Dimeric bis(cyclopentadienyl)butenes and process for their preparation

申请号 US24339762 申请日 1962-12-10 公开(公告)号 US3210331A 公开(公告)日 1965-10-05
申请人 CIBA LTD; 发明人 ALFRED RENNER; RUDOLF WIDMER FRANZ;
摘要 Dimeric 1,4-bis-(cyclopentadienyl)-butene-2 is prepared by heating the monomer to 70-150 DEG C. The monomeric 1,4-bis-(cyclopentadienyl) -butene-2 may be prepared by reacting 1,4 - dichlorobutene - 2 with cyclopentadienyl potassium or sodium or with cyclopentadienyl magnesium bromide when the whole reaction mixture may be heated to 70-150 DEG C. to obtain the dimer. The Specification describes but does not claim the preparation of dimeric a ,a 1-bis-(cyclopentadienyl)-para-xylone by adding tertiary butanol to a suspension of sodium in anhydrous tetrahydrofuran after which monomeric cyclopentadiene followed by a ,a 1-dichloro -para-xylene are added, the reaction mass is neutralized with acetic acid and the above dimer recovered by distillation under reduced pressure. Specifications 1,007,841 and 1,007,842 are referred to.
权利要求
1. A PROCESS FOR THE MANUFACTURE OF CURED POLYMERIC RESINS WHEREIN DIMERIC 1,4-BIS(CYCLOPENTADIENYL)-BUTENE2, SAID DIMERIC 1,4-BIS(CYCLOPENTADIENYL)-BUTENE-2 BEING LIQUID AND SUBSTANTIALLY STABLE AT ROOM TEMPERATURE AND BEING OBTAINED BY HEATING MONOMERIC 1,4-BIS(CYCLOPENTADIENYL)-BUTENE-2 TO A TEMPERATURE OF FROM ABOUT 70*C. TO ABOUT 150*C., IS HEATED TO A TEMPERATURE OF FROM ABOUT 160*C. TO ABOUT 220*C.
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