子分类:
序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 Preparation of polychloroprene for use in adhesives US31010572 1972-11-28 US3872043A 1975-03-18 BRANLARD PAUL; MODIANO JACQUES
Polychloroprene for use in adhesive compositions and having the advantage of remaining in a single phase is prepared by effecting polychloroprene polymerization in the presence of a binary emulsifying system of 1.8 to 3% of resinic derivative and 0.1 to 1% of a fatty acid or salt thereof. Alternatively, a ternary emulsifying system may be used comprising 1 to 3% of the resinic derivative, 0.1 to 1.5% of the fatty acid or salt therof and 0.1 to 2.5% of a sticking agent of a colophony derivative or a polydiene resin.
142 Polychloroprene for non-phasing solvent cements US6912470 1970-09-02 US3824203A 1974-07-16 TABIBIAN R
CHLOROPRENE POLYMERS, USEFUL IN NON-PHASING SOLVENT CEMENTS HAVING GOOD TACK, ARE PRODUCED BY POLYMERIZING CHLOROPRENE, OPTIONALLY WITH ANOTHER COPOLYMERIZABLE MONOMER, IN AN AQUEOUS ALKALINE EMULSION IN THE PRESENCE OF WATEER-SOLUBLE SALTS OF: (A) ABOUT 0.5 TO 1.5 PERCENT OF A ROSIN ACID (B) ABOUT 1 TO 2 PERCENT OF A C12 TO C20 UNSATURATED FATTY ACID AND (C) ABOUT 0.5 TO 1.5 PERCENT OF A CONDENSATION PRODUCT OF FORMALDEHYDE WITH A NAPHTHALENE SULFONIC ACID, ALL PERCENTAGES BEING BY WEIGHT BASED ON THE WEIGHT OF CHLOROPRENE AND ANY OTHER COPOLYMERIZABLE MONOMER PRESENT, THE PERCENTAGE OF (A) AND (B) BEING BASED ON THE FREE ACID AND OF (C) BEING BASED ON THE SALT; THE TOTAL PERCENTAGE OF (A) AND (B) BEING AT LEAST 2, AND THE CONVERSION OF MONOMER TO POLYMER BEING AT LEAST ABOUT 85 PERCENT; AND OPTIONALLY HAVING PRESENT DURING POLYMERIZATION FROM 1 TO 4 PERCENT BY WEIGHT OF A METHYL ESTER OF A NATURALLY OCCURING ROSIN ACID BASED ON THE WEIGHT OF CHLOROPRENE.
143 Adhesive composition for wood and metal US3502605D 1967-11-13 US3502605A 1970-03-24 CLARK TREVOR P; TRUSSELL PAUL C
144 Neoprene cements with extended open time US3488315D 1967-08-09 US3488315A 1970-01-06 STUCKER NOVA E; BEREJKA ANTHONY J
145 Pressure-sensitive chloroprene polymer adhesives US3479311D 1968-01-03 US3479311A 1969-11-18 GORMAN JOHN JOSEPH
146 Rubber adhesives US3475362D 1968-05-07 US3475362A 1969-10-28 ROMANICK JOHN F; PRUIKSMA ARTHUR B
1,137,046. Adhesives based on carboxylated rubber. PITTSBURGH PLATE GLASS CO. 12 Sept., 1967 [13 Sept., 1966 (3)], No. 41585/67. Heading C3P. An adhesive composition comprises:- (1) 100 parts by weight of one or more rubbery diene addition polymers having an average molecular weight of at least 30,000 and containing a total of 0À00025-0À12 carboxyl equivalents/100 grams; (2) From 0À1-80 parts by weight of a metal of Group IA, IIA, IIB or IVA of the Periodic Table in the form of an organic solvent-soluble metalorganic resin; and (3) 50-450 parts by weight of an organic solvent-soluble resin compatible with (1). Ingredient (1) is preferably a carboxylated polybutadiene or butadiene-styrene copolymer. The rubber may also be a mixture of carboxylated and non-carboxylated polymers. The resin (2) may be an oil-soluble heat-hardenable phenol-formaldehyde resin or a rosin acid and the metal may be lithium, sodium, magnesium, calcium, barium, zinc or lead. Resin (3) is suitably a poly-#-pinene or an ethylene glycol ester of polymerized rosin. The compositions may contain filler and a small amount of solvent for use as mastics or dissolved in solvents for brushing and spraying. Ingredients (1) and (2) may be reacted together by masticating at high temperatures. Additionally part or all of resin (3) can be constituted by " excess " resin (2)
