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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
61	Dispositif generateur de gaz portable et alimentation electrique à pile combustible comportant un tel dispositif	EP08159861.7	2008-07-07	EP2014613A1	2009-01-14	Damery, Emmanuel; Delmas, Jérôme; Laurent, Jean-Yves; Valon, Bruno
Dispositif générateur de gaz par mise en contact d'un réactif liquide et d'un réactif solide, comportant un réservoir (6) de réactif liquide et une chambre de réaction (8) destinée à comporter du réactif solide, le réservoir (6) et la chambre de réaction (8) étant séparées de manière étanche par une paroi mobile (4), une sortie de collecte (26) du gaz généré dans la chambre de réaction et des moyens d'injection (14) du réactif liquide sur le réactif solide, lesdits moyens d'injection (14) traversant la paroi mobile (4) et étant aptes à se déplacer dans le réactif solide.
62	PROCEDE DE PREPARATION D ACETYLENE ET INSTALLATION POUR LA MISE EN OEUVRE DU PROCEDE	EP04721220.4	2004-03-17	EP1613713A1	2006-01-11	DELCORSO, Fabrice; CAMPO, Philippe
The invention relates to a method for production of acetylene by hydrolysis of calcium carbide, characterised in comprising an initial step (a) of addition of a water-soluble reducing salt to the water which reacts with the dissolved oxygen. The invention further relates to a plant for carrying out said method.
63	Apparatus and process for the production of acetylene.	EP90916963.3	1990-10-25	EP0498844B1	1994-08-31	BUNGER, James, W.; RYU, Hoil; DEVINENI, Prasad, A., V.
A two-staged process for producing acetylene and calcium chloride from calcium carbide (12) and water (12) has two successive reaction steps. In step Number 1, calcium carbide is charged into an entrained flow-type reactor (10) vessel containing water. The reaction which follows proceeds to about 60-90 % completion. The entrained reaction products and the unreacted feed material are carried over to a secondary reactor (16) to complete the reaction, and the acetylene gas is drawn off (26). Calcium hydroxide product is removed from the reactor (23) and reacted with hydrogen chloride to form calcium chloride. Heat generated by the exothermic reactions of water with calcium carbide and HCl with calcium hydroxide is used to dry the calcium chloride product and improve its value. In the presence of excess of water, the calcium carbide-water reaction is effectively a first order, irreversible reaction.
64	TWO-STAGE PROCESS FOR PRODUCTION OF CALCIUM CHLORIDE AND ACETYLENE	EP90916963.0	1990-10-25	EP0498844A1	1992-08-19	BUNGER, James, W.; RYU, Hoil; DEVINENI, Prasad, A., V.
Un procédé en deux étapes de production d'acétylène et de chlorure de calcium à partir de carbure de calcium (12) et d'eau (12) comprend deux étapes de réaction successives. Dans l'étape numéro 1, du carbure de calcium est chargé dans un réacteur du type à écoulement entraîné (10) contenant de l'eau. La réaction qui suit se poursuit jusqu'à environ 60 à 90 % de la réaction complète. Les produits de réaction entraînés et la matière d'alimentation n'ayant pas réagis sont transportés vers un réacteur secondaire (16) pour terminer la réaction, puis du gaz acétylène est soutiré (26). Un produit d'hydroxyde de calcium est extrait du réacteur (23) puis réagit avec du chlorure d'hydrogène pour former du chlorure de calcium. De la chaleur générée par des réaction exothermiques d'eau avec du carbure de calcium et d'HCl avec de l'hydroxyde de calcium est utilisée pour sécher le produit de chlorure de calcium et améliorer sa valeur. En présence d'un excès d'eau, la réaction carbure de calcium-eau est en réalité une réaction de premier ordre irréversible.
65	Acetylene gas reactor	EP83105750	1983-06-11	EP0097860A3	1984-11-28	Priesemuth, Wolfgang, Dipl.-Ing.

66	A process for the production of an acetylene base stable fuel gas, the products obtained by this process and the use of the produced acetylene base fuel gas	EP80301997.5	1980-06-13	EP0021748B1	1984-10-03	Hayes, Edward O.

