序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 一种苏丹红Ⅳ的降解方法 CN201510943569.6 2015-12-16 CN105561517A 2016-05-11 何强; 李莹; 孔祥虹; 刘晓盼; 付骋宇
发明公开了一种苏丹红Ⅳ的降解方法,具体为:准备苏丹红Ⅳ固体或溶液试样;利用X-射线或γ-射线对苏丹红Ⅳ试样进行辐照降解。本发明利用X-射线或γ-射线辐照技术对致癌污染物苏丹红Ⅳ进行降解,对苏丹红Ⅳ固体的降解率达到12%以上,对苏丹红Ⅳ溶液的降解率达到73%以上,降解效果十分明显,而且成本低廉。在现有技术条件下,辐照过程是可控的,辐照射线本身不会残留,不会对环境造成二次污染,在处理污染、土壤污染方面有良好的应用前景。
2 含卤素、磷、硫和/或金属元素的有机化合物的处理方法 CN96103916.7 1996-03-07 CN1136971A 1996-12-04 E·布泽兹基
为处理在原子键上除了、氢和元素外,还包括卤素、磷、硫和/或金属元素的危险或有毒有机化合物,提出了使该有机化合物电离,紧接着进行电渗析的方法,此离子态的最终反应产物可容易操作,并且可毫无问题地进一步使用或以填埋或焚烧方式处理。在电离辐射作用下发生电离。本发明方法特别适合处理含卤素的芳族化合物如各种农药
3 X-ray targeted bond or compound destruction US14595431 2015-01-13 US09480856B2 2016-11-01 Michael G. Pravica, Sr.
This document provides methods, systems, and devices for inducing a decomposition reaction by directing x-rays towards a location including a particular compound. The x-rays can have an irradiation energy that corresponds to a bond distance of a bond in the particular compound in order to break that bond and induce a decomposition of that particular compound. In some cases, the particular compound is a hazardous substance or part of a hazardous substance. In some cases, the particular compound is delivered to a desired location in an organism and x-rays induce a decomposition reaction that creates a therapeutic substance (e.g., a toxin that kills cancer cells) in the location of the organism. In some cases, the particular compound decomposes to produce a reactant in a reactor apparatus (e.g., fuel cell or semiconductor fabricator).
4 X-RAY TARGETED BOND OR COMPOUND DESTRUCTION US14595431 2015-01-13 US20150196777A1 2015-07-16 Michael G. Pravica, SR.
This document provides methods, systems, and devices for inducing a decomposition reaction by directing x-rays towards a location including a particular compound. The x-rays can have an irradiation energy that corresponds to a bond distance of a bond in the particular compound in order to break that bond and induce a decomposition of that particular compound. In some cases, the particular compound is a hazardous substance or part of a hazardous substance. In some cases, the particular compound is delivered to a desired location in an organism and x-rays induce a decomposition reaction that creates a therapeutic substance (e.g., a toxin that kills cancer cells) in the location of the organism. In some cases, the particular compound decomposes to produce a reactant in a reactor apparatus (e.g., fuel cell or semiconductor fabricator).
5 Method and apparatus for disposing of organic halogen compounds US606049 1996-02-23 US5728914A 1998-03-17 Eduard Buzetzki
A method and integrated apparatus for disposing of an organic halogen compound comprising phosphorus and at least one element selected from the group consisting of sulfur and a metal, in addition to carbon, hydrogen and oxygen, in atomic bond, comprises the steps of ionizing the compound to obtain ionization products, splitting up the ionization products by electrodialysis to obtain ionic end products and residual organic substances, and disposing of the ionic end products and residual organic substances.
6 Method of treating refractory activated carbon by exposure to ionizing radiation US158816 1993-11-29 US5414204A 1995-05-09 Masakazu Hosono; Hidehiko Arai; Teijiro Miyata
The improved method of treating activated carbon having an organochlorine compound adsorbed thereon which comprises adding water to said activated carbon and then exposing said activated carbon to ionizing radiation, thereby decomposing and rendering harmless the organochlorine compound adsorbed on the activated carbon is described. The method is capable of safe and efficient decomposition of the activated carbon that has been used in adsorption treatment of organochlorine compounds such as PCBs and trichloroethylene that have heretofore been difficult to treat. The activated carbon that has hitherto simply been accumulated to date after adsorbing organochlorine compounds can be effectively treated by the method at low cost.
7 In-situ x-ray treatment of organically contaminated material US949777 1992-09-22 US5311566A 1994-05-10 Randy D. Curry; John R. Bayless
Organically contaminated earth-bound material is treated in-situ by positioning one or more x-ray converters in chambers formed in an earth and/or water site containing such earth-bound material and irradiating the contaminated material in-situ adjacent to each chamber with x-radiation from the x-ray converter to decompose the organic compounds. A high energy electron beam from a electron beam source is directed to the x-ray converter to produce the x-radiation. The electron beam source, such as a linear induction accelerator or an RF linear accelerator may be positioned either within the chamber near the x-ray converter or above ground.