147 Compositions for polychloroprene adhesives US3446872D 1965-05-14 US3446872A 1969-05-27 TANNO TAKESHI; SHIBUYA IKUTOSHI; ABO MASAHIRO
148 Multilayer semiconductor heteroepitaxial structure US3433684D 1966-09-29 US3433684A 1969-03-18 ZANOWICK RICHARD L; COKER JESSE E; MORRITZ FRED L
1,137,046. Adhesives based on carboxylated rubber. PITTSBURGH PLATE GLASS CO. 12 Sept., 1967 [13 Sept., 1966 (3)], No. 41585/67. Heading C3P. An adhesive composition comprises:- (1) 100 parts by weight of one or more rubbery diene addition polymers having an average molecular weight of at least 30,000 and containing a total of 0À00025-0À12 carboxyl equivalents/100 grams; (2) From 0À1-80 parts by weight of a metal of Group IA, IIA, IIB or IVA of the Periodic Table in the form of an organic solvent-soluble metalorganic resin; and (3) 50-450 parts by weight of an organic solvent-soluble resin compatible with (1). Ingredient (1) is preferably a carboxylated polybutadiene or butadiene-styrene copolymer. The rubber may also be a mixture of carboxylated and non-carboxylated polymers. The resin (2) may be an oil-soluble heat-hardenable phenol-formaldehyde resin or a rosin acid and the metal may be lithium, sodium, magnesium, calcium, barium, zinc or lead. Resin (3) is suitably a poly-#-pinene or an ethylene glycol ester of polymerized rosin. The compositions may contain filler and a small amount of solvent for use as mastics or dissolved in solvents for brushing and spraying. Ingredients (1) and (2) may be reacted together by masticating at high temperatures. Additionally part or all of resin (3) can be constituted by " excess " resin (2)
149 Water containing organic solvent solutions of chloroprene-methacrylic acid copolymers US47703765 1965-08-03 US3361693A 1968-01-02 HARTMAN GESCHWIND DAVID
150 Adhesive composed of polyepoxide and a chloroprene copolymer with 5 to 25% acrylonitrile US30865263 1963-09-13 US3310603A 1967-03-21 JEROME KELLY DOUGLAS
151 Heat resistant chloroprene based adhesives US19540962 1962-05-17 US3242113A 1966-03-22 KELL ROBERT M
152 Bonding and sealing agents US15981061 1961-11-06 US3153637A 1964-10-20 JOACHIM SCHMIDT; HEINZ STOCK; BERNHARD ZDRALEK
153 Adhesives, cements and the like US56678156 1956-02-21 US2981650A 1961-04-25 ERICH BADER; OTTO SCHWEITZER
154 High strength heat-resistant neoprenephenolic adhesive cement US84653359 1959-10-27 US2918442A 1959-12-22 GERRARD JACK A; MATTSON RAYMOND C
155 Chloroprene cement having improved adhesive properties US54185355 1955-10-20 US2838463A 1958-06-10 FREEMAN STEPHEN E
156 Blend of isoolefin-diolefin and polychloroprene synthetic rubbers for adhering isoolefin-diolefin rubber to other materials US6882449 1949-01-03 US2541550A 1951-02-13 SARBACH DONALD V; LOOMIS GEORGE P
157 Polymerized chloroprene compositions US38726641 1941-04-07 US2386403A 1945-10-09 MACDONALD ALEXANDER D; RISHTON JAMES H
158 Adhesive composition and method of making the same US34036740 1940-06-13 US2313039A 1943-03-09 EARLE ROLAND D
159 Polymerized chloroprene adhesive US32217140 1940-03-04 US2286505A 1942-06-16 PERKINS JOHN L
160 Improving the sprayability of polychloroprene contact by shearing in microfluidizer US664725 1996-06-17 US5733961A 1998-03-31 Daniel C. Purvis II; John J. Ach; John P. Jones
Polychloroprene contact adhesive is made by mixing polychloroprene, tackifier, metallic oxide, antioxidants and organic solvent. The contact adhesive is sheared for reducing its ASTM D 1084 Saybolt viscosity by 10 percent or more. Shearing improves the sprayability of the polychloroprene contact adhesive. It makes it more uniform and reduces its viscosity.
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