141 |
Aliphatic .beta.-keto esters |
US557268 |
1975-03-11 |
US4031130A |
1977-06-21 |
Gunter Renner; Immo Boie; Quirin Scheben |
A process for the production of aliphatic .beta.-keto esters by reacting a dialkyl ketone with a dialkylcarbonate in the presence of an at least equivalent quantity of a basic condensation agent based on the dialkyl ketone at a reaction temperature of 20.degree. to 80.degree. C and the reaction product is subsequently converted by acidification into the .beta.-keto ester. By carrying out the condensation reaction in the presence of hexamethylphosphoric acid triamide as solvent advantageously higher yields of 20 to 50 % can be obtained by the inventive process of compared to conventional processes. |
142 |
|
US31131772 |
1972-12-01 |
USB311317I5 |
1975-01-28 |
|
|
143 |
Beta-arylated naphthoxidines and a method of preparation |
US3539597D |
1967-05-08 |
US3539597A |
1970-11-10 |
BOSSHARD HANS; BOSSARD WERNER |
|
144 |
beta-arylated naphthoxidine containing mono azo dyestuffs |
US50966365 |
1965-10-05 |
US3320234A |
1967-05-16 |
WERNER BOSSARD; HANS BOSSHARD |
|
145 |
THERMAL TRANSFER RECORDING SHEET |
US15844267 |
2017-12-15 |
US20180170085A1 |
2018-06-21 |
Taichi Shintou; Masahiro Suenaga; Koromo Shirota; Yuko Katsumoto; Tsuyoshi Santo; Hajime Muta; Tomoyuki Noda |
In a thermal transfer recording sheet including a base material and a colorant layer, the colorant layer includes a yellow dye layer containing a yellow dye, a magenta dye layer containing a magenta dye, and a cyan dye layer containing a cyan dye, and the cyan dye includes a compound represented by Formula (Ia) or Formula (Ib): where R1 to R7 are substituents, X− is an anion, and the compound of Formula (Ib) has at least one anionic substituent. |
146 |
Compositions for dyeing keratinous fiber |
US10148621 |
2000-12-01 |
US06958080B2 |
2005-10-25 |
Joji Mitamura; Mutsumi Noguchi; Takeshi Onuki |
A composition for dyeing keratinous fiber which includes incorporated therein an oxidative color-developing substance, an enzyme which reacts with oxygen as a substrate but does not evolve hydrogen peroxide, and a weak reducing agent. |
147 |
Stabilizing IR dyes for laser imaging |
US745352 |
1996-11-08 |
US5989772A |
1999-11-23 |
Lee W. Tutt; Mitchell S. Burberry; Gary M. Underwood |
A laser-exposed thermal recording element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye comprising a laser light-absorbing dye absorbing at the wavelength of a laser used to expose the element, wherein the dye layer also contains a stabilizing IR-absorbing dye with an absorption wavelength maximum approximately equal to or longer than that of the laser light-absorbing dye. |
148 |
Preparation of a dye for coloring protein-based fibers and
cellulose-based materials from the oxidation products of the
manufacture of a triphenylmethane dye |
US941406 |
1997-09-30 |
US5922085A |
1999-07-13 |
Gray D. Ellis; Belinda J. DiMarcello; Debra J. Bradshaw |
A process of preparing a dye composition and a resultant dye composition. The process includes preparing a mixture comprising a triphenylmethane dye and oxidation products by reacting methylenedianiline, aniline, an oxidation catalyst, and an oxidant; separating the oxidation products from the triphenylmethane dye to produce an aqueous solution of oxidation products; treating the solution of oxidation products with a basic compound; separating unreacted aniline from the solution of oxidation products and forming a mixture of oxidation products; and sulfonating the mixture of oxidation products to form a dye composition. |
149 |
Dye diffusion thermal transfer printing |
US682510 |
1996-07-11 |
US5783518A |
1998-07-21 |
Roy Bradbury; Clive Moscrop |
A thermal transfer sheet comprising a substrate having a coating comprising a dye which carries an ##STR1## wherein R.sup.1 is an optionally substituted branched chain alkyl group; and R.sup.2 is an optionally substituted alkyl group or an optionally substituted aryl group provided that the dye is not a monoazo dye or that the dye is not 3-(2,3-dihydroindol-1-yl)-2-�4-(isopropylpropylamino)-2-methylphenylimino!-3-oxo-N-(2,4,5-trichlorophenyl)propionamide. |
