1 |
烃的氧化偶联方法 |
CN201080029148.8 |
2010-06-25 |
CN102471183A |
2012-05-23 |
S·钦塔; J·托尔曼; J·R·巴特勒; J·亨特; T·里维斯 |
一种用于烃的氧化偶联,如将甲烷氧化偶联到甲苯上的方法,它包括在反应器内提供氧化催化剂,在一组反应条件下进行氧化偶联反应。所述氧化催化剂包含(A)至少一种选自下组的元素:镧系元素、Mg、Ca以及周期表第4族元素(Ti、Zr和Hf);(B)至少一种选自下组的元素:周期表第1族元素Li、Na、K、Rb、Cs,第3族元素(包括La和Ac)和第5-15族元素;(C)至少一种选自下组的元素:第1族元素Li、Na、K、Rb、Cs,以及元素Ca、Sr和Ba;以及(D)氧。 |
2 |
加氢烷基化方法 |
CN201280070667.8 |
2012-11-30 |
CN104136402A |
2014-11-05 |
C·L·贝克; J·R·莱特纳; K·H·库施乐; H·奈尔 |
在制备苯酚的方法中,在催化剂存在下在有效制备包含环己基苯以及环己烷的反应产物条件下用氢气将苯加氢烷基化。将至少一部分来自所述加氢烷基化反应产物的环己烷然后脱氢以制备包含苯、甲苯以及氢气的脱氢流出物。至少一部分该脱氢流出物用含苯的料流洗涤以将至少一部分来自该脱氢流出物的甲苯转移到含苯的料流。 |
3 |
转换生物质为气体燃料碳氢化合物的方法 |
CN201080008981.4 |
2010-02-23 |
CN102333848A |
2012-01-25 |
玛丽亚·弗莱赞尼-斯特凡诺普洛斯; 布兰科·左吉克; 布赖恩·里克斯; 格雷戈里·斯特凡诺普洛斯 |
一种方法,包括提供含有得自生物质的C2-6羧酸或C2-6羧酸盐的溶液,以及将该溶液与固体催化剂接触以形成C1-5碳氢化合物。 |
4 |
加氢烷基化方法 |
CN201280070667.8 |
2012-11-30 |
CN104136402B |
2015-12-09 |
C·L·贝克; J·R·莱特纳; K·H·库施乐; H·奈尔 |
在制备苯酚的方法中,在催化剂存在下在有效制备包含环己基苯以及环己烷的反应产物条件下用氢气将苯加氢烷基化。将至少一部分来自所述加氢烷基化反应产物的环己烷然后脱氢以制备包含苯、甲苯以及氢气的脱氢流出物。至少一部分该脱氢流出物用含苯的料流洗涤以将至少一部分来自该脱氢流出物的甲苯转移到含苯的料流。 |
5 |
氯化副产物和废产物转化为有用材料的方法 |
CN93121101.8 |
1993-11-30 |
CN1103395A |
1995-06-07 |
L·N·伊托; A·D·哈雷; M·T·霍布鲁克; D·D·史密斯; C·B·莫奇森; M·D·希耐罗斯 |
一种将各种氯代烃副产物和废产物催化转化为主要是有用或可销售的低氯化产物的方法,其中氯代烃原料在一种催化剂存在下与氢气反应,该催化剂包括一种元素或化合物形式的VIII族金属(如铂),和一种元素或化合物形式的IB族金属(如铜)。 |
6 |
1,2-二氯丙烷转化为丙烯的方法 |
CN93121102.6 |
1993-11-30 |
CN1103394A |
1995-06-07 |
L·N·伊托; A·D·哈雷; M·T·霍布鲁克; D·D·史密斯; C·B·莫奇森; M·D·希耐罗斯 |
以高转化率和高选择性将1,2-二氯丙烷催化转化为丙烯的方法,该法是在包含VIII族金属如铂元素或化合物和IB族金属如铜元素或化合物的催化剂存在下使1,2-二氯丙烷与氢进行反应。 |
7 |
Dealkylation process |
US14473464 |
2014-08-29 |
US09067854B2 |
2015-06-30 |
Kun Wang; James R. Lattner |
In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound. |
8 |
Process for the Oxidative Coupling of Hydrocarbons |
US14283529 |
2014-05-21 |
US20140257005A1 |
2014-09-11 |
Sivadinarayana Chinta; Joseph L. Thorman; James R. Butler; Joe Hunter; Taylor Rives |
A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. |
9 |
CONVERTING BIOMASS TO GASEOUS FUEL HYDROCARBONS |
US13202239 |
2010-02-23 |
US20120035403A1 |
2012-02-09 |
Maria Flytzani-Stephanopoulos; Branko Zugic; Brian Ricks; Gregory Stephanopoulos |
A method includes providing a solution containing a C2-6 carboxylic acid or a C2-6 carboxylate that is derived from biomass; and contacting the solution with a solid catalyst to form a C1-5 hydrocarbon. |
10 |
Process for the Oxidative Coupling of Hydrocarbons |
US12494138 |
2009-06-29 |
US20100331593A1 |
2010-12-30 |
Sivadinarayana Chinta; Joseph Thorman; James Butler; Joe Hunter; Taylor Rives |
A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. |
11 |
Process for the oxidative coupling of hydrocarbons |
US14283529 |
2014-05-21 |
US09227887B2 |
2016-01-05 |
Sivadinarayana Chinta; Joseph L. Thorman; James R. Butler; Joe Hunter; Taylor Rives |
A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. |
12 |
Converting biomass to gaseous fuel hydrocarbons |
US13202239 |
2010-02-23 |
US09090833B2 |
2015-07-28 |
Maria Flytzani-Stephanopoulos; Branko Zugic; Brian Ricks; Gregory Stephanopoulos |
