序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 Aliphatic .beta.-keto esters US557268 1975-03-11 US4031130A 1977-06-21 Gunter Renner; Immo Boie; Quirin Scheben
A process for the production of aliphatic .beta.-keto esters by reacting a dialkyl ketone with a dialkylcarbonate in the presence of an at least equivalent quantity of a basic condensation agent based on the dialkyl ketone at a reaction temperature of 20.degree. to 80.degree. C and the reaction product is subsequently converted by acidification into the .beta.-keto ester. By carrying out the condensation reaction in the presence of hexamethylphosphoric acid triamide as solvent advantageously higher yields of 20 to 50 % can be obtained by the inventive process of compared to conventional processes.
142 US31131772 1972-12-01 USB311317I5 1975-01-28
143 Beta-arylated naphthoxidines and a method of preparation US3539597D 1967-05-08 US3539597A 1970-11-10 BOSSHARD HANS; BOSSARD WERNER
144 beta-arylated naphthoxidine containing mono azo dyestuffs US50966365 1965-10-05 US3320234A 1967-05-16 WERNER BOSSARD; HANS BOSSHARD
145 THERMAL TRANSFER RECORDING SHEET US15844267 2017-12-15 US20180170085A1 2018-06-21 Taichi Shintou; Masahiro Suenaga; Koromo Shirota; Yuko Katsumoto; Tsuyoshi Santo; Hajime Muta; Tomoyuki Noda
In a thermal transfer recording sheet including a base material and a colorant layer, the colorant layer includes a yellow dye layer containing a yellow dye, a magenta dye layer containing a magenta dye, and a cyan dye layer containing a cyan dye, and the cyan dye includes a compound represented by Formula (Ia) or Formula (Ib): where R1 to R7 are substituents, X− is an anion, and the compound of Formula (Ib) has at least one anionic substituent.
146 Compositions for dyeing keratinous fiber US10148621 2000-12-01 US06958080B2 2005-10-25 Joji Mitamura; Mutsumi Noguchi; Takeshi Onuki
A composition for dyeing keratinous fiber which includes incorporated therein an oxidative color-developing substance, an enzyme which reacts with oxygen as a substrate but does not evolve hydrogen peroxide, and a weak reducing agent.
147 Stabilizing IR dyes for laser imaging US745352 1996-11-08 US5989772A 1999-11-23 Lee W. Tutt; Mitchell S. Burberry; Gary M. Underwood
A laser-exposed thermal recording element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye comprising a laser light-absorbing dye absorbing at the wavelength of a laser used to expose the element, wherein the dye layer also contains a stabilizing IR-absorbing dye with an absorption wavelength maximum approximately equal to or longer than that of the laser light-absorbing dye.
148 Preparation of a dye for coloring protein-based fibers and cellulose-based materials from the oxidation products of the manufacture of a triphenylmethane dye US941406 1997-09-30 US5922085A 1999-07-13 Gray D. Ellis; Belinda J. DiMarcello; Debra J. Bradshaw
A process of preparing a dye composition and a resultant dye composition. The process includes preparing a mixture comprising a triphenylmethane dye and oxidation products by reacting methylenedianiline, aniline, an oxidation catalyst, and an oxidant; separating the oxidation products from the triphenylmethane dye to produce an aqueous solution of oxidation products; treating the solution of oxidation products with a basic compound; separating unreacted aniline from the solution of oxidation products and forming a mixture of oxidation products; and sulfonating the mixture of oxidation products to form a dye composition.
149 Dye diffusion thermal transfer printing US682510 1996-07-11 US5783518A 1998-07-21 Roy Bradbury; Clive Moscrop
A thermal transfer sheet comprising a substrate having a coating comprising a dye which carries an ##STR1## wherein R.sup.1 is an optionally substituted branched chain alkyl group; and R.sup.2 is an optionally substituted alkyl group or an optionally substituted aryl group provided that the dye is not a monoazo dye or that the dye is not 3-(2,3-dihydroindol-1-yl)-2-�4-(isopropylpropylamino)-2-methylphenylimino!-3-oxo-N-(2,4,5-trichlorophenyl)propionamide.