150 |
One equivalent couplers and low PKA release dyes |
US449891 |
1995-05-23 |
US5612173A |
1997-03-18 |
Gary S. Proehl; Stephen P. Singer; J. Michael Buchanan |
A photographic element containing a dye which when released from a coupler has a sufficiently low pKa, generally less than about 5, such that the dye remains substantially or fully ionized during coating of the film and in the produced film, results in an element containing a dye which has the desired hue without the use of additional additives, such as mordants, to keep the dye ionized. The dye is also useful in photographic elements without release from a coupler, for example, as a filter dye. |
151 |
Cure-indicating molding and coating composition |
US496499 |
1995-06-29 |
US5583178A |
1996-12-10 |
Joel D. Oxman; Mark S. Konings; George V. D. Tiers; Kim M. Vogel; Dennis E. Vogel |
The present invention provides novel hydrosilation-curable compositions, the cure of which can be monitored visually, comprising: (1) an ethylenic compound; (2) a compound containing silicon-bonded-hydrogen groups; (3) a hydrosilation catalyst; and (4) one or more cure-indicating dyes with light absorption in the visible spectrum that exhibit a color change in the presence of a silicon-bonded-hydrogen compound and a precious metal hydrosilation catalyst. The cure-indicating dye provides the composition with an initial pre-cure color and a different post-cure color. As a result of this change in color, the state of cure of the composition can be visually monitored. |
152 |
Composition for the oxidation dyeing of keratinous fibres comprising a
para-aminophenol, a meta-aminophenol and an ortho-aminophenol, and
dyeing process using such a composition |
US379524 |
1995-04-06 |
US5580357A |
1996-12-03 |
Jean Cotteret; Marie P. Audousset; Alain Lagrange; Jean J. Vandenbosche |
A dyeing composition for keratinous fibers and in particular for human keratinous fibers such as hair, comprising, in a suitable dyeing medium, at least one oxidation dye precursor chosen from 3-methyl-para-aminophenol, 2-methyl-para-aminophenol and 2-hydroxymethyl-para-aminophenol and their addition salts with an acid; at least one coupling agent chosen from the 2-methyl-5-aminophenols of formula (I): ##STR1## where R denotes hydrogen, methyl, ethyl, .beta.-hydroxyethyl or .gamma.-hydroxypropyl, and their addition salts with an acid; and at least one ortho-aminophenol chosen from ortho-aminophenol and 3-acetylamino-6-aminophenol or one of their addition salts with an acid. A dyeing process incorporates development by an oxidizing agent. |
153 |
Hydroxyethylated 2-nitro-p-phenylenediamines and use thereof for dyeing
keratin fibers |
US351242 |
1994-12-07 |
US5516942A |
1996-05-14 |
Alain Lagrange; Alex Junino; Alain Genet; Jean Cotteret |
A N1,N4-dihydroxyethylated 2-nitro-p-phenylenediamine of formula (I), wherein R is C3-4 aklyl, and cosmetically acceptable salts thereof, for use in direct dyeing to give blue through purple shades which are wash-fast, light-fast, weatherproof and sweat resistant, and optionally combined with yellow and optionally read or orange-coloured dyes to give natural hues. |
154 |
Thermal imaging dye precursors |
US729426 |
1991-07-12 |
US5424475A |
1995-06-13 |
Roger A. Boggs; Alan L. Borror; Patrick R. Conlon; Richard L. Cournoyer; Ernest W. Ellis; David P. Waller |
Colorless precursors of preformed image dyes are provided which are useful as the color image-forming materials in thermal imaging systems. These colorless precursors possess at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye. |
155 |
Triazine including substituted color-providing moiety |
US201456 |
1994-02-24 |
US5424427A |
1995-06-13 |
Michael J. Arnost |
There are disclosed compounds comprising at least one cyclic 1,3-sulfur-nitrogen substituted color-providing material and at least one ballast group which are linked to each other through a triazine group. The compounds are capable of releasing the color-providing material upon cleavage in the presence of silver ions or a soluble silver complex. The color-providing compounds are useful as image-forming materials in color thermographic, photothermographic and other photographic processes. |