67	Acetylene gas reactor	EP81108804	1981-10-23	EP0071671A3	1983-05-25	Priesemuth, Wolfgang, Dipl.-Ing.

68	Method and system for acetylene (C2H2) or ethylene (C2H4) production	US14949130	2015-11-23	US09850185B2	2017-12-26	Stefan Petters; Klaus Mauthner; Ka Chun Tse
The present invention is concerned with a method of production of acetylene or ethylene. The method has the steps of providing supplies of hydrogen, water, carbon monoxide, carbon dioxide, and methane, respectively, providing a catalyst system having firstly a catalyst selected from group VIII transition metal oxides, and secondly a catalyst support, treating the methane supply with the catalyst system for producing a first reactant, providing a second reactant, and reacting the first reactant with the second reactant for producing an intermediate, wherein the intermediate is calcium carbide (CaC2).
69	Loop-Route Production Method and System for Polyvinyl Chloride	US14904499	2013-12-19	US20160168297A1	2016-06-16	Weimin Yang; Hua Yan; Dongsheng Liu; Jinguang Zhong
The present invention relates to a loop-route production method and system for polyvinyl chloride, and belongs to the intersecting fields of coal chemicals, polymer materials and chemical machinery. Limestone and carbon materials such as coal are reacted in an oxygen-enriched high temperature furnace to obtain calcium carbide and carbon monoxide, and then acetylene and carbon monoxide are respectively produced from calcium carbide and dichloroethane (obtaining ethylene, etc., through methanol or ethanol); both of the end products are combined to form a closed-loop; acetylene and dichloroethane are reacted to produce a vinyl chloride monomer, which is polymerized to obtain polyvinyl chloride. The system of the present invention mainly includes a device for pulverizing and mixing solid raw materials, a device for conveying solid materials, an oxygen-enriched calcium carbide furnace, an oxygen-enriched air-blowing device, a tube-shell thermostatic reactor, a fixed bed tubular reactor, a fluidized bed reactor, an acetylene generator having a heat exchanger, a fixed bed reactor and a polymerization reactor, The present invention has the advantages of not only removing the dependence on oil resources during the production of polyvinyl chlorides, but also totally eliminating the mercury pollution.
70	Hydrocarbon-containing mixture and method and system for making the same	US13476702	2012-05-21	US08742194B2	2014-06-03	Douglas O. Mapp, Sr.; Douglas O. Mapp, II
A hydrocarbon-containing mixture including acetylene and butenyne is disclosed. The hydrocarbon-containing mixture can include 10% to 89% acetylene, 10% to 89% butenyne, and at least 0.25% dimethyl butadiyne. A method and system for producing the hydrocarbon-containing mixture is also disclosed. The system can include an acetylene production subsystem comprising at least one vessel and an acetylene output for delivering acetylene to a finishing vessel via a finishing vessel inlet. The finishing vessel can include a diffuser in fluid communication with the finishing vessel inlet, and gas exiting the diffuser can pass through a reaction chamber filled with solid calcium carbide before passing through a finishing vessel outlet.
71	Self contained fuel system for solid oxide fuel cell	US11208125	2005-08-18	US07635531B1	2009-12-22	Louis G. Carreiro; A. Alan Burke; Steven P. Tucker
A power source for an unmanned undersea vehicle with increased energy density is described that employs a self-contained fuel system to address carbon dioxide evolution. A solid oxide fuel cell serves as the power source in the self-contained fuel system. In combination with the solid oxide fuel cell, the system comprises a chemical composite that is combined with water to create both a hydrocarbon fuel for the solid oxide fuel cell and a water-soluble byproduct. The byproduct is then combined with the carbon dioxide gas generated by the fuel cell to create a storable solid precipitate.
72	PORTABLE GAS GENERATING DEVICE AND ELECTRICAL FUEL CELL POWER SUPPLY COMPRISING SUCH A DEVICE	US12171561	2008-07-11	US20090017347A1	2009-01-15	Emmanuel Damery; Jerome Delmas; Jean-Yves Laurent; Bruno Valon
Device for generating gas by placing a liquid reactant in contact with a solid element, comprising a liquid reactant tank (6) and a reaction chamber (8) intended to contain the solid element, wherein the tank (6) and the reaction chamber (8) are separated in a sealed manner by a mobile wall (4), with an outlet port (26) for collecting the gas generated in the reaction chamber and means (14) for injecting the liquid reactant onto the solid element, which injection means (14) pass through the mobile wall (4) and are capable of moving into the solid element.
