Surface treatments

申请号 US41787173 申请日 1973-11-21 公开(公告)号 US3890664A 公开(公告)日 1975-06-24
申请人 USM CORP; 发明人 HANSON RAYMOND;
摘要 Method and apparatus for treating the surface of a synthetic elastomer workpiece to improve its ability to be coated or bonded in which the surface of the workpiece is exposed to and reacted with products generated by electrolysis at an anode in a body of aqueous electrolyte to form a surface of reacted elastomer integral with the elastomer of the workpiece. The apparatus includes an anode and a cathode mounted for immersion in a body of electrolyte, a source of electricity to create a potential difference between the anode and cathode and a workholder for supporting the workpiece with its surface adjacent the anode to receive the products of electrolysis, the workholder and anode being moveable relative to each other to control the extent of exposure of the workpiece to the products of electrolysis.
权利要求
1. THE METHOD OF SURFACE PRETREATMENT OF BODIES OF NONCONDUCTIVE SYNTHETIC ELASTOMER MATERIAL TO IMPROVE THE ABILITY OF THAT SURFACE TO BE COATED OR ADHESIVELY BONDED COMPRISING ESTABLISHING AN ELECTRICAL POTENTIAL ACROSS AN ANODE AND A CATHODE IN A BODY OF AQUEOUS ELECTROLYTE TO GENERATED AT SAID ANODE, PRODUCTS OF ELECTROLYSIS REACTIVE WITH SAID ELASTOMER TO FORM REACTION PRODUCTS MORE READILY WET AND BONDED BY COATINGS AND ADHESIVE COMPOSITIONS, SAID ANODE BEING SUBSTANTIALLY INERT TO PRODUCTS OF ELECTROLYSIS GENERATED AT SAID ANODE, DISPOSING THE SURFACE TO BE TREATED IN SAID BODY OF ELECTROLYTE CLOSELY ADJACENT TO SAID ANODE FOR ENGAGEMENT AND REACTION WITH SAID PRODUCTS OF ELECTROLYSIS AS THEY ARE FORMED AND MAINTAINING SAID SURFACE ADJACENT SAID ANODE FOR A PERIOD FOR REACTION OF THE ELASTOMER AT SAID SURFACE WITH PRODUCTS OF ELECTROLYSIS GENERATED AT SAID ANODE TO FORM ON SAID BODY A SURFACE OF REACTED ELASTOMER INTEGRAL WITH THE ELASTOMER OF
2. A method according to claim 1 in which the aqueous electrolyte includes a member of the group consisting of sodium chloride, zinc chloride, nickel chloride, stannous chloride, cobalt chloride, magnesium chloride, ammonium chloride, calcium chloride or barium chloride.
3. A method according to claim 1 wherein the anode comprises graphite rods located adjacent and parallel to each other and the cathode is of carbon or stainless steel.
4. A method according to claim 1 in which a sole attaching surface of a tread member of synthetic elastomeric material is passed through the body of aqueous electrolyte closely ajacent the anode at a rate providing said period of reaction with products of electrolysis, the tread member is removed from the body of aqueous electrolyte, washed and dried.
5. A shoe making process in which a surface to be adhesively bonded of a tread member of synthetic elastomeric material is disposed adjacent an anode in a body of aqueous inorganic halide electrolyte, an electrical potential is established between said anode and a cathode in said body of electrolyte to generate at said anode products of electrolysis including a halogen reactive with said elastomer to form reaction products more readily wet and bonded by tread member attaching adhesive compositions, said anode being substantially inert to said products of electrolysis, said surface is maintained closely adjacent to said anode for a period for reaction of the elastomer at said surface with said products of electrolysis as they are generated at said anode, the tread member is removed from said body of electrolyte, unwanted residue from the electrolytic treatment is removed, and an adhesive composition is applied to the tread member.
6. A process according to claim 5 wherein the adhesive composition on the tread member is activated, and the tread member is pressed against a prepared shoe bottom in order to adhesively bond the tread member to the shoe bottom.
7. A shoe making process according to claim 6 in which the aqueous electrolyte includes a member of the group consisting of sodium chloride, zinc chloride, nickel chloride, stannous chloride, cobalt chloride, magnesium chloride, ammonium chloride, calcium chloride and barium chloride.
8. A shoe making process as defined in claim 9 in which the anode comprises graphite rods located adjacent and parallel to each other and the cathode is of carbon or stainless steel, and in which the tread member is passed through the body of aqueous electrolyte adjacent the anode at a rate providing said period for reaction with products of electrolysis.
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