序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
201 Multifunctional melamine epoxy resins, methylols and amines US13879289 2012-10-31 US08911858B2 2014-12-16 Georgius Abidal Adam
Multifunctional melamine epoxy resins, methylols and amines are provided. Methods of making multifunctional melamine epoxy resins, methylols and amines are also provided.
202 Process for Making Hybrid Polyester-Polyether Polyols US14365961 2012-12-10 US20140357887A1 2014-12-04 Pavel L. Shutov; David S. Laitar; David A. Babb
Hybrid polyester-polyether polyols are prepared by polymerizing an alkylene oxide in the presence of a carboxylate initiator. The polymerization is catalyzed with a mixture of double metal cyanide catalyst complex and certain magnesium, group 3-group 15 metal or lanthanide series metal compounds.
203 POLY(ARYL ETHER SULFONE) COMPOSITION AND METHOD OF MAKING US14263063 2014-04-28 US20140350207A1 2014-11-27 Eric Lee Lutz; William Hoy Heath; Roy Ray Odle; Thomas Link Guggenheim; Juan Justino Rodriguez Ordonez; Jose Roman Galdamez Pena
A poly(aryl ether sulfone) comprises units of formula (I): wherein Ar1 is a divalent C6-C15 aromatic group, Ar2 is a divalent C6-C15 aromatic group, Ar3 is a divalent C6-C15 aromatic group, and n is greater than 1;and a terminal group of formula (II) derived from a monofunctional phenoxide wherein is X is a hydrogen atom or an organic substituent having from 1 to 20 carbon atoms; wherein the poly(aryl ether sulfone) has a hydroxyl group content greater than 0 and less than 50 parts per million (ppm), based on the poly(aryl ether sulfone) weight, a glass transition temperature of 180 to 290° C., a weight average molecular weight of 20,000 to 100,000, a halogen content of greater than 0 and less than 3000 ppm based on the poly(aryl ether sulfone) weight. The poly(aryl ether sulfone) can have a thermal stability factor greater than or equal to 90%. The poly(aryl ether sulfone) can have a yellowness index (YI) less than 120 after an article made from the poly(aryl ether sulfone) is exposed to a temperature of 200° C. in ambient air for 28 days. The poly(aryl ether sulfone) is free of methoxy groups. Methods of making the polymer are also disclosed.
204 Crosslinked polymers with the crosslinker as therapeutic for sustained release US13862500 2013-04-15 US08889889B2 2014-11-18 Rachit Ohri; Phillip Blaskovich; Joshua Kennedy; Steven L. Bennett; Arthur Driscoll
Crosslinked polymers, methods for their preparation and use, are described in which the crosslinked polymers are formed from at least two polymer precursors, one of which is designed, upon degradation of the crosslinked polymer, to release the second polymer precursor in its original, unmodified chemical form.
205 THIOL-SELECTIVE WATER-SOLUBLE POLYMER DERIVATIVES US14229547 2014-03-28 US20140330041A1 2014-11-06 Antoni Kozlowski; Remy F. Gross, III; Samuel P. McManus
The present invention provides water-soluble, polymer derivatives having a thiol-selective terminus suitable for selective coupling to thiol groups, such as those contained in the cysteine residues of proteins, as well as methods for preparing the water-soluble, polymer derivatives having a thiol-selective terminus.
206 PROCESS FOR REDUCING UNSTABLE END-GROUPS IN FLUORINATED POLYMERS US14359825 2012-11-20 US20140309376A1 2014-10-16 Marco Galimberti; Stefano Millefanti; Vito Tortelli
A process for reducing the number of unstable end-groups in a fluorinated polymer is disclosed, said process comprising reacting a fluorinated polymer comprising unstable end-groups with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond. The fluorinated polymer may be selected from those polymers comprising recurring units derived from at least one ethylenically unsaturated fluorinated monomer or from fluorinated polyethers.
207 SEMIBATCHWISE PROCESS FOR PREPARING OLEFIN-CO COPOLYMERS US14203867 2014-03-11 US20140275475A1 2014-09-18 Thomas Ernst Müller; Christoph Gürtler; Walter Leitner; Henning Vogt; Saeeda Soomro
A process for preparing olefin-CO copolymers with the steps of: providing a reactor; charging the reactor with a gaseous olefin and with CO, such that there is a first pressure p1 in the reactor; and reacting olefin with CO in the presence of a catalyst in the reactor. Prior to the reaction, either no CO is present in the reactor or the volume ratio of gaseous olefin to CO is ≧90:10. During the reaction, gaseous olefin and CO are metered in at least intermittently, with an average over time of the volume ratio of the olefin metered into CO metered in of ≧90:10.
