序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 具有降低的亮度和雾度的黑色喷墨油墨 CN200780101769.0 2007-11-30 CN101878273B 2013-07-17 S·雷格斯瓦米; Z·U·雷曼; M·E·奥斯汀
发明揭示了一种在喷墨油墨印刷图像的黑色区域中减小L*min并降低层叠雾度的方法,该方法包括提供喷墨油墨接受介质,将至少一种喷墨油墨喷射在该介质上形成印刷介质,该印刷介质包含具有至少一个黑色区域的图像。所述至少一种喷墨油墨包括黑色喷墨油墨,该黑色喷墨油墨包含液体载剂和某种式1的黑色偶氮染料。该方法包括层叠所述印刷介质,获得在该黑色区域中具有减小的L*min和降低的层叠雾度的印刷介质。
2 具有降低的亮度和雾度的黑色喷墨油墨 CN200780101769.0 2007-11-30 CN101878273A 2010-11-03 S·雷格斯瓦米; Z·U·雷曼; M·E·奥斯汀
发明揭示了一种在喷墨油墨印刷图像的黑色区域中减小L*min并降低层叠雾度的方法,该方法包括提供喷墨油墨接受介质,将至少一种喷墨油墨喷射在该介质上形成印刷介质,该印刷介质包含具有至少一个黑色区域的图像。所述至少一种喷墨油墨包括黑色喷墨油墨,该黑色喷墨油墨包含液体载剂和某种式1的黑色偶氮染料。该方法包括层叠所述印刷介质,获得在该黑色区域中具有减小的L*min和降低的层叠雾度的印刷介质。
3 多偶氮染料 CN97122918.X 1997-11-25 CN1183437A 1998-06-03 G·拉姆; M·维森菲尔特
式Ⅰ的多偶氮染料,其中各基团如说明书中定义,该多偶氮染料用新型的磺酰胺中间体制备,适用作天然物质或合成物质染色的染料。
4 폴리에스테르 섬유용 아조 흑색 염료 조성물 KR1019980029639 1998-07-23 KR1020000009319A 2000-02-15 손건평; 조승현; 이철호
PURPOSE: An azo black dye composition is provided which has improved dyeability and does not induce allergy to human body. CONSTITUTION: The composition comprises: 5-30 wt.% of the azo dye represented by formula I; 5-30 wt.% of the azo dye represented by formula II; 10-40 wt.% of the azo dye represented by formula III; 2-10 wt.% of one selected from naphthalene sulfuric acid formaldehyde condensate, arylsulfonate formaldehyde condensate, special polycarboxylate type dispersing agent and sulfide phenolformaldehyde condensate; 25-50 wt.% of lignin sulfonate dispersing agent; 0-3 wt.% of one selected from alkylnaphthalene sulfonate, dialkylsulfosuccinate, alkylphenylether disulfonate, alkylphosphate and polyoxyethylene alkylethersulfate. In the formula, R1, R2, R3 and R4 are methyl or ethyl; R5 and R6 are ethyl, cyanoethyl, acetoxyethyl or aryl; X, X1, X2, R7 and R8 are, independently, H, cyano, nitro or Br; R9 and R10 are, independently, ethyl, cyanoethyl or acetoxyethyl. The black dye composition can be useful for dying polyester fabrics.
5 수용성 폴리아조 염료 및 그 제조방법 KR1019950002457 1995-02-10 KR1019960031550A 1996-09-17 김갑수
본 발명은 수용성 폴리아조 염료 및 그 제조 방법에 관한 것이다. 헥사키스아조를 갖는 본 발명의 염료는 일광 견뢰도, 수세 견뢰도, 버핑효과, 내산성 등의 염료 특성이 우수하다. 또한 본 발명의 염료는 제조공정의 중간 단계에서의 염석, 여과 단계를 거치지 않고 단일 반응기 내에서 제조될 수 있으므로서 그 생산비용이 저렴하다.
6 수불용성 복합 모노 아노 염료의 제조 방법 KR1019830004811 1983-10-11 KR1019850003419A 1985-06-17 김준호; 이병진; 박재서
내용없음
7 BISAZO COMPOUNDS PCT/EP2010002836 2010-05-08 WO2010130377A3 2011-03-10 NUSSER RAINER; GEIGER ULRICH; HASEMANN LUDWIG
Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates.
8 BISAZO COMPOUNDS PCT/EP2010/002836 2010-05-08 WO2010130377A2 2010-11-18 NUSSER, Rainer; GEIGER, Ulrich; HASEMANN, Ludwig

Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates.

9 BLACK INK-JET INKS WITH REDUCED LIGHTNESS AND HAZE PCT/US2007/086141 2007-11-30 WO2009070176A1 2009-06-04 RENGASWAMY, Sukanya; REHMAN, Zia, U.; AUSTIN, Mary, E.

A method of decreasing L*min and reducing stacked haze in a black region of an ink-jet printed image is disclosed which comprises providing an ink-jet ink receptive medium and ink-jetting at least one ink-jet ink onto the medium to form a printed medium comprising an image having at least one black region. At least one of the ink-jet inks includes a black ink-jet ink comprising a liquid vehicle and a certain black azo dye having the Formula 1. The method includes stacking the printed medium, to obtain a printed medium having decreased L*min and reduced stacked haze in the black region(s).

