POLY(VINYL ESTER) BLOCK COPOLYMERS

申请号 PCT/US2011028066 申请日 2011-03-11 公开(公告)号 WO2011112911A3 公开(公告)日 2012-04-19
申请人 WISCONSIN ALUMNI RES FOUND; MAHANTHAPPA MAHESH KALYANA; LIPSCOMB CORINNE ELIZABETH; 发明人 MAHANTHAPPA MAHESH KALYANA; LIPSCOMB CORINNE ELIZABETH;
摘要 Polyvinyl ester) block copolymers comprising blocks of two or more different vinyl ester repeating units. The vinyl ester repeating units may be wherein R is H, C1-C22 straight or branched alkyl or alkylhalide, or phenyl or substituted phenyl, and n is 10 to 12,000. Methods of making polyvinyl ester) block copolymers, including reversible-addition fragmentation chain transfer, organobismuthine-mediated living radical polymerization, and cobalt mediated radical polymerization. Chemically-degradeable and biodegradable polymers comprising polyvinyl ester) block copolymers.
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