A method for producing a C1-5 hydrocarbon from a solution containing a C2-6 carboxylic acid or a C2-6 carboxylate which is derived from biomass by contacting the solution with a solid catalyst to decarboxylate the C2-6 carboxylic acid or the C2-6 carboxylate, thereby forming a C1-5 hydrocarbon. |
13 |
Process for the oxidative coupling of hydrocarbons |
US13867295 |
2013-04-22 |
US08729328B2 |
2014-05-20 |
Sivadinarayana Chinta; Joseph L. Thorman; James R. Butler; Joe Hunter; Taylor Rives |
A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. |
14 |
Dealkylation Process |
US13578755 |
2011-02-03 |
US20120310024A1 |
2012-12-06 |
Kun Wang; James R. Lattner |
In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound. |
15 |
Valid chlorinated alkanes by-products or waste, how to convert to a low degree of chlorination alkene |
JP50902893 |
1993-08-13 |
JPH08502248A |
1996-03-12 |
エヌ. イトー,ラリー; ディー. シスネロス,マーク; ディー. スミス,デビッド; ハーレー,エー.デイル; ティー. ホルブルック,マイケル; ビー. マーチソン,クレイグ |
(57)【要約】 種々の塩素化されているアルカン副生成物及び廃棄物を有効なかつ商品性のある塩素化度の低いアルケンを含む反応生成物に触媒を用いて転化する方法であって、元素もしくは化合物形状の1種以上のIB族金属(例えば銅)及び元素もしくは化合物形状の1種以上のVIII族金属(例えば白金)を含む触媒の存在下において塩素化されているアルカン供給材料を水素と反応させる方法。 |
16 |
Hydroalkylation process |
US14375967 |
2012-11-30 |
US09090528B2 |
2015-07-28 |
Christopher L. Becker; James R. Lattner; Keith H. Kuechler; Hari Nair |
In a process for producing phenol, benzene is hydroalkylated with hydrogen in the presence of a catalyst under conditions effective to produce a hydroalkylation reaction product comprising cyclohexylbenzene and cyclohexane. At least a portion of the cyclohexane from said hydroalkylation reaction product is then dehydrogenated to produce a dehydrogenation effluent comprising benzene, toluene and hydrogen. At least a portion of the dehydrogenation effluent is washed with a benzene-containing stream to transfer at least a portion of the toluene from the dehydrogenation effluent to the benzene-containing stream. |
17 |
Hydroalkylation Process |
US14375967 |
2012-11-30 |
US20150005531A1 |
2015-01-01 |
Christopher L. Becker; James R. Lattner; Keith H. Kuechler; Hari Nair |
In a process for producing phenol, benzene is hydroalkylated with hydrogen in the presence of a catalyst under conditions effective to produce a hydroalkylation reaction product comprising cyclohexylbenzene and cyclohexane. At least a portion of the cyclohexane from said hydroalkylation reaction product is then dehydrogenated to produce a dehydrogenation effluent comprising benzene, toluene and hydrogen. At least a portion of the dehydrogenation effluent is washed with a benzene-containing stream to transfer at least a portion of the toluene from the dehydrogenation effluent to the benzene-containing stream. |
18 |
Dealkylation Process |
US14473464 |
2014-08-29 |
US20140371499A1 |
2014-12-18 |
Kun Wang; James R. Lattner |
In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound. |
19 |
Dealkylation process |
US13578755 |
2011-02-03 |
US08853482B2 |
2014-10-07 |
Kun Wang; James R. Lattner |
In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound. |
20 |
Process for the oxidative coupling of hydrocarbons |
US14072971 |
2013-11-06 |
US08796497B2 |
2014-08-05 |
Sivadinarayana Chinta; Joseph L. Thorman; James R. Butler; Joe Hunter; Taylor Rives |
A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen. |