Unsaturated acrylic rubber and vinyl monomer paint
阅读：358发布：2023-04-14
专利汇可以提供Unsaturated acrylic rubber and vinyl monomer paint专利检索，专利查询，专利分析的服务。并且A radiation-curable paint which on a pigment and particulate filler-free basis consists essentially of vinyl monomers and an alpha-beta olefinically unsaturated, elastomeric particle of crosslinked acrylic polymer. The coating is applied as a filmforming dispersion to the surface of a substrate and cured thereon by ionizing radiation, e.g., an electron beam. This application is further directed to articles of manufacture coated with this paint using this process of curing.，下面是Unsaturated acrylic rubber and vinyl monomer paint专利的具体信息内容。
2. about 2 to about 20 mole percent of divinyl benzene, a diester of acrylic or methacrylic acid and a C2-C6 dihydric alcohol or a triester of acrylic acid or methacrylic acid and a C2-C6 trihydric alcohol, and being provided with alpha-beta olefinic unsaturation by reacting at least a major portion of the resultant epoxy groups with an alpha-beta olefinically unsaturated monocarboxylic acid.
2. An article of manufacture in accordance with claim 1 wherein said epoxy acrylate is glycidyl acrylate.
2. about 2 to about 20 mole percent of divinyl benzene, a diester of acrylic or methacrylic acid and a C2 -C6 dihydric alcohol or a triester of acrylic acid or methacrylic acid and a C2-C6 trihydric alcohol, and being provided with alpha-beta olefinic unsaturation by reacting at least a major portion of the resultant epoxy groups with an alpha-beta olefinically unsaturated monocarboxylic acid.
2. about 2 to about 20 mole percent of divinyl benzene, a diester of acrylic or methacrylic acid and a C2-C6 dihydric alcohol or a triester of acrylic acid or methacrylic acid and a C2-C6 trihydric alcohol, and being provided with alpha-beta olefinic unsaturation by reacting at least a major portion of the resultant epoxy groups with an alpha-beta olefinically unsaturated monocarboxylic acid.
3. An article of manufacture in accordance with claim 1 wherein said epoxy acrylate is glycidyl methacrylate.
4. An article of manufacture in accordance with claim 1 wherein said alpha-beta olefinically unsaturated monocarboxylic acid is selected from acrylic acid and methacrylic acid.
5. A radiation-curable paint which on a pigment and particulate filler-free basis comprises a film-forming dispersion of about 30 to about 90 weight percent vinyl monomers at least a major proportion of which are selected from esters of acrylic or methacrylic acid and a C1 -C8 monohydric alcohol and C8-C9 monovinyl hydrocarbons, and about 10 to about 70 weight percent of alpha-beta olefinically unsaturated, elastomeric particles of crosslinked acrylic polymer, said particles of crosslinked acrylic polymer consisting essentially of
6. A radiation-curable paint in accordance with claim 5 wherein said epoxy acrylate is glycidyl acrylate.
7. A radiation-curable paint in accordance with claim 5 wherein said epoxy acrylate is glycidyl methacrylate.
8. A radiation-curable paint in accordance with claim 5 wherein said alpha-beta olefinically unsaturated monocarboxylic acid is selected from acrylic acid and methacrylic acid.
9. In a method for painting a substrate wherein a film-forming solution is applied as a paint film to a surface of said substrate and crosslinked thereon by exposing the coated surface to ionizing radiation, the improvement wherein said film-forming solution, exclusive of nonpolymerizable solvents, pigments and particulate filler, consists essentially of about 30 to about 90 weight percent vinyl monomers at least a major proportion of which are selected from esters of acrylic or mEthacrylic acid and a C1-C8 monohydric alcohol and C8-C9 monovinyl hydrocarbons, and about 10 to about 70 weight percent of alpha-beta olefinically unsaturated, elastomeric particles of crosslinked acrylic polymer, said particles of crosslinked acrylic polymer consisting essentially of
10. A method in accordance with claim 9 wherein said epoxy acrylate is glycidyl acrylate.
11. A method in accordance with claim 9 wherein said epoxy acrylate is glycidyl methacrylate.
12. A method in accordance with claim 9 wherein said alpha-beta olefinically unsaturated monocarboxylic acid is selected from acrylic acid and methacrylic acid.
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