208 LINEAR (PER) FLUOROPOLYETHERS WITH -CF(CF3)COF END GROUPS AND DERIVATIVES THEREOF US14349468 2012-09-25 US20140243547A1 2014-08-28 Simonetta Antonella Fontana; Claudio Adolfo Pietro Tonelli; Piero Gavezotti
The present invention relates to mono- or bi-functional (per)fluoropolyethers comprising a linear (per)fluoropolyether chain having two ends, wherein one or two ends contain —CF(CF3)COF groups, to a process for preparing them and to their use as precursors in the preparation of further functionalised (per)fluoropolyethers. The invention also relates to these further functionalised (per)fluoropolyethers.
209 (PER) FLUOROPOLYMER COMPOSITION US14236282 2012-07-17 US20140235816A1 2014-08-21 Vincenzo Arcella; Claudio Adolfo Pietro Tonelli; Solange Barbieri
The present invention relates to (per)fluoropolymer compositions, in particular to (per)fluoropolyether compositions comprising: —a (per)fluoropolymer having more than two carboxy groups and —a polyamine. The invention further relates to processes for preparing said compositions and to moulded articles obtained from said compositions.
210 Polymer electrolyte membrane US13890687 2013-05-09 US08796412B2 2014-08-05 Seong-Ho Choi; Won-Ho Lee
Disclosed are a multi-block copolymer, its producing method and an electrolyte membrane using the same. The multi-block copolymer includes a hydrophobic block having a plurality of repeating units represented as chemical formula 1; and a hydrophilic block having a plurality of repeating units represented as chemical formula 2. The multi-block copolymer is acidified, and can be used to an electrolyte membrane and a fuel cell. The use of the multi-block copolymer as an electrolyte membrane ensures excellent dimensional stability.
211 GLUCOSE-PEG CONJUGATES FOR REDUCING GLUCOSE TRANSPORT INTO A CELL US14149493 2014-01-07 US20140193849A1 2014-07-10 Karthikeyan Narayanan; Andrew Chwee Aun Wan; Jackie Y. Ying; Nandanan Erathodiyil
There is provided a glucose-PEG conjugate comprising a PEG moiety conjugated to a linear glucose moiety at the C1 position of the glucose moiety. The glucose-PEG conjugate may be used to reduce glucose transport into a cell and may be used to treat a proliferative disorder.
212 TELECHELIC MACROMER, METHOD FOR PRODUCING TELECHELIC MACROMER AND COMPOSITION CONTAINING TELECHELIC MACROMER US13727859 2012-12-27 US20140187663A1 2014-07-03 Miroslawa EL FRAY; Jedrzej Skrobot
A telechelic macromer is disclosed having (meth)acrylic end-groups and a core. The macromer defined by Formula 1 comprises a core Y (Formulas 2 to 9) that is linked to (meth)acrylic groups by urethane, ester or anhydride bonds and has iodine value ranging from 5 to 75. The method involves a chemical reaction carried out in solvent, ranging 6-24 hours, wherein the precursor of a core (Formulas 2 and 3) reacts in two stages with compounds forming urethane bonds, or wherein the precursor of a core (Formulas 4 to 8) reacts in one stage with compounds forming ester bonds, or wherein the precursor of a core defined by Formula 9 reacts in one stage with compounds forming anhydride bonds. The urethane, ester and anhydride moieties comprise groups capable of free radical polymerization isolating the final product by evaporation. The composition disclosed provides the macromer, a photoinitiator and possibly a reactive diluent.
213 N-maleimidyl polymer derivatives US13890799 2013-05-09 US08765111B2 2014-07-01 Xiaoming Shen
The invention is directed to multi-functional N-maleimidyl polymer derivatives comprising a water soluble and non-peptidic polymer backbone having a terminal carbon, such as a poly(alkylene glycol), the terminal carbon of the polymer backbone being directly bonded to the nitrogen atom of a N-maleimidyl moiety without a linking group therebetween. The invention also provides two methods of preparing such linkerless N-maleimidyl polymer derivatives.
