化合物，和在合适的染色介质中包含至少一种该化合物的用于染色角蛋白纤维，尤其是人角蛋白纤维如头发的染料组合物。本发明还涉及实施该组合物的染色方法及其应用。 | ||||||
| 6 | 有机溶剂基印刷油墨 | CN03817843.5 | 2003-07-17 | CN1671809A | 2005-09-21 | I·F·弗拉塞尔; S·C·尼文; J·维尔科克斯 |
| 本发明公开了一种印刷油墨组合物，其包含吲哚类阳离子染料，有机溶剂，可溶于有机溶剂中的，有机酸优选树脂酸，和可有可元的有机颜料。阳离子染料由其甲醇前体(原位)形成。该组合物具有例如高颜色强度和优异的流变性能，并可用于出版物或包装凹版柔性图形，平版印刷或凸印印刷工艺。 | ||||||
| 7 | 二硫化物染料 | CN201280027370.3 | 2012-05-02 | CN103582680B | 2016-04-06 | S·马夸伊斯-比奈瓦尔德; C·克雷梅尔; B·弗洛林 |
| 本发明公开了式(1)或式(2)的化合物。这些化合物用于染色有机材料，例如角质纤维、羊毛、皮革、丝绸、纤维素或聚酰胺，尤其是含有角质的纤维，棉或尼龙，优选毛发，更优选人毛发。(1)A-(X1)p-(Csat)r-S-S-(Csat)q-(X2)p-D。 | ||||||
| 8 | 黄色系染发用染料、染发用组合物及染发方法 | CN201480034726.5 | 2014-06-10 | CN105324105A | 2016-02-10 | 秋叶光弘; 铃木健一郎; 权田通博; 矶边昌敏 |
| 本发明涉及含有下述通式(I)所示化合物的染发用染料、含有其的染发用组合物以及染发方法。[式中，R1、R2和R3各自独立地表示氢原子、直链或支链的碳数为1～6的烷基、或者直链或支链的碳数为1～6的烷氧基，An-表示无机阴离子或有机阴离子]。 | ||||||
| 9 | 着色组合物、着色固化膜及显示元件 | CN201480030683.3 | 2014-05-26 | CN105246978A | 2016-01-13 | 米田英司; 江幡敏; 仓怜史; 成濑秀则 |
| 本发明提供一种适合于形成能兼顾耐热性与耐溶剂性的着色固化膜的着色组合物。一种着色组合物，是包含(A)着色剂和(B)聚合性化合物的着色组合物，所述着色剂含有具有下述式(1)所示的结构单元的化合物，[式(1)中，R1表示氢原子、甲基或三氟甲基；R2和R3相互独立地表示氢原子、卤素基或者取代或未取代的烃基，其中R2和R3中至少一个为卤素基或卤素取代的烃基；A表示2价基团；G表示2价烃基或单键，其中2价烃基在C-C键间也可具有选自-O-基、-S-基、-CO-基、-NR7-基中的连结基团，R7表示氢原子或者取代或未取代的烃基；Zm+表示阳离子性发色团；m表示1～3的自然数；p表示1～8的自然数]。 | ||||||
| 10 | 三价阳离子染料 | CN200780022263.0 | 2007-06-04 | CN101466797A | 2009-06-24 | 克里斯琴·克里默; 奥洛夫·沃尔奎斯特; 维克托·P·埃利厄; 基肖尔·R·尼瓦尔卡 |
| 本发明披露了式(1)的化合物，其中D是芳族基团或阳离子杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、羟基－C1－C14烷基、C3－C8环烷基、－CN，NO2、－NR3R4、卤素、任选被C1－C14烷基取代的C6－C10芳基，或一个或多个基团Z；E1和E2各自独立地为＝CH；或＝N－；K为芳族基团或杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、C3－C8环烷基、C6－C10芳基、卤素、羟基、NO2、－NR3R4、－N(R3)(CO)R4、－SO2NR1R2、－SONR1R2或一个或多个Z；或式－NR1R2的基团；R1和R2各自独立地为氢；C1－C14烷基；C1－C14环烷基；C6－C10芳基；芳族基团或杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、C3－C8环烷基、C6－C10芳基、卤素、羟基、－NR5R6、－N(R5)－(CO)R5或Z；Z是式(1a)*－X1－Y1－W1的基团，其中X1是直接键；－NR7－；－O－；－NR7(C＝O)－；－(CO)NR7－；－O(C＝O)－；－(CO)O－；或－(C＝O)－；Y1是直接键；C1－C12亚烷基，所述C1－C12亚烷基可任选被－O－、－NR8、－S－、－(C＝O)－、－O(C＝O)－、(C＝O)O－、－NR7(C＝O)－、－(C＝O)NR7－隔断，并且其可被C1－C14烷基、羟基－C1－C14烷基、羟基、－NR9R10或卤素取代；或C6－C10亚芳基，所述C6－C10亚芳基可被C1－C14烷基、羟基－C1－C14烷基、羟基、氨基或卤素取代；W1是阳离子基团；和R3、R4、R5、R6、R7、R8、R9和R10各自独立地为氢；C1－C14烷基；或Z；和An1－、An2－和An3－各自独立地为阴离子。所述化合物可用于对有机物质进行染色，所述有机物质例如是角蛋白纤维、羊毛、皮革、丝、纤维素或聚酰胺，特别是含角蛋白的纤维、棉或尼龙、优选为毛发，更优选为人类毛发。 | ||||||
| 11 | 阳离子取代的腙染料 | CN200480004356.7 | 2004-02-09 | CN1751100A | 2006-03-22 | V·P·艾留; B·弗勒林 |
| 本发明涉及新颖的通式(1)、(2)或者(3)的阳离子染料，其中R1和R2各自独立地是C1－C8烷基或者未被取代或被取代的苄基，R3是氢、C1－C8烷基、C1－C8烷氧基、氰化物或者卤化物，和R4是C1－C8烷基或者未被取代或被取代的芳基，和X－是阴离子。此外，本发明涉及其组合物、尤其是包含其它染料的组合物，涉及其制备方法以及其在有机材料染色中的用途，所述有机材料例如是角蛋白纤维、特别是毛发；或者羊毛、皮革、丝、纤维素或者聚酰胺，并且优选人发。 | ||||||
| 12 | Disulfide dyes | US14114783 | 2012-05-02 | US08992633B2 | 2015-03-31 | Sophie Marquais-Bienewald; Christian Cremer; Beate Frohling |
| Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2). A-(X1)p—(Csat)r—S—S—(Csat)q—(X2)p-D (1) | ||||||
| 13 | POLYMERIC HAIR DYES | US13381967 | 2010-07-15 | US20120110750A1 | 2012-05-10 | Christian Cremer; Oliver Becherer; Beate Fröhling |
| Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —S—, —S—S—, —N—, —N═—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (formula II) —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; which may be interrupted and/or terminated at one or both ends by one or more than one —C1C30alkylene- or —C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are —CR8— or —NR9+-; and at least one of Z1, Z2 or Z3 is —NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1-C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; —NO2; —Cl; —Br; —COOH; —SO3H; —CN; NH2; or CH3—CO—NH—; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m+n+p≧3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing. | ||||||