73	Power generation system	US11504201	2006-08-15	US20080044323A1	2008-02-21	Pete Rosas
A modular system for generation of acetylene gas, in a reactor suitable for the controlled reaction of calcium carbide and water, is disclosed. In this system, a self-container reactor module is provided which is suitable for coupling to an acetylene gas reservoir. In one of the preferred embodiments of this invention, this reactor module can include a primary and a secondary charge of calcium carbide, and a stoichiometric excess of water. Acetylene gas is formed by initial contact of a primary calcium carbide charge with water in the reactor reservoir. Upon essentially complete reaction of the primary charge and the water in the reservoir, the pressure within the reactor is monitored, as such gas is drawn off to fuel the operation of an internal combustion engine. Where such pressure drops to, or below a pre-determined level, a secondary charge of calcium carbide is contacted with the remaining water in the reactor reservoir, so as to prevent interruption in the fueling of the internal combustion engine. These modules can also be “daisy chained” together, and thereafter sequentially activated, to provide essentially continuous operation of an internal combustion engine.
74	CARBIDE SUPERCELL FOR DRY ACETYLENE GENERATION AND AN INTERNAL COMBUSTION ENGINE USING THE SAME	US11767335	2007-06-22	US20070295288A1	2007-12-27	Joseph W. Wulff; Harry J. Wulff
Novel carbide supercells for dry acetylene generation are disclosed herein, along with methods of use and internal combustion engines incorporating the carbide supercells. A carbide supercell according to one embodiment includes an outer shell defining an interior gas chamber and a rotating basket positioned in the gas chamber. The basket defines a plurality of holes and is configured to contain at least one calcium carbide rock. An injector is adjacent the basket for spraying a liquid into the basket, and a controller is in data communication with the injector for actuating the injector. A chamber outlet is adjacent an upper end of the gas chamber.
75	Composition for acetylene production and method for treating lime slurry by-product from acetylene production	US10410939	2003-04-10	US20030208958A1	2003-11-13	G. Wayne Linn; Nancy H. Davis; Michael D. Simons; Mark F. Nilsen
The use of a settling aid in the reactor during acetylene production results in the by-product lime slurry being easier to handle and allows the acetylene producers to use different sources of calcium carbide as well as the calcium carbide manufacturers to use different sources of raw materials to make calcium carbide.
76	Integrated apparatus and process for high recovery of acetylene from the reaction of calcium carbide with water	US880933	1997-06-23	US5955040A	1999-09-21	James W. Bunger; Christopher P. Russell; Jerald W. Wiser; Jesse C. Tsai
An apparatus for the manufacture of acetylene and hydrated lime from the reaction of calcium carbide and an excess of water is disclosed. A primary reactor for the initial reaction of the calcium carbide and water is disposed concentrically within a secondary reactor. Hydrated lime and unreacted calcium carbide flow directly from the primary reactor to the secondary reactor, where the carbide lime settles from the water and is removed.
77	Acetylene generating system	US3743487D	1971-08-06	US3743487A	1973-07-03	BAKER G
A SYSTEM FOR GENERATING ACETYLENE GAS BY REACTING CALCIUM CARBIDE AND AN EXCESS OF WATER WHEREIN THE RESULTING WATER LIME SLURRY IS TREATED TO REMOVE THE LIME SLUDGE AND THE TREATED WATER IS RECYCLED FOR USE IN THE REACTION VESSEL.
78	Composition causing combustion when contacted with water	US3662801D	1969-05-15	US3662801A	1972-05-16	SCHNEIDER KARL
A material for causing combustion which includes a carbide capable of reacting with water to form an inflammable gas, an igniter in the form of a metal such as sodium and, optionally, an amide or peroxide of an alkali metal or an alkaline earth metal, and/or other compounds evolving oxygen.
79	Method of and apparatus for the production of acetylene	US3485605D	1966-06-02	US3485605A	1969-12-23	GHITA DUMITRU; SAIZESCU NASTASE; BOLINTINEANU RAZVAN

80	Lime fines briquetting	US48096465	1965-08-19	US3414643A	1968-12-03	COLLIE WILLIAM D

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