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Reduction of cuprous cyanide with hydrogen in a liquid medium

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专利汇可以提供Reduction of cuprous cyanide with hydrogen in a liquid medium专利检索,专利查询,专利分析的服务。并且Cuprous cyanide is dispersed in a high boiling hydrocarbon oil nonreactive with hydrogen, copper or HCN, such as a paraffin mineral oil, and hydrogen is passed through at temperatures from 190* C. to temperatures at or a little below the boiling point of the oil. With an oil boiling above 325* C., suitable temperatures are from a little below 300* C. to approximately 325* C. Hydrogen is passed through at a rate and for a time to produce a substantial excess, for example at least 50 percent excess, and the cuprous cyanide is reduced almost quantitatively to a very pure copper powder. After reduction is complete, the copper powder is separated from the oil, the last traces of oil being removed by known means, such as solvent washing, or removed when the copper is melted. The excess hydrogen carries with it HCN formed in the reduction, and the two are separated and reused.,下面是Reduction of cuprous cyanide with hydrogen in a liquid medium专利的具体信息内容。

  • 2. A process according to claim 1 in which the temperature during reaction ranges from about 300* C. to the temperature below at which the oil boils.
  • 3. A process according to claim 2 in which the oil is a high-boiling paraffin oil.
  • 4. A process according to claim 3 in which the reaction of hydrogen with cuprous cyanide is at substantially atmospheric pressure.
  • 5. A process according to claim 2 in which the reaction of hydrogen with cuprous cyanide is at substantially atmospheric pressure.
  • 6. A process according to claim 2 in which the hydrogen and hydrocyanic acid gases produced by the reaction are cooled down and are separated from each other and oil vapor, the cooling being effected by heat exchange with separated hydrogen, whereby the latter is preheated.
  • 7. A process according to claim 3 in which the hydrogen and hydrocyanic acid gases produced by the reaction are cooled down and are separated from each other and oil vapor, the cooling being effected by heat exchange with separated hydrogen, whereby the latter is preheated.
  • 8. A process according to claim 4 in which the hydrogen and hydrocyanic acid gases produced by the reaction are cooled down and are separated from each other and oil vapor, the cooling being effected by heat exchange with separated hydrogen, whereby the latter is preheated.
  • 9. A process according to claim 5 in which the hydrogen and hydrocyanic acid gases produced by the reaction are cooled down and are separated from each other and oil vapor, the cooling being effected by heat exchange with separated hydrogen, whereby the latter is preheated.
  • 10. A continuous process according to claim 2 in which the suspension of cuprous cyanide is introduced into a first reaction vessel through which the hydrogen is passed, excess hydrogen and HCN are removed, and the suspension of partially reduced cuprous cyanide in oil is overflowed into a succeeding reactor through which further hydrogen is passed and overflow repeated to further reactors in series until the cuprous cyanide is substantially completely reduced in the last reactor and the suspension of copper in oil is overflowed from the last reactor and the copper separated and recovered.
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