Process for the defined increase of the molecular weight of solid,unsaturated elastomers

申请号 US27293972 申请日 1972-07-05 公开(公告)号 US3803080A 公开(公告)日 1974-04-09
申请人 HUELS CHEMISCHE WERKE AG; 发明人 NORDSIEK K;
摘要 The molecular weight of solid hydrocarbon elastomers, e.g., polybutadienes, is increased step-wise in a defined manner by subjecting them to thermal-mechanical treatment in which the elastomer is subjected to strong shearing forces at, e.g., 80*220* C., in the presence of a non-basic metallic compound as catalyst and a basic compound as cocatalyst.
权利要求
  • 2. A process according to claim 1 wherein the reaction mixture contains a filler.
  • 3. A process according to claim 2 wherein the filler is carbon black.
  • 4. A process according to claim 3 wherein the reaction mixture contains 40 to 120 percent of carbon black, based on the elastomer.
  • 5. A process according to claim 1 wherein the reaction mixture contains an extender oil.
  • 6. A process according to claim 5 wherein the reaction mixture contains 10 to 100 percent by weight of a predominantly aromatic or naphthenic type extender oil, based on the elastomer.
  • 7. A process according to claim 1 wherein the reaction mixture contains both an extender oil and a filler.
  • 8. A process according to claim 1 wherein the elastomer is a polydiene.
  • 9. A process according to claim 8 wherein the polydiene is a member of the group consisting of polybutadienes, polyisoprenes, and copolymers of butadiene and styrene.
  • 10. A process according to claim 1 wherein the reaction temperature is 120* to 190* C.
  • 11. A process according to claim 1 wherein the reaction mixture contains 1 to 5 percent by weight of water, based on the elastomer.
  • 12. A process according to claim 11 wherein the reaction mixture contains 1.5 to 3 percent by weight of water, based on the elastomer.
  • 13. A process according to claim 1 wherein the reaction mixture contains about 0.001 to 0.1 percent by weight of the metallic compound catalyst, based on the elastomer.
  • 14. A process according to claim 1 wherein the reaction mixture contains as the catalyst a salt of aluminum, trivalent iron, tin, boron, zinc, or of trivalent or tetravalent titanium.
  • 15. A process according to claim 14 wherein the salt is a halide salt.
  • 16. A process according to claim 15 wherein the reaction mixture contains FeCl3 or AlCl3 as catalyst.
  • 17. A process according to claim 1 wherein the reaction mixture contains about 0.04 to 0.9 percent by weight of the base as cocatalyst, based on the elastomer.
  • 18. A process according to claim 1, wherein the base co-catalyst is a member of the group consisting of alkali-metal and alkaline earth alcoholates, and primary, secondary, and tertiary amines.
  • 19. A process according to claim 18 wherein the co-catalyst base is an amine.
  • 20. A procesS according to claim 19 wherein the amine is a primary aromatic amine or diamine containing 6 to 30 carbon atoms.
  • 21. A process according to claim 20 wherein the amine is p-phenylenediamine, benzidine or p,p''-diaminodiphenylmethane.
  • 22. A process according to claim 1 wherein the starting elastomer has a molecular weight of between 10,000 and 50,000 and is a member of the group consisting of polybutadienes, polyisoprenes and copolymers of butadiene and styrene; the reaction is conducted for up to about 20 minutes at a temperature of 120* to 190* C; the reaction mixture contains a metallic compound catalyst selected from the group consisting of a salt of aluminum, trivalent iron, tin, boron, zinc, or trivalent or tetravalent titanium and an amine as the co-catalyst.
  • 23. A process according to claim 22 wherein the reaction mixture contains about 0.001 to 0.1 percent by weight of a halide salt as the catalyst and 0.04 to 0.9 percent by weight of a primary aromatic amine or diamine containing 6 to 30 carbon atoms as the cocatalyst, based on the elastomer.
  • 24. A process according to claim 1 wherein the molecular weights of the solid hydrocarbon elastomers are between 10,000 and 500, 000.
  • 25. A process according to claim 1 wherein the molecular weights of the solid hydrocarbon elastomers are between 50,000 and 250, 000.
  • 26. A process according to claim 22 wherein the co-catalyst is p-phenylenediamine, benzidine or p,p''-diaminodiphenylmethane.
  • 27. A process according to claim 23 wherein the co-catalyst is p-phenylenediamine, benzidine or p,p''-diaminodiphenylmethane.
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