8 Removal of dioxin generated accompanying with dust combustion JP23616590 1990-09-06 JPH03178389A 1991-08-02 MACHI SUEO; SATO SHOICHI; TOKUNAGA OKIKIMI; AOKI YASUSHI; SUDA SHOICHI; MIYAJI TSUNEHARU; SHIBAMURA YOKICHI; KAMISATOTA TORU; KAWAMURA KEITA; SUZUKI RYOJI
PURPOSE: To economically and safely remove dioxin generating a deadly poison accompanied with combustion by converting the same to a stable and harmless substance by adding moisture to dust combustion ash so as to adjust the moisture content of the ash to 10-90wt.% and irradiating the moistened ash with ionizing radiation under a specific condition. CONSTITUTION: Water 4 is added to dust combustion ash (1 and 3) so as to adjust the moisture content of the ash to 10-90wt.%. The mixture becoming a pasty state is taken out on a belt conveyor 7 from a take-out port 5. The belt conveyor 7 passes through an irradiation chamber 8 at constant speed and the mixture receives the irradiation treatment with electron beam of 10-2000KGV by an electron beam generator 9 and dioxin is decomposed to be converted to a harmless substance while the treated mixture is carried out to the outside by the belt conveyor 7 and taken out of a take-out port 12 to be disposed. The temp. of the combustion ash before the irradiation with radiation is set in a range from room temp. to about 80°C. COPYRIGHT: (C)1991,JPO&Japio
9 Verfahren zur Entsorgung von organischen Verbindungen EP96890031.6 1996-03-01 EP0730885B1 2000-01-05 Buzetzki, Eduard
10 Method for removal of dioxin generated in waste combustion EP90117443.3 1990-09-11 EP0417714B1 1995-02-01 Machi, Sueo c/o Takasaki Lab.of Japan Atomic; Sato, Shoichi c/o Takasaki Lab. of Japan Atomic; Tokunaga, Okihiro c/o Takasaki Lab.of Japan Atomic; Aoki, Yasushi c/o Takasaki Lab.of Japan Atomic; Suda, Shouichi; Miyachi, Tsuneharu; Shibamura, Yokichi; Agarida, Toru; Suzuki, Ryoji; Kawamura, Keita
11 Treatment of organic compound and apparatus therefor JP5208896 1996-03-08 JPH0975709A 1997-03-25 EEDOARUTO BUZETSUKII
PROBLEM TO BE SOLVED: To make it possible to neutralize dangerous compds. by subjecting the compds. to be treated to ionization, dividing the resulted product ionized by electrodialysis and subjecting the final resulted ionic products and residual org. materials to known use or filling up of land or to a treatment by incineration. SOLUTION: A raw material mixture in an equipment section I is supplied from a tank 20 to an ionization section II via a line 21 having a pump and valve. The materials to be treated by the influence of an ionization device 22 in this ionization section II are divided and separated in a dialysis device 23. The org. materials which are rare materials in the dialysis section II are discharged form the dialysis device 23 by a line 24. On the other hand, the inorg. reaction product/condensate and a caustic or salt soln. are supplied via lines 29, 30 to circulation paths 25, 26 and are discharged from discharge lines 27, 28. The discharged materials are used for filling up of land or are treated by incineration. As a result, the dangerous compds. as harmful biotic pesticides, e.g. insecticides and herbicides, are neutralized and treated.
12 A method for removing the dioxins that occurs due to the dust combustion JP23616590 1990-09-06 JP2549755B2 1996-10-30 MACHI SUEO; SATO SHOICHI; TOKUNAGA OKIKIMI; AOKI YASUSHI; SUDA SHOICHI; MYAJI TSUNEHARU; SHIBAMURA YOKICHI; KAMISATOTA TOORU; KAWAMURA KEITA; SUZUKI RYOJI
13 Processing method of the flame treatment activated carbon due to ionizing radiation JP21195791 1991-08-23 JP2554802B2 1996-11-20 HOSONO MASAKAZU; ARAI HIDEHIKO; MYATA SADAJIRO
14 Treatment of hardly treatable activated carbon by irradiation with ionizing radiation JP21195791 1991-08-23 JPH0549927A 1993-03-02 HOSONO MASAKAZU; ARAI HIDEHIKO; MIYATA SADAJIRO
PURPOSE:To safely and efficiently decompose activated carbon which has been used in the adsorbing treatment of an organochlorine compound such as PCB or trichloroethylene(TCE) which is difficult to treat heretofore. CONSTITUTION:In the treatment of hardly treatable activated carbon, water is added to activated carbon having an organochlorine compound adsorbed thereon and the resulting mixture is irradiated with ionizing radiation to decompose the organochlorine compound adsorbed on activated carbon. By this method, hardly treatable activated carbon which has been accumulated up to now without being treated can be treated in low cost.
15 Verfahren zur Entsorgung von organischen Verbindungen EP96890031.6 1996-03-01 EP0730885A1 1996-09-11 Buzetzki, Eduard