10 폴리에스테르 섬유용 아조 흑색 염료 조성물 KR1019980029639 1998-07-23 KR100289005B1 2001-09-17 손건평; 조승현; 이철호
본 발명은, 다음 조성으로 구성되는 폴리에스테르 섬유용 아조 흑색 염료 조성물에 관한 것이다. 다음 일반식(Ⅰ)의 아조 염료 5∼30중량%, 다음 일반식(Ⅱ)의 아조 염료 5∼30중량%, 다음 일반식(Ⅲ)의 아조 염료 10∼40중량%, 나프탈렌술포릭액시드포름알데히드컨덴세이트, 아릴술포네이트포름알데히드컨덴세이트, 스페셜폴리카르복실레이트타입분산제, 설파이티드페놀포름알데히드컨덴세이트 중에 선택된 어느하나가 2∼10중량%, 리그닌술포네이트분산제 25∼50중량%, 알킬나프탈렌술포네이트, 디알킬술포석시네이트, 알킬디페닐에테르디술포네이트, 알킬포스페이트, 폴리옥시에틸렌알킬에테르설페이트 중에서 선택된 어느하나가 0∼3중량%. 상기 아조 염료 및 첨가제를 함유하는 분산 염료 조성물은 직물 형태의 폴리에스테르 섬유를 흑색으로 염색시키는데 유용하게 사용될 수 있다. 상기에서, R 1 , R 2 , R 3 , R 4 는 메틸, 에틸기이고, R 5 는 에틸, 시아노에틸, 아세톡시에틸 또는 아릴기이며, R 6 는 에틸, 시아노에틸, 아세톡시에틸 또는 아릴기이며, X, X 1 , X 2 , R 7 , R 8 는 각각 독립적으로 수소, 시아노, 니트로 또는 브롬이고, R 9 , R 10 은 각각 독립적으로 에틸, 시아노에틸 또는 아세톡시 에틸기이다.
11 신규 흑색 및 네이비블루 분산염료 조성물 KR1020000051549 2000-09-01 KR1020000072392A 2000-12-05 최재홍; 이의재; 홍성의
PURPOSE: A black or navy blue disperse dye composition compounded with three blue azo dyes, one red azo dye, one yellow dye and one brown azo dye in an optimum ratio is provided which has excellent heat migration, a characteristic by which an unexhausted dye is easily washed from the surface of fibers by a detergent and high wet fastness and gas fastness and exhibits low metamerism. CONSTITUTION: The disperse dye composition comprises 10 to 30% by weight of a blue azo dye compound of formula 4, 10 to 20% by weight of a blue azo dye compound of formula 5, 10 to 30% by weight of a blue azo dye compound of formula 6, 10 to 20% by weight of a red azo dye compound of formula 7, 10 to 30% by weight of a yellow azo dye compound of formula 8 and 2 to 10% by weight of a brown azo dye compound of formula 9. In formula, R is H, methyl or acetylamino, Y is methoxy or ethoxy, A and B are the same or different acetoxy or oxopropoxy, R1 and R2 are H or halogen.
12 수용성 폴리아조 염료 및 그 제조방법 KR1019950002457 1995-02-10 KR100124152B1 1997-11-20 김갑수
Water insoluble polyazo dye(I) having a good light fastness, water fastness, buffing effect, and acid resistant properties is manufactured. For an example, 31.9g 1-hydroxy-8-amino naphthalene-3,6-disulfonic acid is diazotiated with 100 ml water, 4.1g caustic soda, 7g sodium nitrite and excess sodium nitride is removed from a reactant to give a diazo solution, which is added with 10.9g 1-hydroxy-3-amino benzene. 4g 5-Amino-2-(para-aminoanilino)-benzene sulfonic acid, is tetraazotiated with 30% sodium nitrite and bisazo solution. In formula, X is NH, SO2NH, SO2 or O, X is SO3H, SO3Na, SO3K, H, Cl, or COOH.
13 BLACK INK-JET INKS WITH REDUCED LIGHTNESS AND HAZE EP07854878.1 2007-11-30 EP2220168A1 2010-08-25 RENGASWAMY, Sukanya; REHMAN, Zia, U.; AUSTIN, Mary, E.
A method of decreasing L*min and reducing stacked haze in a black region of an ink-jet printed image is disclosed which comprises providing an ink-jet ink receptive medium and ink-jetting at least one ink-jet ink onto the medium to form a printed medium comprising an image having at least one black region. At least one of the ink-jet inks includes a black ink-jet ink comprising a liquid vehicle and a certain black azo dye having the Formula 1. The method includes stacking the printed medium, to obtain a printed medium having decreased L*min and reduced stacked haze in the black region(s).
14 Ink jet ink, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus EP09005655.7 2009-04-22 EP2113539A1 2009-11-04 Nakata, Eiichi; Tomioka, Hiroshi; Tamanuki, Yukako

An ink jet ink including at least a compound represented by the following general formula (I) and organic solvents. When the organic solvents are classified by MOH/MW indicating a proportion of the molecular weight of hydroxyl group to the molecular weight of the organic solvents into an organic solvent A whose MOH/MW is 0 or more and less than 0.2, an organic solvent B whose MOH/MW is 0.2 or more and less than 0.4, and an organic solvent C whose MOH/MW is 0.4 or more and less than 1.0, the ink contains at least one organic solvent A, at least one organic solvent B and at least one organic solvent C. The at least one organic solvent A contains a nitrogen-containing organic solvent in an amount of 80.0% by mass or more of the at least one organic solvent A.

