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Desulfurization with subsequent h{11 s absorption

阅读:63发布:2023-04-05

专利汇可以提供Desulfurization with subsequent h{11 s absorption专利检索,专利查询,专利分析的服务。并且Process for removal of a selected constituent from a vapor stream which comprises contacting the vapor stream in a high pressure absorption zone with a first stream of lean absorbent, mixing the resulting rich absorbent with a second stream of lean absorbent in a low pressure contacting zone, and separating the resulting mixture in a separation zone under conditions sufficient to provide selected constituent and separated lean absorbent. In a preferred embodiment, the separation zone comprises a phase separator and a low pressure absorption zone, the resulting mixture is passed from the low pressure contacting zone into the phase separator, and a resulting vapor stream is passed from the phase separator into the low pressure absorber wherein it is contacted with a third lean absorbent stream. The process has particular utility in the removal of selected constituent, such as an acid gas or mixture of acid gases, in a high pressure absorption zone maintained at a pressure in excess of 1,000 psig. Particular application is in the removal of hydrogen sulfide from a hydrogenation reaction zone, such as a hydrotreating zone or a hydrocracking zone, wherein a hydrocarbon charge stock containing organic sulfur compounds is desulfurized.,下面是Desulfurization with subsequent h{11 s absorption专利的具体信息内容。

  • 2. Process of claim 1 wherein said separation zone comprises a phase separator and said low pressure absorption zone, said second rich absorbent stream is passed into said phase separator under conditions sufficient to provide a third vapor stream and a third rich absorbent, said third vapor stream is contacted in said low pressure absorption zone with a third portion of separated lean absorbent under conditions sufficient to provide a fourth rich absorbent and a fourth vapor stream having substantial freedom from selected constituent, and said third rich absorbent and said fourth rich absorbent are separated under conditions sufficient to provide said separated lean absorbent.
  • 3. Process of claim 1 wherein the ratio of said first portion of separated lean absorbent to said second portion of separated lean absorbent is in the range of from about 7:3 to about 3:7.
  • 4. Process of claim 1 wherein said high pressure absorption zone is maintained at a pressure of at least 1,000 psig.
  • 5. Process of claim 4 wherein said selected constituent comprises an acid gas selected from the group consisting of hydrogen sulfide, carbon dioxide, and carbonyl sulfide.
  • 6. Process of claim 5 wherein said lean absorbent comprises an amine absorbent selective for said acid gas, said amine absorbent selected from the group consisting of monoethanolamine, diethanolamine, diglycolamine, and aminodiisopropanol.
  • 7. Process of claim 6 wherein said high pressure absorption zone is maintained at a temperature below 200*F.
  • 8. In a hydrogenation process wherein a hydrocarbon charge stock containing organic sulfur compounds is reacted in a high pressure reaction zone with a stoichiometric excess of hydrogen under desulfurization conditions including the presence of a hydrogenation catalyst selective for desulfurizing organic sulfur compounds, a resulting reaction zone effluent is separated into a hydrocarbon liquid phase and into a hydrogen-rich vapor phase containing hydrogen sulfide, and said hydrogen-rich vapor phase is returned at least in part to said reaction zone, the improvement which comprises: a. contacting at least a portion of said hydrogen-rich vapor phase in a high pressure absorption zone, with a hereinafter specified first stream of lean absorbent selective for hydrogen sulfide; b. removing from said absorption zone, a hydrogen-rich vapor stream having reduced concentration of hydrogen sulfide; c. withdrawing from said absorption zone, a first rich absorbent containing hydrogen sulfide; d. mixing said first rich absorbent with a hereinafter specified second stream of said lean absorbent in a low pressure liquid-liquid contacting zone of high turbulence under conditions sufficient to provide a reduced mole ratio of hydrogen sulfide to absorbent in a resulting second rich absorbent; e. passing said resulting second rich absorbent from said contacting zone into a separation zone which includes a low pressure absorption zone, said separation zone maintained under conditions sufficient to provide a stream comprising hydrogen sulfide and a stream comprising separated lean absorbent; f. passing a first portion of separated lean absorbent into said high pressure absorption zone as said specified first stream of lean absorbent; g. passing a second portion of said separated lean absorbent into said low pressure contacting zone as said specified second stream of lean absorbent; and, h. passing from said high pressure absorption zone into said high pressure reaction zone, said hydrogen-rich vapor stream having reduced concentration of hydrogen sulfide.
  • 9. Process of claim 8 wherein said high pressure reaction zone and said high pressure absorption zone are maintained at a pressure in excess of 1000 psig.
  • 10. Process of claim 8 wherein said lean aBsorbent comprises an organic amine compound selective for hydrogen sulfide, said organic amine compound selected from the group consisting of monethanolamine, diethanolamine, diglycolamine, and aminodiisopropanol.
  • 11. Process of claim 8 wherein said separation zone comprises a phase separator and said low pressure absorption zone, said second rich absorbent is passed into said phase separator under conditions sufficient to provide a separated vapor stream and a third rich absorbent, said separated vapor stream is contacted in said low pressure absorption zone with a third portion of separated lean absorbent under conditions sufficient to provide a fourth rich absorbent and a contacted vapor stream having substantial freedom from hydrogen sulfide, and said third rich absorbent and said fourth rich absorbent are separated under conditions sufficient to provide said separated lean absorbent.
  • 12. Process of claim 8 wherein the ratio of said first portion of separated lean absorbent to said second portion of separated lean absorbent is in the range of from about 7:3 to about 3:7.
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