Zur Entsorgung gefährlicher und toxischer organischer Verbindungen, die zusätzlich zu den Elementen Kohlenstoff, Was-serstoff und Sauerstoff noch Halogen, Phosphor, Schwefel und/oder Metallelemente in atomarer Bindung enthalten, wird vorgeschlagen, dieselben einer Ionisation und sofort anschließenden Elektrodialyse zu unterwerfen. Die ionischen Endprodukte der Reaktion sind leicht handhabbar und können problemlos einer weiteren Verwendung zugeführt oder zur Deponierung oder Verbrennung abgeführt werden.

Die Ionisation erfolgt durch Einwirkung von ionisierender Strahlung.

Besonders geeignet ist das erfindungsgemäße Verfahren für die Entsorgung halogenhaltiger aromatischer Verbindungen, wie diverser Schädlingsbekämpfungsmittel.

16 Method for removal of dioxin generated in waste combustion EP90117443.3 1990-09-11 EP0417714A3 1991-08-21 Machi, Sueo c/o Takasaki Lab.of Japan Atomic; Sato, Shoichi c/o Takasaki Lab. of Japan Atomic; Tokunaga, Okihiro c/o Takasaki Lab.of Japan Atomic; Aoki, Yasushi c/o Takasaki Lab.of Japan Atomic; Suda, Shouichi; Miyachi, Tsuneharu; Shibamura, Yokichi; Agarida, Toru; Suzuki, Ryoji; Kawamura, Keita

Dioxin generated during the combustion of waste material can be satisfactorily removed efficiently and economically by irradiating waste incineration ash contain­ing ca. 10 - 90% by weight of water in a temperature range from ambient temperature to ca. 80°C with ionizing radiation for a total dose of ca. 10 - 2,000 kGy. The ash or sludge after the irradiation treatment can be very conveniently disposed of by burial, etc.

17 Method for removal of dioxin generated in waste combustion EP90117443.3 1990-09-11 EP0417714A2 1991-03-20 Machi, Sueo c/o Takasaki Lab.of Japan Atomic; Sato, Shoichi c/o Takasaki Lab. of Japan Atomic; Tokunaga, Okihiro c/o Takasaki Lab.of Japan Atomic; Aoki, Yasushi c/o Takasaki Lab.of Japan Atomic; Suda, Shouichi; Miyachi, Tsuneharu; Shibamura, Yokichi; Agarida, Toru; Suzuki, Ryoji; Kawamura, Keita

Dioxin generated during the combustion of waste material can be satisfactorily removed efficiently and economically by irradiating waste incineration ash contain­ing ca. 10 - 90% by weight of water in a temperature range from ambient temperature to ca. 80°C with ionizing radiation for a total dose of ca. 10 - 2,000 kGy. The ash or sludge after the irradiation treatment can be very conveniently disposed of by burial, etc.

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