15 Photoreceptor EP85300955 1985-02-13 EP0156481A3 1986-01-29 Hirose, Naohiro; Sasaki, Osamu; Takizawa, Yoshio

Disclosed is a photoreceptor comprising a support and a photosensitive layer which contains an axo compounf of the formula [i]: wherein Q is a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an alkylsulfonyl group, an aryl group, an acetylamido group, (Q, is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or (Q,, Q3 and Q4 independently are an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group, a cyano group, a vinyl group, a halogen atom or a hydrogen atom), said alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y, and Y2 independently are hydrogen atom, a halogen atom, a cyano group, a hydroxy group, an alkyl group or an alkoxy group; m and n each represent an integer of 0 to 2, and m and n cannot be both 0; A represents a group represented

by any one of the following formulae: wherein Z is a group of atoms necessary for constituting a substituted or unsubstituted aromatic carbon ring or an aromatic heterocyclic ring. P3 is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group. R. is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxyl group and its ester group or a cyano group, A' is a substituted or unsubstituted aryl group, R, and R3 independently are a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted aryl group.

16 Photoreceptor EP85300954.6 1985-02-13 EP0153145A2 1985-08-28 Hirose, Naohiro; Sasaki, Osamu; Takizawa, Yoshio

Disclosed is a photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula (I): wherein PI and P2 are independently a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an acetylamido group, an alkylsulfonyl group, (Q1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or Q2-C- (Q1, Q3 and Q4 independently are a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group or a vinyl group), the alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent;

Y1 and Y2 independently are a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, an alkyl group or an- alkoxy group; m and n each represent an integer of 0 to 2, and m and n cannot be both 0; A represents a group representend by any one of the following formulae: wherein Z is a group of atoms necessary for constituting a substituted or unsubstituted aromatic carbon ring or an aromatic heterocyclic ring, P3 is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group, R1 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxyl group and its ester group or a cyano group, A' is a substituted or unsubstituted aryl group, R2 and R3 independently are a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted aryl group.

17 Water-soluble azo compounds, methods for their preparation and their use as dyestuffs EP81107663 1981-09-26 EP0052716B1 1985-02-20 ROSENBUSCH, KURT, DR.
18 Herstellung von Pigmenten EP80810339.4 1980-11-05 EP0029009A1 1981-05-20 Pechey, David Thomas, Dr.; Coy, John Hugh, Dr.

Verfahren zum Herstellen von Monoazo- oder Disazo- pigmenten, dadurch gekennzeichnet, dass man a) zu einer Lösung eines Diazonium- und/oder Tetrazoniumsalzes eines aromatischen oder heterocyclischen Amins eine Lösung oder Suspension enthaltend 0,1-50 Gew.% des theoretisch einzusetzenden Gesamtgewichts einer oder mehrerer Kupplungskomponenten zugibt, und b) die Kupplungsreaktion durch Beimischen des gemäss Verfahrensschritt a) erhaltenen teilweise gekuppelten Produkts zu einer Lösung oder Suspension einer oder mehrerer im Verfahrensschritt a) eingesetzten oder davon verschiedenen Kupplungskomponente vervollständigt.

Die so hergestellten Pigment zeigen verglichen mit nach herkömmlichen Methoden hergestellten Produkten erhöhte Farbstärke, verbesserte Transparenz, verbesserte Fliesseigenschaften, erhöhte Reinheit und Dispergierbarkeit.

19 BLACK INK-JET INKS WITH REDUCED LIGHTNESS AND HAZE EP07854878.1 2007-11-30 EP2220168B1 2012-07-25 RENGASWAMY, Sukanya; REHMAN, Zia, U.; AUSTIN, Mary, E.
A method of decreasing L*min and reducing stacked haze in a black region of an ink-jet printed image is disclosed which comprises providing an ink-jet ink receptive medium and ink-jetting at least one ink-jet ink onto the medium to form a printed medium comprising an image having at least one black region. At least one of the ink-jet inks includes a black ink-jet ink comprising a liquid vehicle and a certain black azo dye having the Formula 1. The method includes stacking the printed medium, to obtain a printed medium having decreased L*min and reduced stacked haze in the black region(s).
20 Bisazo compounds EP09160232.6 2009-05-14 EP2251322A1 2010-11-17 Nusser, Rainer, Dr.; Geiger, Ulrich, Dr.; Hasemann, Ludwig, Dr.

Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates.

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