150 One equivalent couplers and low PKA release dyes US449891 1995-05-23 US5612173A 1997-03-18 Gary S. Proehl; Stephen P. Singer; J. Michael Buchanan
A photographic element containing a dye which when released from a coupler has a sufficiently low pKa, generally less than about 5, such that the dye remains substantially or fully ionized during coating of the film and in the produced film, results in an element containing a dye which has the desired hue without the use of additional additives, such as mordants, to keep the dye ionized. The dye is also useful in photographic elements without release from a coupler, for example, as a filter dye.
151 Cure-indicating molding and coating composition US496499 1995-06-29 US5583178A 1996-12-10 Joel D. Oxman; Mark S. Konings; George V. D. Tiers; Kim M. Vogel; Dennis E. Vogel
The present invention provides novel hydrosilation-curable compositions, the cure of which can be monitored visually, comprising: (1) an ethylenic compound; (2) a compound containing silicon-bonded-hydrogen groups; (3) a hydrosilation catalyst; and (4) one or more cure-indicating dyes with light absorption in the visible spectrum that exhibit a color change in the presence of a silicon-bonded-hydrogen compound and a precious metal hydrosilation catalyst. The cure-indicating dye provides the composition with an initial pre-cure color and a different post-cure color. As a result of this change in color, the state of cure of the composition can be visually monitored.
152 Composition for the oxidation dyeing of keratinous fibres comprising a para-aminophenol, a meta-aminophenol and an ortho-aminophenol, and dyeing process using such a composition US379524 1995-04-06 US5580357A 1996-12-03 Jean Cotteret; Marie P. Audousset; Alain Lagrange; Jean J. Vandenbosche
A dyeing composition for keratinous fibers and in particular for human keratinous fibers such as hair, comprising, in a suitable dyeing medium, at least one oxidation dye precursor chosen from 3-methyl-para-aminophenol, 2-methyl-para-aminophenol and 2-hydroxymethyl-para-aminophenol and their addition salts with an acid; at least one coupling agent chosen from the 2-methyl-5-aminophenols of formula (I): ##STR1## where R denotes hydrogen, methyl, ethyl, .beta.-hydroxyethyl or .gamma.-hydroxypropyl, and their addition salts with an acid; and at least one ortho-aminophenol chosen from ortho-aminophenol and 3-acetylamino-6-aminophenol or one of their addition salts with an acid. A dyeing process incorporates development by an oxidizing agent.
153 Hydroxyethylated 2-nitro-p-phenylenediamines and use thereof for dyeing keratin fibers US351242 1994-12-07 US5516942A 1996-05-14 Alain Lagrange; Alex Junino; Alain Genet; Jean Cotteret
A N1,N4-dihydroxyethylated 2-nitro-p-phenylenediamine of formula (I), wherein R is C3-4 aklyl, and cosmetically acceptable salts thereof, for use in direct dyeing to give blue through purple shades which are wash-fast, light-fast, weatherproof and sweat resistant, and optionally combined with yellow and optionally read or orange-coloured dyes to give natural hues.
154 Thermal imaging dye precursors US729426 1991-07-12 US5424475A 1995-06-13 Roger A. Boggs; Alan L. Borror; Patrick R. Conlon; Richard L. Cournoyer; Ernest W. Ellis; David P. Waller
Colorless precursors of preformed image dyes are provided which are useful as the color image-forming materials in thermal imaging systems. These colorless precursors possess at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye.
155 Triazine including substituted color-providing moiety US201456 1994-02-24 US5424427A 1995-06-13 Michael J. Arnost
There are disclosed compounds comprising at least one cyclic 1,3-sulfur-nitrogen substituted color-providing material and at least one ballast group which are linked to each other through a triazine group. The compounds are capable of releasing the color-providing material upon cleavage in the presence of silver ions or a soluble silver complex. The color-providing compounds are useful as image-forming materials in color thermographic, photothermographic and other photographic processes.
