Hydrocarbazolenines
阅读：255发布：2023-08-12
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1. THE PROCESS FOR THE PREPARATION OF A HYDROCARBAZOLENINE WHICHH COMPRISES HEATING WITH AN ACID CYCLIZING AGENT A HYDRAZONE OF A PHENYL HYDRAZINE HAVING A HYDROGEN ATTACHED TO A CARBON ATOM IN THE ORTHO POSITION TO THE HYDRAZINO-BEARING CARBON ATOM AND A KETONE OF THE GROUP CONSISTING OF A 2,3-X-CYCLOEXANONE AND A 2,3-X-CYCLOEXENONE WHEREIN X IS A 3 TO 5 ATOMS STRAIGHT CHAIN SELECTED FROM THE GROUP CONSISTING OF SATURATED AND MONO-OLEFINIC HYDROCARBON RADICALS AND SATURATED MONOOXA-, AND MONOAZA-, AND MONOTHIAHYDROCARBON RADICALS AND WHEREIN A HYDROGEN ATOM IS AVAILABLE AT THE 2-POSITION WHEREBY CYCLIZATION IS EFFECTED BETWEEN THE 2-POSITION OF SAID KETONE AND THE CARBON ATOM IN TE ORTHO POSITION TO THE SAID YDRAZINO-BEARING CARBON ATOM WITH THE SPLITTING OUT OF AMMONIA TO FORM A HYDROCARBAZOLENINE.
4. A HYDROCARBAZOLENINE HAVING THE FORMULA: WHEREIN R IS FROM ZERO TO THREE RADICALS SELECTED FROM THE GROUP CONSISTING OF HYDROXY, LOWER-HYDROCARBONOXY, HALOGEN, LOWER-ALKYL, NITRO, AMINO, AND ACYLAMIDE GROUPS IN WHICH ACYL IS THE ACYL GROUP OF A LOWER-HYDROCARBON CARBOXYLIC ACID; X IS A 3 TO 5 ATOM SATURATED MONOAZAHYDROCARBON STRAIGHT CHAIN; R1 IS AN N-SUBSTITUENT SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, A LOWERALKYL GROUP, AND A LOWER-ACYL GROUP IN WHICH ACYL IS THE ACYL RADICAL OF A LOWER-HYDROCARBON CARBOXYLIC ACID; R2 IS A C-SUBSTITUENT SELECTED FROM TE GROUP CONSISTING OF HYDROGEN AND LOWER-ALKYL, CARBOXY, AND LOWER-CARBALKOXY GROUPS; AND R3 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, LOWER-CARBOXYALKYL GROUP, A CARBOXY GROUP, A LOWER-CARBALKOXY GROUP, AN OXO GROUP, AND A 2 TO 3 CARBON ATOM KETALIZED-OXO GROUP.
5. THE HYDROCARBAZOLENINE HAVING THE FOLLOWING FORMULA:
7. THE HYDROCARBAZOLENINE HAVING TE FOLLOWING FORMULA:
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