Curable compositions comprising a polymeric bis-cyclopentadienyl compound and a poly-unsaturated material |
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申请号 | US24361062 | 申请日 | 1962-12-10 | 公开(公告)号 | US3242112A | 公开(公告)日 | 1966-03-22 |
申请人 | CIBA LTD; | 发明人 | ALFRED RENNER; RUDOLF WIDMER FRANZ; | ||||
摘要 | Dimeric 1,4-bis-(cyclopentadienyl)-butene-2 is prepared by heating the monomer to 70-150 DEG C. The monomeric 1,4-bis-(cyclopentadienyl) -butene-2 may be prepared by reacting 1,4 - dichlorobutene - 2 with cyclopentadienyl potassium or sodium or with cyclopentadienyl magnesium bromide when the whole reaction mixture may be heated to 70-150 DEG C. to obtain the dimer. The Specification describes but does not claim the preparation of dimeric a ,a 1-bis-(cyclopentadienyl)-para-xylone by adding tertiary butanol to a suspension of sodium in anhydrous tetrahydrofuran after which monomeric cyclopentadiene followed by a ,a 1-dichloro -para-xylene are added, the reaction mass is neutralized with acetic acid and the above dimer recovered by distillation under reduced pressure. Specifications 1,007,841 and 1,007,842 are referred to. | ||||||
权利要求 | 1. A CURABLE RESIN COMPOSITION OF MATTER, WHICH COMPRISES (1) AN OLIGOMERIC BIS (CYCLOPENTADIENYL) COMPOUND OF THE FORMULA |
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说明书全文 |