| 14 | Dichromophore carbonyl or heterocyclic dye, dye composition comprising this dye, process for dyeing keratin materials using this dye | US12679657 | 2008-09-23 | US08075638B2 | 2011-12-13 | Andrew Greaves |
| The invention relates to the dyeing of keratin materials using dichromophore dyes with a carbonyl or heterocyclic linker. The invention relates to a dye composition comprising a dye with a carbonyl or heterocyclic linker, and to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers such as the hair, using said composition, optionally in the presence of a cosmetically acceptable acid or base. It similarly relates to novel dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers. | ||||||
| 15 | Tricationic dyes | US12308042 | 2007-06-04 | US07794509B2 | 2010-09-14 | Christian Cremer; Olof Wallquist; Victor Paul Eliu; Kishor Ramachandra Nivalkar |
| Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims. [D-E1=E2-K]3+(An1−) (An2−) (An3−) (1) | ||||||
| 16 | Dyes containing a thiol group | US11990813 | 2006-08-21 | US07771490B2 | 2010-08-10 | Victor Paul Eliu; Beate Fröhling; Dominique Kauffmann |
| Disclosed are thiol dyes of formula (I), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds. | ||||||
| 17 | Yellow cationic dyes for dyeing of organic material | US10501576 | 2003-01-07 | US20050000034A1 | 2005-01-06 | Victor Eliu; Beate Brohling; Julia Hauser |
| The present invention relates to novel cationic yellow dyes of formula (1) wherein R1 and R2 are each independently of the other a C1-C8alkyl radical or an unsubstituted or substituted benzyl radical, R3 is hydrogen, C1-C8alkyl, C1-C8alkoxy, cyanide or halide, preferably hydrogen and X is an anion, with the proviso that at least one of the substitutents R1 is a benzyl radical and R2 is a methyl radical, R2 is not hydrogen, also to compositions therof, especially comprising other dyes, to processes for the preparation therof and to the use therof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, especially keratin-containging fibres, cotton or nylon, and preferably human hair. | ||||||
| 18 | Method for reducing the toxicity of spent liquors and novel cationic dyes | US937289 | 1997-09-25 | US5869731A | 1999-02-09 | Henry Giera; Felix Reichel; Horst Berneth |
| There has been found1) a method for reducing the toxicity of spent liquors from dyeing with cationic dyes or mixtures thereof, characterized by the step of dyeing with cationic dyes having a computed electrostatic shielding energy (idealized hydration energy) of .gtoreq.50 kcal/mol,2) cationic, generally low toxicity dyes, their preparation and use for dyeing. | ||||||
| 19 | Metal complexes of azomethines | US955038 | 1978-10-26 | US4237292A | 1980-12-02 | Francois L'Eplattenier; Andre Pugin; Jost von der Crone |
| Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties. | ||||||
| 20 | Process for the manufacture of cationic hydrazone dyes | US680638 | 1976-04-27 | US4026885A | 1977-05-31 | Christian Frey; Peter Moser |
| A process for the manufacture of dyes of the formula ##STR1## WHEREIN EACH OF R.sub.1 and R.sub.2 represents a methyl or ethyl radical, n is 1 or 2, X.sup.- is the charge equivalent of an anion and B represents a divalent radical which completes the ring a to form a pyridinium or quinolinium ring which is unsubstituted or substituted by chlorine or methyl, and the ring b is unsubstituted or substituted by low molecular alkyl or alkoxy or by halogen, which process comprises treating a compound of the formula ##STR2## WHEREIN R.sub.1, n, X.sup.-, B, a and b are as defined in formula (1) and m is 1 or 2, in aqueous medium at a pH of 12 or above, with dimethyl or diethyl sulphate, with the proviso that if m=1, at least 2 equivalents of dimethyl or diethyl sulphate are used. | ||||||
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