首页 / 专利库 / 油,脂肪和蜡 / 蜡油 / Isomerization of waxy lube streams and waxes using zeolite catalyst

Isomerization of waxy lube streams and waxes using zeolite catalyst

阅读:287发布:2022-01-11

专利汇可以提供Isomerization of waxy lube streams and waxes using zeolite catalyst专利检索,专利查询,专利分析的服务。并且Waxy hydrocarbons, per se or in a petroleum fraction in the lubricating oil viscosity range, can be converted to oily, nonwaxy hydrocarbons by contacting the wax or wax-containing stream with an acidic alumino-silicate zeolite catalyst (e.g., CeHY, GdHX, CaHX, MgHY, NiHY, etc.) preferably in combination with a hydrogenation catalyst (e.g., Ni, Co, Mo, W, Pt, Pd, Re, Ru, etc.) at temperatures above 300*F. and at elevated hydrogen pressure (e.g., 400-6,000 p.s.i., more preferred at least 1,500 p.s.i. of hydrogen, the hydrogen purity being 50-100 percent). Preferably, the zeolite contains polyvalent metal cations, is virtually free from alkali metal cations and halide ions and is substantially anhydrous (containing about 1-10% H20 as determined by ignition analysis at 1,800*F.). Preferably, the isomerization is conducted at a temperature below the point where substantial hydrocracking will occur (e.g., below about 675*F.). More preferably, the temperature, space velocity, hydrogen pressure and gas recycle rate are so selected as to attain significant conversion of the waxy hydrocarbons to oils in the lubricating oil boiling range and with no appreciable conversion of the waxy hydrocarbons to materials boiling below the lubricating oil boiling range.,下面是Isomerization of waxy lube streams and waxes using zeolite catalyst专利的具体信息内容。

  • 2. Process according to claim 1 wherein said conditions are selected so as to attain said conversion with no appreciable conversion of said waxy hydrocarbons to materials of lower carbon number.
  • 3. Process according to claim 1 wherein said temperature is in the range of 550* to 650*F. and wherein less than 10 percent of the waxy hydrocarbon which is so contacted is converted to hydrocarbons boiling below 600*F.
  • 4. Process according to claim 2 wherein said temperature is in the range of 500*-575*F.
  • 5. Process according to claim 2 wherein said temperature is in the range of 520*-560*F.
  • 6. Process according to claim 1 wherein said waxy hydrocarbons are contained in a distillate oil having a viscosity at 100*F. in the range of 35-10,000 SUS and wherein the concentration of wax in said distillate is less than 50 weight percent and wherein said contact temperature is no greater than 650*F.
  • 7. Process according to claim 6 wherein said wax concentration is less than about 20 percent and wherein said temperature is no greater than 550*F. and wherein said contacting is at a liquid hourly space velocity in the range of 0.5 to 5.
  • 8. Process according to claim 2 whereisaid wherein said hydrocarbons are contained in a feed material comprising from 50-100 percent wax, wherein said temPerature is no greater than 550*F. and wherein less than 15 percent of the charge stock is converted, in a single pass through a reactor, to products boiling below 650*F.
  • 9. Process according to claim 1 wherein said waxy hydrocarbons are contained in a raffinate oil obtained by solvent extraction of a distillate oil having a viscosity at 100*F. in the range of 35-10,000 SUS.
  • 10. Process according to claim 1 wherein said alumino-silicate zeolite catalyst is combined with a hydrogenation catalyst, and wherein said catalyst combination includes at least one metal, oxide or sulfide of at least one metal selected from the group consisting of Ni, Co, Mo, W, Pt, Pd, Re and Ru.
  • 11. Process according to claim 1 wherein said waxy hydrocarbons are contained in an oily feed stock which contains less than 50 weight percent of wax and wherein less than 75 scf of C1-C5 hydrocarbon gases are produced, in a single pass through a reactor, for each barrel of fresh feed stock.
  • 12. Process according to claim 1 wherein less than 35 scf of C1-C5 hydrocarbon gases are produced, in a single pass through a reactor, for each barrel of fresh feed stock.
  • 13. Process according to claim 1 wherein the framework of said zeolite has a ratio Al/Si in the range of 0.35-0.65 and wherein in the range of 10-60 percent of the exchange capacity of said zeolite is satisfied by protons.
  • 14. Process according to claim 13 wherein at least 40 percent of the exchange capacity of said zeolite is satisfied by cations of cerium III.
  • 15. Process according to claim 1 wherein at least 90 percent of the feed to said process boils above 600*F.
  • 说明书全文
    高效检索全球专利

    专利汇是专利免费检索,专利查询,专利分析-国家发明专利查询检索分析平台,是提供专利分析,专利查询,专利检索等数据服务功能的知识产权数据服务商。

    我们的产品包含105个国家的1.26亿组数据,免费查、免费专利分析。

    申请试用

    分析报告

    专利汇分析报告产品可以对行业情报数据进行梳理分析,涉及维度包括行业专利基本状况分析、地域分析、技术分析、发明人分析、申请人分析、专利权人分析、失效分析、核心专利分析、法律分析、研发重点分析、企业专利处境分析、技术处境分析、专利寿命分析、企业定位分析、引证分析等超过60个分析角度,系统通过AI智能系统对图表进行解读,只需1分钟,一键生成行业专利分析报告。

    申请试用

    QQ群二维码
    意见反馈