156 Azo dyes for thermotransfer printing US166103 1993-12-14 USRE34877E 1995-03-14 Volker Bach; Karl-Heinz Etzbach; Sabine Gruettner; Gunther Lamm; Helmut Reichelt; Ruediger Sens
Azo dyes useful for thermotransfer printing have the formula ##STR1##
157 2-alkoxy-3,5-diaminopyridine derivatives and their salts, and dye compositions for keratinous fibers containing the derivatives or salts US26284 1993-03-04 US5378244A 1995-01-03 Tadashi Tamura; Akira Kiyomine; Osamu Morita; Michio Tanaka; Masahiko Ogawa; Hidetoshi Tagami; Toru Yoshihara
A dye composition for keratinous fibers which contains a coupler and a developer are disclosed. The present coupler component is a novel 2-alkoxy-3,5-diaminopyridine derivatives of the formula (1): ##STR1## wherein R1 and R2 are the same or different from each other and independently represent a hydrogen atom, a lower alkanoyl group or a lower alkyl group which may be substituted by at least one hydroxyl group, and R3 is a lower alkyl group which may be substituted by at least one hydroxyl group, or a salt thereof; provided that R1 and R2 are not both a hydrogen atom or an acetyl group at the same time. The present 2-alkoxy-3,5-diaminopyridine derivatives are useful as couplers in dye compositions, and are capable of dyeing keratinous fibers such as hair in a bright blue color with excellent dyeability. Dye compositions containing the present compounds as a coupler show excellent resistance to discoloration, excellent resistance to shampooing and excellent resistance to friction.
158 Use of pyridine dyes in the textile sector, dye mixtures with pyridine dyes, and triazolopyridine dyes having a thienyl radical US116958 1993-09-07 US5376150A 1994-12-27 Arno Lange; Volker Bach; Ruediger Sens; Karl-Heinz Etzbach; Helmut Reichelt; Sabine Gruettner-Merten
There are described the use of pyridine dyes of the formula ##STR1## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a carbocyclic or heterocyclic radical,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxy carbonyl,R.sup.4 is oxygen or the radical of an acidic CH compound,R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.6 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl, hydroxyl or substituted or unsubstituted amino, andX is nitrogen or optionally CH,for dyeing or printing synthetic fibers, cellulose esters or blends thereof, dye mixtures comprising pyridine dyes of the above formulae and blue disperse dyes, the use thereof for dyeing and printing synthetic fibers, cellulose esters or blends thereof, and triazolopyridine dyes having a thienyl radical.
159 Mixture of indoaniline dyes in dye-donor element for thermal dye transfer US169831 1993-12-16 US5340790A 1994-08-23 Raymond P. Scaringe; Steven Evans; William H. Simpson; Richard C. Vanhanehem
A cyan dye-donor element for thermal dye transfer imaging comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, wherein the dye comprises a mixture of at least two different 2-carbamoyl-4-[N-(p-aminoaryl)-imino]-1,4-naphthoquinone dyes, each of the dyes having the formula: ##STR1## with the proviso that at least 50% of the dye mixture is a dye having the formula: ##STR2## and with the further proviso that at least one of the other dyes in the mixture has the formula: ##STR3##
160 Indonaphthol dyes and thermal transfer thereof US677291 1991-03-29 US5312926A 1994-05-17 Volker Bach; Karl-Heinz Etzbach; Ruediger Sens
Indonaphthol thermal transfer dyes have the formula ##STR1## where X is nitrogen or the radical CH,R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.6 -alkyl, which may be substituted, C.sub.1 -C.sub.6 -monooxaalkyl or -dioxaalkyl or allyl,R.sup.3 and R.sup.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino, andR.sup.5 is five-membered hetaryl which is not benzofused and has two or more hetero atoms,with the proviso that R.sup.1 and R.sup.2 are not both unsubstituted C.sub.1 -C.sub.6 -alkyl at one and the same time.
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