214 PROCESS FOR MAKING POLYETHER ALCOHOLS HAVING OXYETHYLENE UNITS BY POLYMERIZATION OF ETHYLENE CARBONATE IN THE PRESENCE OF DOUBLE METAL CYANIDE CATALYSTS US14234577 2012-08-15 US20140163197A1 2014-06-12 Esther E. Quintanilla; Hanno R. Van Der Wal; Daniel C. Floyd; Myriam Linke; Francois M. Casati; Carlos M. Villa; Jean-Paul Masy; Ricco B. Borella; Paul Cookson
Ethylene carbonate is polymerized by itself or together with another cyclic monomer such as 1,2-propylene oxide in the presence of a double metal cyanide catalyst. Most of the ethylene carbonate adds to the chain to form a terminal carbonate group, which decarboxylates to produce a hydroxyethyl group at the end of the polymer chain. The polymerization of more ethylene carbonate onto the chain end results in the formation of poly(ethyleneoxy) units. Therefore, the process provides a method for making poly(ethyleneoxy) polymers without the need to polymerize ethylene oxide. The process is useful for making polyethers that are useful as water-absorbable polymers, surfactants and as raw materials for polyurethanes. The process is also useful for increasing the primary hydroxyl content of a polyether.
215 Thiol-selective water-soluble polymer derivatives US13681357 2012-11-19 US08722032B2 2014-05-13 Antoni Kozlowski; Remy F. Gross, III; Samuel P. McManus
The present invention provides water-soluble, polymer derivatives having a thiol-selective terminus suitable for selective coupling to thiol groups, such as those contained in the cysteine residues of proteins, as well as methods for preparing the water-soluble, polymer derivatives having a thiol-selective terminus.
216 Chemically resistant membranes, coatings and films and methods for their preparation US13202303 2010-02-21 US08710109B2 2014-04-29 Charles Linder; Ora Kedem; Yoram Oren
There is provided herein a membrane or film comprising one or more aromatic ionomers covalently crosslinked through aryl-aryl (—Ar—Ar—), aryl-ether-aryl (—Ar—O—Ar—), aryl-sulfide-aryl (—Ar—S—Ar—), aryl-sulfone-aryl bonds, or any combination thereof, wherein said one or more aromatic ionomers further comprises at least one electron withdrawing group adapted to improve oxidant resistance of said membrane or film.
217 TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE US14003141 2012-02-24 US20140073737A1 2014-03-13 Miguel A. Guerra; Rudolf J. Dams; Steven G. Corveleyn
There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
218 ALKYL ETHER COMPOSITIONS AND METHODS OF USE US13761512 2013-02-07 US20140039214A1 2014-02-06 William B. CARLSON; Gregory D. Phelan
A polymer includes a linker represented by Formula I ([OR1OCH2OR2OCH2]m), where R1 and R2 are, independently, alkylene, alkenylene, arylene, heteroarylene, or alkylarylalkylene; and the polymer has a weight average molecular weight of about 500 g/mol to about 2,000,000 g/mol, and m is 1 to 1000.
219 MONO-LAYER THIN FILM ADHESIVE COMPOUNDS AND METHODS OF SYNTHESIS AND USE US13951182 2013-07-25 US20140030944A1 2014-01-30 John L. Murphy; Jeffrey L. Dalsin; Arinne N. Lyman; Laura L. Vollenweider; Joel L. Broussard; Neil Winterbottom; Justin T. Koepsel
The invention relates provides synthetic medical adhesives which exploit plant derivatives to form covalent bonds with amines and thiols on tissue surfaces.
220 ACETAL METATHESIS POLYMERIZATION US14034839 2013-09-24 US20140024801A1 2014-01-23 STEPHEN A. MILLER; ALEXANDER G. PEMBA
A method of preparing a polyacetal comprising polymerization of a mixture comprising a plurality of at least one bis-acetal monomer in the presence of an acid catalyst that promotes the metathesis of the acetal units. The bis-acetal can be formed from an acid catalyzed exchange between a mono-acetal monomer with a diol. The formation of the bis-acetal and the polyacetal can be carried out simultaneously. The diol can be isolated from a biorenewable source and the ultimate polyacetal is a degradable or biodegradable polymer.
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