156 |
Azo dyes for thermotransfer printing |
US166103 |
1993-12-14 |
USRE34877E |
1995-03-14 |
Volker Bach; Karl-Heinz Etzbach; Sabine Gruettner; Gunther Lamm; Helmut Reichelt; Ruediger Sens |
Azo dyes useful for thermotransfer printing have the formula ##STR1## |
157 |
2-alkoxy-3,5-diaminopyridine derivatives and their salts, and dye
compositions for keratinous fibers containing the derivatives or salts |
US26284 |
1993-03-04 |
US5378244A |
1995-01-03 |
Tadashi Tamura; Akira Kiyomine; Osamu Morita; Michio Tanaka; Masahiko Ogawa; Hidetoshi Tagami; Toru Yoshihara |
A dye composition for keratinous fibers which contains a coupler and a developer are disclosed. The present coupler component is a novel 2-alkoxy-3,5-diaminopyridine derivatives of the formula (1): ##STR1## wherein R1 and R2 are the same or different from each other and independently represent a hydrogen atom, a lower alkanoyl group or a lower alkyl group which may be substituted by at least one hydroxyl group, and R3 is a lower alkyl group which may be substituted by at least one hydroxyl group, or a salt thereof; provided that R1 and R2 are not both a hydrogen atom or an acetyl group at the same time. The present 2-alkoxy-3,5-diaminopyridine derivatives are useful as couplers in dye compositions, and are capable of dyeing keratinous fibers such as hair in a bright blue color with excellent dyeability. Dye compositions containing the present compounds as a coupler show excellent resistance to discoloration, excellent resistance to shampooing and excellent resistance to friction. |
158 |
Use of pyridine dyes in the textile sector, dye mixtures with pyridine
dyes, and triazolopyridine dyes having a thienyl radical |
US116958 |
1993-09-07 |
US5376150A |
1994-12-27 |
Arno Lange; Volker Bach; Ruediger Sens; Karl-Heinz Etzbach; Helmut Reichelt; Sabine Gruettner-Merten |
There are described the use of pyridine dyes of the formula ##STR1## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a carbocyclic or heterocyclic radical,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxy carbonyl,R.sup.4 is oxygen or the radical of an acidic CH compound,R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.6 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl, hydroxyl or substituted or unsubstituted amino, andX is nitrogen or optionally CH,for dyeing or printing synthetic fibers, cellulose esters or blends thereof, dye mixtures comprising pyridine dyes of the above formulae and blue disperse dyes, the use thereof for dyeing and printing synthetic fibers, cellulose esters or blends thereof, and triazolopyridine dyes having a thienyl radical. |
159 |
Mixture of indoaniline dyes in dye-donor element for thermal dye transfer |
US169831 |
1993-12-16 |
US5340790A |
1994-08-23 |
Raymond P. Scaringe; Steven Evans; William H. Simpson; Richard C. Vanhanehem |
A cyan dye-donor element for thermal dye transfer imaging comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, wherein the dye comprises a mixture of at least two different 2-carbamoyl-4-[N-(p-aminoaryl)-imino]-1,4-naphthoquinone dyes, each of the dyes having the formula: ##STR1## with the proviso that at least 50% of the dye mixture is a dye having the formula: ##STR2## and with the further proviso that at least one of the other dyes in the mixture has the formula: ##STR3## |
160 |
Indonaphthol dyes and thermal transfer thereof |
US677291 |
1991-03-29 |
US5312926A |
1994-05-17 |
Volker Bach; Karl-Heinz Etzbach; Ruediger Sens |
Indonaphthol thermal transfer dyes have the formula ##STR1## where X is nitrogen or the radical CH,R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.6 -alkyl, which may be substituted, C.sub.1 -C.sub.6 -monooxaalkyl or -dioxaalkyl or allyl,R.sup.3 and R.sup.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino, andR.sup.5 is five-membered hetaryl which is not benzofused and has two or more hetero atoms,with the proviso that R.sup.1 and R.sup.2 are not both unsubstituted C.sub.1 -C.sub.6 -alkyl at one and the same time. |